Recycling method for styrene-containing plastic waste
US-2021277202-A1 · Sep 9, 2021 · US
US12173124B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12173124-B2 |
| Application number | US-202117450234-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 7, 2021 |
| Priority date | Oct 9, 2020 |
| Publication date | Dec 24, 2024 |
| Grant date | Dec 24, 2024 |
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Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.
Opening claim text (preview).
The invention claimed is: 1. A method of depolymerizing polyolefins comprising: a) adding a polyolefin-based feed stream and a styrene oligomer or a styrene polymer to a depolymerization unit heated to a temperature between about 200° C. and about 600° C.; and b) reacting said polyolefin-based feed stream with said styrene oligomer or said styrene polymer to depolymerize said polyolefin-based feed stream. 2. The method of claim 1 , wherein said polyolefin-based feed stream is combined with said styrene oligomer. 3. The method of claim 2 , wherein said styrene oligomer is an oligostyrene. 4. The method of claim 1 , wherein said polyolefin-based feed stream is combined with said styrene polymer. 5. The method of claim 4 , wherein said styrene polymer is a polystyrene. 6. The method of claim 1 , wherein said polyolefin-based feed stream is a low-density polyethylene, a high density polyethylene, a polypropylene, or a combination thereof. 7. The method of claim 1 , wherein said polyolefin-based feed stream is post-consumer waste. 8. The method of claim 1 , wherein said polyolefin-based feed stream is post-industrial waste. 9. The method of claim 1 , wherein said polyolefin-based feed stream comprises both post-industrial waste and post-consumer waste. 10. The method of claim 1 , wherein the polystyrene is post-consumer waste, post-industrial waste, or a combination thereof. 11. The method of claim 1 , wherein the concentration of said styrene oligomer or said styrene polymer is between greater than 0 to about 20 weight percent. 12. The method of claim 11 , wherein the concentration of said styrene oligomer or said styrene polymer is between about 2.5 and about 5 weight percent.
Polystyrene · CPC title
Polypropene · CPC title
Polyethene · CPC title
Plastics recycling; Rubber recycling · CPC title
Homopolymers or copolymers of ethene · CPC title
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