Organic light emitting device and display apparatus

Patent metadata

Field	Value
Publication number	US-12167617-B2
Application number	US-202017419307-A
Country	US
Kind code	B2
Filing date	Sep 28, 2020
Priority date	Sep 28, 2020
Publication date	Dec 10, 2024
Grant date	Dec 10, 2024

Abstract

An organic light emitting device and a display apparatus are provided. The organic light emitting device includes an anode, a cathode and a light-emitting layer arranged between the anode and the cathode, wherein a first hole injection layer and a second hole injection layer are arranged between the anode and the light-emitting layer. The first hole injection layer and the second hole injection layer are different in structure, including one or more of the following: the first hole injection layer and the second hole injection layer are different in thickness, different in material structure, different in quantity of the material and number of types of the material, and different in energy level of the material.

First claim

What is claimed is:

1. An organic light emitting device, comprising an anode, a cathode and a light-emitting layer arranged between the anode and the cathode, wherein a first hole injection layer and a second hole injection layer are arranged between the anode and the light-emitting layer, the first hole injection layer is arranged between the anode and the second hole injection layer, the first hole injection layer comprises at least one of an arylamine compound, a quinone derivative, a ketone derivative, a fluorenone derivative and a boron dioxide heterocyclic hexadiene and a derivative thereof, and the second hole injection layer comprises at least one of an arylamine compound, a quinone derivative, a ketone derivative, a fluorenone derivative and a boron dioxide heterocyclic hexadiene and a derivative thereof;
the first hole injection layer and the second hole injection layer are different in structure, comprising one or more of the following: thicknesses of the first hole injection layer and the second hole injection layer are different, material structures of the first hole injection layer and the second hole injection layer are different, quantities of materials of the first hole injection layer and the second hole injection layer are different, or energy levels of the materials of the first hole injection layer and the second hole injection layer are different;
wherein a material structure comprises a chemical formula of the material, a quantity of materials comprises a quantity of types of the materials, and an energy level of a material comprises a highest occupied molecular orbit (HOMO) energy level and a lowest unoccupied molecular orbit (LUMO) energy level of the material,
wherein the second hole injection layer comprises a second host material and a guest material doped in the second host material, one of the second host material and the guest material comprises an aromatic amine compound, and the other comprises a quinone derivative, a ketone derivative, a fluorenone derivative or a boron dioxide heterocyclic hexadiene and a derivative thereof, the second host material and the guest material satisfy:
−1.5 eV<|LUMO( B )|−|HOMO( A 2)|<1.5 eV;

where LUMO (B) is the lowest unoccupied molecular orbit (LUMO) energy level of the guest material, and HOMO (A2) is the highest occupied molecular orbit (HOMO) energy level of the second host material.

2. The organic light emitting device according to claim 1 , wherein
both the first hole injection layer and the second hole injection layer comprise no more than three types of materials.

3. The organic light emitting device according to claim 1 , wherein the guest material further satisfies:
|HOMO( B )|≥6 eV, |LUMO( B )|≥4 eV;

where HOMO (B) is the highest occupied molecular orbit (HOMO) energy level of the guest material.

4. The organic light emitting device according to claim 1 , wherein the second host material further satisfies:
5 eV≤|HOMO( A 2)≤6 eV.

5. The organic light emitting device according to claim 1 , wherein a doping ratio of the guest material to the second hole injection layer is 1% to 35%.

6. The organic light emitting device according to claim 1 , wherein the first hole injection layer comprises a first host material, and the first host material is the same as the guest material.

7. The organic light emitting device according to claim 1 , wherein a thickness of the first hole injection layer is 1 nm to 3 nm, and a thickness of the second hole injection layer is 1 nm to 8 nm.

8. The organic light emitting device according to claim 1 , wherein a substituent group of the aromatic amine compound comprises carbazole, methylfluorene, spirofluorene, dibenzothiophene or furan.

9. The organic light emitting device according to claim 1 , wherein the second host material comprises but is not limited to a compound having a structure of formula (I):

in the formula (I), Ar 1 to Ar 4 are each independently a substituted or unsubstituted aryl group having 5 to 50 ring atoms, L is a connecting group formed by a substituted or unsubstituted arylene group having 5 to 50 ring atoms, or a connecting group obtained by connecting a plurality of substituted or unsubstituted arylene groups having 5 to 50 ring atoms with M1, wherein M1 is any one of single bond, oxygen atom, sulfur atom, nitrogen atom, and saturated or unsaturated divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms.

10. The organic light emitting device according to claim 9 , wherein at least one of Ar 1 to Ar 4 is selected from any one of the following structures:

where R1 to R25 are each independently any one of hydrogen atom, aryl group having 5 to 50 ring atoms, substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, substituted or unsubstituted alkoxy group having 1 to 50 carbon atoms, substituted or unsubstituted aralkyl group having 6 to 50 ring atoms, substituted or unsubstituted aryloxy group having 5 to 50 ring atoms, substituted or unsubstituted arylthio group having 5 to 50 ring atoms, substituted or unsubstituted alkoxycarbonyl group having 1 to 50 carbon atoms, and aryl group having 5 to 50 ring atoms substituted by M2, wherein M2 is amino, halogen atom, cyano, nitro, hydroxyl or carboxyl.

11. The organic light emitting device according to claim 1 , wherein the guest material comprises but is not limited to a compound having a structure of formula (II):

in the formula (II), Z is a substituted or unsubstituted benzene ring, pyridine ring, thiophene ring, quinoline, indole or thienothiophene ring;
Ar 5 is

Ar 6 is

Y 1 to Y 4 are each independently N or C—R35;
R31 to R35 are each independently selected from any one of hydrogen, deuterium, halogen group, nitrile group, substituted or unsubstituted alkyl group, substituted or unsubstituted haloalkyl group, substituted or unsubstituted alkoxy group, substituted or unsubstituted haloalkoxy group, substituted or unsubstituted aryl group, substituted or unsubstituted halogenated aryl group, substituted or unsubstituted silyl group and substituted or unsubstituted heterocycle;
X1 and X2 are each independently selected from any one of the following structures:

R41 to R43 are each independently any one of hydrogen, fluoroalkyl, alkyl, aryl and heterocyclic group, and R42 and R43 form a ring.

12. The organic light emitting device according to claim 1 , wherein at least one organic layer is further arranged between the second hole injection layer and the light-emitting layer, a carrier mobility in the at least one organic layer ranges from 10 −3 cm 2 /Vs to 10 −5 cm 2 /Vs, and/or a conductivity of the at least one organic layer is less than or equal to that of the first hole injection layer and the second hole injection layer.

13. The organic light emitting device according to claim 12 , wherein a material of the at least one organic layer is the same as that of the second host material.

14. The organic light emitting device according to claim

Assignees

• Boe Technology Group Co Ltd
• Beijing Boe Technology Dev Co Ltd

Inventors

• Xu Meishan
• Sun Haiyan
• Wang Dan
• Lee Changho

Classifications

• H10K50/11 Primary

  characterised by the electroluminescent [EL] layers · CPC title

• H10K50/17 Primary

  Carrier injection layers · CPC title

• C09K11/07

  having chemically-interreactive components, e.g. reactive chemiluminescent compositions · CPC title

• C09K11/06

  containing organic luminescent materials · CPC title

• H10K2102/351

  Thickness · CPC title