Method for producing fluorine gas and device for producing fluorine gas

Patent metadata

Field	Value
Publication number	US-12152308-B2
Application number	US-202017613865-A
Country	US
Kind code	B2
Filing date	Dec 11, 2020
Priority date	Dec 27, 2019
Publication date	Nov 26, 2024
Grant date	Nov 26, 2024

Abstract

A method for producing fluorine gas including electrolyzing an electrolyte in an electrolytic cell, measuring the average particle size of a mist contained in a fluid generated in the inside of the electrolytic cell in the electrolyzing the electrolyte, and sending the fluid from the inside to the outside of the electrolytic cell through a flow path. The flow path in which the fluid flows is switched in accordance with the average particle size of the mist measured in the measuring the average particle size, such that the fluid is sent to a first flow path when the average particle size of the mist measured in the measuring the average particle size is not more than a predetermined reference value, or the fluid is sent to a second flow path when the average particle size is more than the predetermined reference value.

First claim

The invention claimed is:

1. A method for producing fluorine gas, the fluorine gas being produced by electrolyzing an electrolyte containing hydrogen fluoride and a metal fluoride, the method comprising:
electrolyzing the electrolyte in an electrolytic cell;
measuring an average particle size of a mist contained in a fluid generated in an inside of the electrolytic cell in the electrolyzing the electrolyte; and
sending the fluid from the inside to an outside of the electrolytic cell through a flow path, wherein
in the sending, the flow path in which the fluid flows is switched in accordance with the average particle size of the mist measured in the measuring an average particle size, such that the fluid is sent to a first flow path that sends the fluid from the inside of the electrolytic cell to a first outside when the average particle size of the mist measured in the measuring an average particle size is not more than a predetermined reference value, or the fluid is sent to a second flow path that sends the fluid from the inside of the electrolytic cell to a second outside when the average particle size is more than the predetermined reference value, and
the predetermined reference value is a numerical value of 0.1 μm or more and 1.0 μm or less.

2. The method for producing fluorine gas according to claim 1 , wherein the metal fluoride is a fluoride of at least one metal selected from the group consisting of potassium, cesium, rubidium, and lithium.

3. The method for producing fluorine gas according to claim 1 , wherein an anode used in the electrolyzing is a carbonaceous electrode formed from at least one carbon material selected from the group consisting of diamond, diamond-like carbon, amorphous carbon, graphite, and glassy carbon.

4. The method for producing fluorine gas according to claim 1 , wherein the electrolytic cell has a structure in which bubbles generated on an anode or a cathode used in the electrolyzing are capable of rising vertically in the electrolyte to reach a surface of the electrolyte.

5. A device for producing fluorine gas, the fluorine gas being produced by electrolysis of an electrolyte containing hydrogen fluoride and a metal fluoride, the device comprising:
an electrolytic cell storing the electrolyte and configured to perform the electrolysis;
an average particle size measurement unit configured to measure an average particle size of a mist contained in a fluid generated in an inside of the electrolytic cell during the electrolysis of the electrolyte, and
a flow path configured to send the fluid from the inside to an outside of the electrolytic cell, wherein
the flow path includes a first flow path configured to send the fluid from the inside of the electrolytic cell to a first outside and a second flow path configured to send the fluid from the inside of the electrolytic cell to a second outside and includes a flow path switching unit configured to switch the flow path in which the fluid flows, to the first flow path or the second flow path in accordance with the average particle size of the mist measured by the average particle size measurement unit,
the flow path switching unit is configured to send the fluid from the inside of the electrolytic cell to the first flow path when the average particle size of the mist measured by the average particle size measurement unit is not more than a predetermined reference value, or to send the fluid from the inside of the electrolytic cell to the second flow path when the average particle size is more than the predetermined reference value, and
the predetermined reference value is a numerical value of 0.1 μm or more and 1.0 μm or less.

6. The method for producing fluorine gas according to claim 2 , wherein an anode used in the electrolyzing is a carbonaceous electrode formed from at least one carbon material selected from the group consisting of diamond, diamond-like carbon, amorphous carbon, graphite, and glassy carbon.

7. The method for producing fluorine gas according to claim 2 , wherein the electrolytic cell has a structure in which bubbles generated on an anode or a cathode used in the electrolyzing are capable of rising vertically in the electrolyte to reach a surface of the electrolyte.

8. The method for producing fluorine gas according to claim 3 , wherein the electrolytic cell has a structure in which bubbles generated on the anode or a cathode used in the electrolyzing are capable of rising vertically in the electrolyte to reach a surface of the electrolyte.

Assignees

• Showa Denko Kk
• Resonac Corp

Inventors

• Mikami Katsumi
• FUKUCHI Yohsuke
• Kobayashi Hiroshi

Classifications

• C25B15/08 Primary

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B1/245 Primary

  Fluorine; Compounds thereof · CPC title

• C25B11/043

  Carbon, e.g. diamond or graphene · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title

• C25B9/60

  Constructional parts of cells · CPC title