Combined reforming apparatus

Patent metadata

Field	Value
Publication number	US-12172895-B2
Application number	US-202117548574-A
Country	US
Kind code	B2
Filing date	Dec 12, 2021
Priority date	Oct 6, 2021
Publication date	Dec 24, 2024
Grant date	Dec 24, 2024

Abstract

A combined reforming apparatus is provided. The combined reforming apparatus includes a body, a first catalyst tube disposed inside the body and reacting at a first temperature to reform hydrocarbons (C x H y ) having two or more carbon atoms into methane (CH 4 ), a second catalyst tube disposed inside the body, connected to the first catalyst tube, and reacting at a second temperature higher than the first temperature to reform methane (CH 4 ) into synthesis gas comprising hydrogen (H 2 ) and carbon monoxide (CO), a combustion unit configured to supply heat to the first and second catalyst tubes, a gas supply pipe configured to supply hydrocarbon gas to the first catalyst tube, a first steam supply pipe configured to supply steam to the first catalyst tube, and a second steam supply pipe configured to supply steam to the second catalyst tube.

First claim

What is claimed is:

1. A combined reforming apparatus comprising:
a body;
a first catalyst tube disposed inside the body and reacting at a first temperature to reform hydrocarbons having two or more carbon atoms into methane (CH 4 );
a second catalyst tube disposed inside the body, connected to the first catalyst tube, and reacting at a second temperature higher than the first temperature to reform methane (CH 4 ) into synthesis gas comprising hydrogen (H 2 ) and carbon monoxide (CO);
a combustion unit configured to supply heat to the first and second catalyst tubes;
a gas supply pipe configured to supply hydrocarbon gas to the first catalyst tube;
a first steam supply pipe configured to supply steam to the first catalyst tube; and
a second steam supply pipe configured to supply steam to the second catalyst tube.

2. The combined reforming apparatus according to claim 1 ,
wherein the first steam supply pipe is configured to supply an amount of steam to the first catalyst tube, the amount of steam being determined according to a content of hydrocarbons having two or more carbon atoms included in the hydrocarbon gas received and contained by the first catalyst tube.

3. The combined reforming apparatus according to claim 1 ,
wherein the gas supply pipe is configured to supply the hydrocarbon gas, which is pyrolysis gas generated through pyrolysis of waste.

4. The combined reforming apparatus according to claim 1 ,
wherein the first catalyst tube has a U-curved portion.

5. The combined reforming apparatus according to claim 4 , further comprising:
a third steam supply configured to supply steam to the first catalyst tube in a flow direction of gas passing through the U-curved portion of the first catalyst tube.

6. The combined reforming apparatus according to claim 5 , wherein the third steam supply pipe is connected to an outlet side of the U-curved portion of the first catalyst tube.

7. The combined reforming apparatus according to claim 5 ,
wherein the U-curved portion extends along a circumferential direction of the body.

8. The combined reforming apparatus according to claim 1 ,
wherein the second steam supply pipe is connected to the second catalyst tube, is disposed in the body, and extends in a longitudinal direction of the body.

9. The combined reforming apparatus according to claim 8 ,
wherein combustion gas discharged from the combustion unit is discharged through a center portion of the body.

10. The combined reforming apparatus according to claim 9 , wherein the second catalyst tube is radially more inner than the first catalyst tube.

11. The combined reforming apparatus according to claim 10 ,
wherein the first catalyst tube and the second catalyst tube are arranged in parallel along the longitudinal direction of the body, and
a first wall extending from a first side of the body is disposed between the first catalyst tube and the second catalyst tube.

12. The combined reforming apparatus according to claim 11 ,
wherein a second wall extending from a second side of the body is disposed more inward than the second catalyst tube.

13. The combined reforming apparatus according to claim 10 ,
wherein the first catalyst tube includes a plurality of first catalyst tubes and the second catalyst tube includes a plurality of second catalyst tubes.

14. The combined reforming apparatus according to claim 13 ,
wherein the plurality of second catalyst tubes are arranged at intervals along a circumferential direction of the body, and
the plurality of first catalyst tubes are arranged to surround the plurality of second catalyst tubes.

15. The combined reforming apparatus according to claim 14 ,
wherein the second steam supply pipe includes a plurality of second steam supply pipes alternately arranged with the plurality of first catalyst tubes.

16. The combined reforming apparatus according to claim 1 , wherein the second steam supply pipe extends in parallel with the first catalyst tube along the longitudinal direction of the body and is connected to an inlet side of the second catalyst tube.

17. The combined reforming apparatus according to claim 16 , wherein steam supplied to the second catalyst tube is heated by combustion gas and then supplied to the second catalyst tube.

Assignees

• Doosan Enerbility Co Ltd

Inventors

• Nam Gyeong Mo
• Kim Bong Keun
• You Su Nam

Classifications

• C01B3/382

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C01B2203/0238

  the reforming step being a carbon dioxide reforming step · CPC title

• B01J2208/021

  comprising a plurality of beds with flow of reactants in parallel · CPC title

• B01J2208/00938

  Flow distribution elements · CPC title

• B01J2208/00893

  Feeding means for the reactants · CPC title