Processed lignin and process to prepare such

Patent metadata

Field	Value
Publication number	US-12168672-B2
Application number	US-202017616105-A
Country	US
Kind code	B2
Filing date	Jun 8, 2020
Priority date	Jun 25, 2019
Publication date	Dec 17, 2024
Grant date	Dec 17, 2024

Abstract

Processed lignin comprising the elements carbon (C), hydrogen (H) and oxygen (O) in the following amounts:
C in an amount of between 60 and 85% by weight, H in an amount of between 3.0 and 6.0% by weight, O in an amount of between 10 and 29% by weight,

wherein the weight ratio C/H is at least 12.5, the ratio C/O is at least 2.5, the processed lignin comprises less than 0.1% by weight of total CI, a sulphur content below 1 g/kg, and a moisture content less than 3% by weight.

A process to prepare the processed lignin comprising subjecting particles comprising lignin and cellulose and optionally hemicellulose to acidic hydrolysis using hydrochloric acid of at least 35%, subjecting the obtained residue to a high temperature treatment of between 300 and 500° C. under inert gaseous atmosphere to a total CI level of below 0.1% by weight, after drying.

First claim

The invention claimed is:

1. A process for preparing a processed lignin containing less than 0.1% by weight of total CI, wherein the process comprises the steps of subjecting particulate matter comprising lignin and cellulose and optionally hemicellulose to:
a. acidic hydrolysis using hydrochloric acid of at least 35% by weight so that at least 60% by weight of the cellulose is hydrolysed, yielding hydrolysate and a particulate residue,
b. wherein said residue is dried to a moisture content of less than 3% by submitting the residue to a temperature of less than 240° C. under an inert atmosphere, and said drying step is carried out such that it recovers at least part of the hydrogen chloride used in step a,
c. subjecting the obtained particulate residue to a high temperature treatment of between 300 and 500° C. under inert gaseous atmosphere to a level of total CI in the particulate residue level of below 0.1% by weight.

2. The process according to claim 1 , wherein the processed lignin comprises the elements carbon (C), hydrogen (H) and oxygen (O) in the following amounts:
carbon in an amount of between 60 and 85% by weight
hydrogen in an amount of between 3.0 and 6.0% by weight,
oxygen in an amount of between 10 and 29% by weight,

wherein the weight ratio carbon/hydrogen C/H is at least 12.5 and the ratio C/O is at least 2.5, and wherein the processed lignin comprises less than 0.1% by weight of total CI, wherein it has a sulphur content of below 1 g/kg, and wherein the moisture content of it is less than 3% by weight.

3. The process according to claim 1 , wherein said high temperature treatment step c. is conducted at a temperature of between 320 and 480° C.

4. The process according to claim 1 , wherein the dried residue is subjected to the high temperature treatment step c. for a duration of between 5 and 240 minutes.

5. The process according to claim 1 , wherein the high temperature treatment step c. is carried out under an inert gaseous atmosphere comprising nitrogen, fluegas, carbon dioxide, or mixtures thereof.

Assignees

• Avantium Knowledge Centre Bv

Inventors

• Jongerius Anna Louise
• Russell Scott Henry
• Damen Kay Jochem
• Mckay Benjamin

Classifications

• C07G1/00 Primary

  Low-molecular-weight derivatives of lignin (high-molecular-weight derivatives of lignin {C08H6/00}) · CPC title