Iron based powder

Patent metadata

Field	Value
Publication number	US-12168818-B2
Application number	US-202318301024-A
Country	US
Kind code	B2
Filing date	Apr 14, 2023
Priority date	Mar 23, 2016
Publication date	Dec 17, 2024
Grant date	Dec 17, 2024

Abstract

A diffusion-bonded powder having an iron powder having 1-5%, preferably 1.5-4% and most preferably 1.5-3.5% by weight of copper particles diffusion bonded to the surfaces of the iron powder particles. The diffusion bonded powder is suitable for producing components having high sintered density and minimum variation in copper content. The iron powder may be produced by providing an atomized iron powder with an oxygen content of 0.3-1.2% by weight and with a carbon content of 0.1-0.5% by weight, and subjecting the atomized iron powder and a copper containing powder to a reduction annealing process in a reducing atmosphere to obtain the iron based powder.

First claim

The invention claimed is:

1. An iron based powder consisting of particles of reduced copper oxide diffusion bonded to the surface of an atomized iron powder,
wherein the content of copper is 1-5% by weight of the iron based powder,
wherein the iron based powder is produced by providing an atomized iron powder with an oxygen content of 0.3-1.2% by weight and with a carbon content of 0.1-0.5% by weight, and subjecting the atomized iron powder and a copper containing powder to a reduction annealing process in a reducing atmosphere to obtain the iron based powder, and
wherein the iron based powder has a maximum particle size of 250 μm, at least 75% is below 150 μm and at most 30% is below 45 μm, wherein the iron based powder has an apparent density of at least 2.70 g/cm 3 and an oxygen content of at most 0.16% by weight, and wherein other impurities are at most 1% by weight of the iron based powder.

2. The iron based powder according to claim 1 having an SSF-factor of at most 2.0, wherein the SSF-factor is defined as the quotient between the Cu content in weight % in the fraction of the iron based powder which passes a 45 μm sieve and the Cu content in weight % in the fraction of the iron based powder which does not pass a 45 μm sieve.

3. The iron based powder according to claim 1 , wherein the maximum copper content in a cross section of a sintered component made from said iron based powder is at most 100% higher than the nominal copper content, wherein the sintered component is produced by mixing said iron-based powder with 0.5 wt % of graphite, having a particle size, X90, of at most 15 μm measured with laser diffraction according to ISO 13320:1999, and 0.9 wt % of lubricant and the obtained mixture is transferred into a compaction die for production of tensile strength samples (TS-bars) according to ISO 2740:2009 and subjected to a compaction pressure of 600 MPa and the compacted sample is thereafter ejected from the compaction die and subjected to a sintering process at 1120° C. for a period of time of 30 minutes in an atmosphere of 90% nitrogen/10% hydrogen at atmospheric pressure and the maximum copper content is determined through lines scanning in a Scanning Electron Microscope (SEM) equipped with a system for Energy Dispersive Spectroscopy (EDS), wherein the magnification is 130×, working distance is 10 mm and the scanning time is 1 minute.

4. The iron based powder according to claim 1 , wherein the largest pore area in a cross section of a sintered component made from said iron based powder is at most 4,000 μm 2 , wherein the sintered component is produced by mixing said iron-based powder with 0.5 wt % of graphite, having a particle size, X90, of at most 15 μm measured with laser diffraction according to ISO 13320:1999, and 0.9 wt % of lubricant and the obtained mixture is transferred into a compaction die for production of tensile strength samples (TS-bars) according to ISO 2740:2009 and subjected to a compaction pressure of 600 MPa and the compacted sample is thereafter ejected from the compaction die and subjected to a sintering process at 1120° C. for a period of time of 30 minutes in an atmosphere of 90% nitrogen/10% hydrogen at atmospheric pressure and the largest pore area is determined in a Light Optical Microscope (LOM) at a magnification of 100× with the aid of a digital video camera and a computer based software and the total measured area is 26.7 mm 2 .

5. An iron-based powder composition comprising:
10 to 99.8 weight % of the iron based powder according to claim 1 ,
optionally graphite up to 1.5 weight %, and
when graphite is present, lubricant is present at 0.3-1.5 weight %, and
up to 1.0 weight % of machinability enhancing additives.

6. An iron-based powder composition comprising:
50 to 99.8 weight % of the iron based powder according to claim 1 ,
optionally graphite up to 1.5 weight %, and
when graphite is present, lubricant is present at 0.3-1.5 weight %, and
up to 1.0 weight % of machinability enhancing additives.

Assignees

• Hoeganaes Ab Publ

Inventors

• Larsson Caroline
• Engström Ulf
• Szabo Christophe

Classifications

• C22C38/16

  containing copper · CPC title

• B22F1/06

  Metallic powder characterised by the shape of the particles (nanosized particles B22F1/054) · CPC title

• B22F1/17 Primary

  Metallic particles coated with metal · CPC title

• B22F1/052

  characterised by a mixture of particles of different sizes or by the particle size distribution · CPC title

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title