Method for making functional structural body

Patent metadata

Field	Value
Publication number	US-12179182-B2
Application number	US-202318303034-A
Country	US
Kind code	B2
Filing date	Apr 19, 2023
Priority date	May 31, 2017
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

A method for making a functional structural body includes a skeletal body of a porous structure composed of a zeolite-type compound, and at least one type of metallic nanoparticles present in the skeletal body, the skeletal body having channels connecting with each other, the metallic nanoparticles being present at least in the channels of the skeletal body.

First claim

What is claimed is:

1. A method for making a functional structural body, comprising:
a calcination step of calcinating a precursor material (B) obtained by impregnating a precursor material (A) for obtaining a skeletal body of a porous structure composed of a zeolite-type compound with a metal containing solution;
a hydrothermal treatment step of hydrothermally treating a precursor material (C) obtained by calcinating the precursor material (B) to obtain the functional structural body; and
a step of subjecting the hydrothermally treated precursor material (C) to a reduction treatment,
wherein the zeolite-type compound is selected from FAU type, MTW type, MFI type, FER type, LTA type, MWW type, MOR type, LTL type, and BEA type,
wherein the precursor material (A) is a regular mesopore material, and wherein the regular mesopore material is a compound including a Si—O skeletal body in which pores are uniformly sized and regularly developed one-dimensionally, two-dimensionally, or three-dimensionally.

2. The method for making a functional structural body according to claim 1 , wherein 50 to 500 mass % of a non-ionic surfactant is added to the precursor material (A) before adding the metal-containing solution to the precursor material (A).

3. The method for making a functional structural body according to claim 1 , wherein the precursor material (A) is impregnated with the metal containing solution by adding the metal containing solution to the precursor material (A) in multiple portions prior to the calcination step.

4. The method for making a functional structural body according to claim 1 , wherein an atomic ratio of silicon (Si) constituting the Si—O skeletal body of the precursor material (A) to a metal element (M) of the metal-containing solution ranges from 10 to 1000.

5. The method for making a functional structural body according to claim 1 , wherein in the hydrothermal treatment step, the precursor material (C) and a structure directing agent are mixed.

Assignees

• Univ Hokkaido Nat Univ Corp
• Furukawa Electric Co Ltd

Inventors

• Masuda Takao
• Nakasaka Yuta
• Yoshikawa Takuya
• Kato Sadahiro
• Fukushima Masayuki
• Inamori Kojiro
• Takahashi Hiroko
• BANBA Yuichiro
• Sekine Kaori

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/396

  Distribution of the active metal ingredient · CPC title

• B01J35/394

  Metal dispersion value, e.g. percentage or fraction · CPC title