Atomization and pyrolysis of resid cracking feed

Patent metadata

Field	Value
Publication number	US-12151223-B2
Application number	US-202017627060-A
Country	US
Kind code	B2
Filing date	Jun 17, 2020
Priority date	Jul 18, 2019
Publication date	Nov 26, 2024
Grant date	Nov 26, 2024

Abstract

A method and apparatus for conversion of petroleum resid fluid through atomization and pyrolysis, including: generating a stream of atomized resid fluid; and delivering the stream to a plurality of cracking particles, wherein the cracking particles have a temperature from 700° C. to 1200° C. when the stream is delivered. Generating the stream of atomized resid fluid may include: delivering heated resid fluid to a nozzle; and delivering diluent fluid to the nozzle. A method and apparatus includes: a first multi-phase fluid application device configured to generate a first stream of atomized resid fluid; a port configured to guide a plurality of cracking particles to intersect the first stream; and a particle heating component configured to heat the cracking particles before the particles intersect the first stream.

First claim

The invention claimed is:

1. A method comprising:
delivering heated resid fluid to a nozzle through a first conduit, and also delivering diluent fluid to the nozzle through a second conduit;
generating a stream of heated atomized resid fluid through the nozzle, which is a two-phase nozzle, a three-phase nozzle, or a capillary nozzle, wherein the stream comprises droplets independently having a diameter from 3 μm to 50 μm; and
delivering the stream to a plurality of cracking particles having a diameter of from 40 μm to 400 μm, wherein the plurality of cracking particles have a temperature from 700° C. to 1200° C. when the stream is delivered, wherein the droplets are smaller than the cracking particles by a factor of from 2 to 10.

2. The method of claim 1 , wherein the nozzle has a nozzle temperature of from 700° C. to 1000° C. while the heated resid fluid and the diluent fluid are delivered to the nozzle.

3. The method of claim 1 , wherein the heated resid fluid has a temperature of from 50° C. to 300° C. when delivered to the nozzle.

4. The method of claim 1 , wherein the heated resid fluid comprises asphaltene or ash content from 500 ppm to 30 wt %.

5. The method of claim 1 , wherein the heated resid fluid comprises hydrocarbons having a Conradson carbon residue from 1% to 20%.

6. The method of claim 1 , wherein the cracking particles move translationally relative to the nozzle while the stream is delivered to the cracking particles.

7. The method of claim 6 , wherein the stream is at an angle of from 0° to 90° relative to a line that is normal to the translational motion of the cracking particles.

8. The method of claim 6 , wherein each cracking particle has a residence time in the stream from 10 msec to 500 msec.

9. The method of claim 1 , wherein the nozzle is from −0.5 cm to 10 cm from the cracking particles.

10. The method of claim 1 , wherein at least one of:
at least some of the cracking particles are spherical; and
at least some of the cracking particles comprise a ceramic.

11. The method of claim 1 , comprising reducing bogging or fouling when delivering the heated residual fluid at least by:
delivering the heated resid fluid with a temperature to reduce a stickiness factor, wherein the temperature of the heated resid fluid is at least 50° C. when delivered to the nozzle, and the temperature of the heated resid fluid is increased in the nozzle having a nozzle temperature of at least 700° C.; and
providing the diluent fluid and the heated resid fluid with a diluent-to-hydrocarbon weight ratio of 0.3 to 1.0.

12. The method of claim 1 , comprising vaporizing the stream of heated atomized resid fluid using heat energy present in the heated atomized resid fluid and heat energy present in the plurality of cracking particles to convert the heated atomized resid fluid into one or more cracked products.

13. The method of claim 1 , comprising thermally cracking the stream via pyrolysis, without catalysis, upon delivering the stream to the plurality of cracking particles.

14. The method of claim 1 , wherein the stream of heated atomized resid fluid comprises one or more contaminants or compounds that cause deactivation of cracking catalysts.

15. The method of claim 1 , wherein the nozzle is from −0.5 cm to 0.5 cm from the cracking particles.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Keusenkothen Paul F
• Young Zachary D
• Harandi Mohsen N

Classifications

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• C10G9/28 Primary

  with preheated moving solid material · CPC title

• B01J2219/00159

  controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling · CPC title

• B01J6/008

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• B01J4/002

  Nozzle-type elements (nozzle-type reactors B01J19/26) · CPC title