Hydrogen-selective oxygen carrier materials and methods of use

Patent metadata

Field	Value
Publication number	US-12151233-B2
Application number	US-201917271089-A
Country	US
Kind code	B2
Filing date	Aug 27, 2019
Priority date	Aug 31, 2018
Publication date	Nov 26, 2024
Grant date	Nov 26, 2024

Abstract

Embodiments of the present disclosure are directed to hydrogen-selective oxygen carrier materials and methods of using hydrogen-selective oxygen carrier materials. The hydrogen-selective oxygen carrier material may comprise a core material, which includes a redox-active transition metal oxide; a shell material, which includes one or more alkali transition metal oxides; and a support material. The shell material may be in direct contact with at least a majority of an outer surface of the core material. At least a portion of the core material may be in direct contact with the support material. The hydrogen-selective oxygen carrier material may be selective to combust hydrogen in an environment that includes hydrogen and hydrocarbons.

First claim

The invention claimed is:

1. A hydrogen-selective oxygen carrier material comprising:
a core material consisting of a redox-active transition metal oxide chosen from Mn 2 O 3 , Fe 2 O 3 , Co 3 O 4 , CuO, (LaSr)CoO 3 , (LaSr)MnO 3 , Mg 6 MnO 8 , MgMnO 3 , MnO 2 , Fe 3 O 4 , Mn 3 O 4 , and Cu 2 O;
a shell material comprising one or more alkali transition metal oxides, the shell material in direct contact with at least a majority of an outer surface of the core material; and
a support material, wherein at least a portion of the core material is in direct contact with the support material; and
wherein the hydrogen-selective oxygen carrier material is selective to combust hydrogen in an environment comprising hydrogen and one or more hydrocarbons.

2. The hydrogen-selective oxygen carrier material of claim 1 , wherein the one or more alkali transition metal oxides comprise one or more of Na, Li, K, or Cs.

3. The hydrogen-selective oxygen carrier material claim 1 , wherein the one or more alkali transition metal oxides are chosen from Na 2 WO 4 , K 2 MoO 4 , Na 2 MoO 4 , K 2 WO 4 , Li 2 WO 4 , Cs 2 WO 4 , Cs 2 MoO 4 , or Li 2 MoO 4 .

4. The hydrogen-selective oxygen carrier material of claim 1 , wherein the shell material has a thickness of at least one crystalline unit cell.

5. The hydrogen-selective oxygen carrier material of claim 1 , wherein the shell material has a thickness of from 1 nm to 50 nm.

6. The hydrogen-selective oxygen carrier material of claim 1 , further comprising a secondary coating material comprising one or more alkali transition metal oxides, wherein the material composition of the shell material is different from the material composition of the secondary coating material.

7. The hydrogen-selective oxygen carrier material of claim 1 , wherein the shell material is in direct contact with at least 90% of the outer surface of the core material.

8. The hydrogen-selective oxygen carrier material of claim 1 , wherein the shell material is in direct contact with at least a majority of the outer surface of the support material and the core material.

9. The hydrogen-selective oxygen carrier material of claim 1 , wherein at least a portion of the support material has a pore size between 0.1 nm to 100 nm.

10. The hydrogen-selective oxygen carrier material of claim 1 , wherein the core material is in direct contact with and surrounds the support material.

11. The hydrogen-selective oxygen carrier material of claim 1 , wherein the support material is in direct contact with and surrounds the core material.

12. A method for converting hydrocarbons, the method comprising:
contacting the hydrogen with a hydrogen-selective oxygen carrier material to combust the hydrogen, wherein the hydrogen-selective oxygen carrier material comprises:
a core material consisting of a redox-active transition metal oxide chosen from Mn 2 O 3 , Fe 2 O 3 , Co 3 O 4 , CuO, (LaSr) CoO 3 , (LaSr)MnO 3 , Mg 6 MnO 8 , MgMnO 3 , MnO 2 , Fe 3 O 4 , Mn 3 O 4 , and Cu 2 O; and
a shell material comprising one or more alkali transition metal oxides, the shell material in direct contact with at least a majority of an outer surface of the core material;
a support material, wherein at least a portion of the core material is in direct contact with the support material; and

wherein the hydrogen-selective oxygen carrier material is selective for combusting hydrogen.

13. The process of claim 12 , further comprising dehydrogenating the one or more alkanes and alkyl aromatics to produce a dehydrogenated product and hydrogen.

14. The process of claim 12 , wherein the one or more alkanes is dehydrogenated by thermal cracking or by contact with a catalyst.

15. The hydrogen-selective oxygen carrier material of claim 1 , wherein the core material, the shell material, and the support material are not intermixed in the hydrogen-selective oxygen carrier material.

Assignees

• Dow Global Technologies Llc

Inventors

• Goodfellow Brian W
• Sharma Manish
• Yancey David F
• Malek Andrzej
• Stangland Eric E

Classifications

• C01G45/125

  of the type (MnO3)n-, e.g. CaMnO3 · CPC title

• C01G45/1221

  Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof · CPC title

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• B02C17/24

  Driving mechanisms · CPC title

• C01B3/26

  using catalysts · CPC title