Carbonation of reactive magnesia cement (RMC)-based systems

Patent metadata

Field	Value
Publication number	US-12180118-B2
Application number	US-202117455203-A
Country	US
Kind code	B2
Filing date	Nov 16, 2021
Priority date	Nov 16, 2020
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

Herein discloses a method of carbonating reactive magnesia cement, which includes: (i) providing an aqueous suspension including a carbon dioxide-producing bacteria; (ii) mixing the aqueous suspension with a precursor which the carbon dioxide-producing bacteria generates carbon dioxide from for a duration to form an aqueous mixture sufficient for substantially carbonating the reactive magnesia cement; (iii) mixing the aqueous mixture with the reactive magnesia cement to form a blend; wherein a nutrient is provided in the aqueous suspension of step (i) or in the reactive magnesia cement of step (iii) to sustain the carbon dioxide-producing bacteria in the reactive magnesia cement; and (iv) curing the blend to carbonate the reactive magnesia cement. A reactive magnesia cement composite formed by the method is also disclosed.

First claim

The invention claimed is:

1. A method of carbonating reactive magnesia cement, the method comprising:
(i) providing an aqueous suspension comprising a carbon dioxide-producing bacteria;
(ii) mixing the aqueous suspension with a precursor which the carbon dioxide-producing bacteria generates carbon dioxide from for a duration to form an aqueous mixture sufficient for substantially carbonating the reactive magnesia cement;
(iii) mixing the aqueous mixture with the reactive magnesia cement to form a blend;
wherein a nutrient is provided in the aqueous suspension of step (i) or in the reactive magnesia cement of step (iii) to sustain the carbon dioxide-producing bacteria in the reactive magnesia cement; and
(iv) curing the blend to carbonate the reactive magnesia cement.

2. The method of claim 1 , wherein providing the aqueous suspension comprises dissolving the nutrient in water prior to dispersing the carbon dioxide-producing bacteria in the water.

3. The method of claim 1 , wherein the carbon dioxide-producing bacteria comprises an alkaliphilic bacteria or ureolytic bacteria.

4. The method of claim 1 , wherein the carbon dioxide-producing bacteria comprises Sporosarcina pasteurii, Bacillus sphaericus, Bacillus subtilis , and/or Bacillus cohnii.

5. The method of claim 1 , wherein the nutrient comprises yeast extract, soy broth, lysogeny broth, meat extract, and/or peptone.

6. The method of claim 1 , wherein mixing the aqueous suspension with the precursor comprises dissolving the precursor in water prior to mixing the aqueous suspension with the precursor.

7. The method of claim 1 , wherein the duration is 30 seconds or less.

8. The method of claim 1 , wherein the precursor comprises urea or magnesium lactate.

9. The method of claim 1 , wherein the aqueous mixture comprises water, and mixing the aqueous mixture with the reactive magnesia cement is carried out with the water of the aqueous mixture and the reactive magnesia cement present in a weight ratio of 0.43 to 0.7.

10. The method of claim 1 , further comprising mixing the reactive magnesia cement with a hydration agent prior to mixing the reactive magnesia cement with the aqueous mixture.

11. The method of claim 10 , wherein the hydration agent comprises hydrochloric acid, magnesium acetate, or magnesium chloride.

12. The method of claim 1 , further comprising mixing the aqueous suspension with seed particles, wherein the seed particles comprise hydromagnesite, carbon nanotubes, nano-sized silicon dioxide, nano-sized titanium dioxide, or carbon nanofibers.

13. The method of claim 12 , wherein mixing the aqueous suspension with the seed particles comprises dispersing the seed particles in water.

14. The method of claim 1 , further comprising mixing coarse aggregates with the blend prior to curing the blend.

15. The method of claim 14 , wherein the coarse aggregates have a size ranging from 4 mm to 10 mm.

16. The method of claim 1 , further comprising curing the blend at:
atmospheric pressure;
a temperature ranging from −10° C. to 50° C.; and
a humidity ranging from 75% to 100%.

17. A reactive magnesia cement composite formed by the method of claim 1 , the reactive magnesia cement composite comprising:
a carbon dioxide-producing bacteria; and
a X-ray diffraction pattern comprising:
one peak having a two theta value between 30° and 35° which corresponds to magnesite;
one peak having a two theta value between 35° and 40° which corresponds to brucite;
one peak having a two theta value between 40° and 45° which corresponds to periclase; and
wherein the intensity of the one peak which corresponds to brucite is lower in the presence of the carbon dioxide-producing bacteria as compared to another reactive magnesia cement composite absent of the carbon dioxide-producing bacteria.

18. The reactive magnesia cement composite of claim 17 , wherein the X-ray diffraction pattern further comprises:
one peak having a two theta value between 5° and 10° which corresponds to dypingite; and/or
one peak having a two theta value between 15° and 20° which corresponds to hydromagnesite.

19. The reactive magnesia cement composite of claim 17 , wherein the X-ray diffraction pattern further comprises one peak having a two theta value between 30° and 35° which corresponds to artinite.

20. The reactive magnesia cement composite of claim 17 , wherein the carbon dioxide-producing bacteria comprises Sporosarcina pasteurii, Bacillus sphaericus, Bacillus subtilis , and/or Bacillus cohnii.

Assignees

• Univ Nanyang Tech

Inventors

• Yang En-Hua
• Xiao Xi
• Unluer Cise
• Nguyen Tien Dung

Classifications

• C04B40/0091

  Processes of mixing characterised by carbon dioxide treatment · CPC title

• C04B2111/00019

  Carbon dioxide sequestration · CPC title

• C04B40/0231

  Carbon dioxide hardening · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01P2004/03

  obtained by SEM · CPC title