Metal composite oxide and production method thereof, and electrode for solid oxide fuel cell

Patent metadata

Field	Value
Publication number	US-12148934-B2
Application number	US-202017440506-A
Country	US
Kind code	B2
Filing date	Mar 17, 2020
Priority date	Mar 25, 2019
Publication date	Nov 19, 2024
Grant date	Nov 19, 2024

Abstract

A method for producing a metal composite oxide, the method including steps of: preparing a slurry by mixing different kinds of metal compounds in a powder form, a dispersion medium, and a dispersant, and baking the different kinds of metal compounds after the dispersion medium in the slurry is removed. The slurry further includes a polyalkylene oxide having a viscosity average molecular weight of 150,000 or more. The slurry has a viscosity of 10 mPa·s to 2000 mPa·s, the viscosity being measured using a B-type viscometer under conditions of a temperature of 23° C. to 27° C. and a rotation rate of 60 rpm. According to the production method, a slurry in which different kinds metal compound powders are uniformly dispersed and a precipitate is unlikely to be formed can be obtained. Therefore, a metal composite oxide having a desired composition can be obtained.

First claim

The invention claimed is:

1. A method for producing a metal composite oxide, the method comprising steps of:
preparing a slurry by mixing different kinds of metal compounds in a powder form, a dispersion medium, and a dispersant, and
baking the different kinds of metal compounds after the dispersion medium in the slurry is removed, wherein
the slurry further includes a polyalkylene oxide having a viscosity average molecular weight of 150,000 or more.

2. The method for producing a metal composite oxide according to claim 1 , wherein the polyalkylene oxide is added in an amount of 0.1 parts by mass or more and 5 parts by mass or less per 100 parts by mass of the dispersion medium.

3. The method for producing a metal composite oxide according to claim 1 , wherein the slurry has a viscosity of 10 mPa·s or more and 2000 mPa·s or less, the viscosity being measured using a B-type viscometer under conditions of a temperature of 23° C. to 27° C. and a rotation rate of 60 rpm.

4. The method for producing a metal composite oxide according to claim 1 , wherein the viscosity average molecular weight of the polyalkylene oxide is 2,200,000 or less.

5. The method for producing a metal composite oxide according to claim 1 , wherein the polyalkylene oxide is polyethylene oxide.

6. The method for producing a metal composite oxide according to claim 1 , wherein the dispersant is anionic.

7. The method for producing a metal composite oxide according to claim 1 , wherein the dispersant is added in an amount of 0.5 parts by mass or more and 4 parts by mass or less per 100 parts by mass of a total of the different kinds of metal compounds.

8. The method for producing a metal composite oxide according to claim 1 , wherein the different kinds of metal compounds at least include: a metal compound containing at least one of lanthanum and samarium; a metal compound containing at least one selected from the group consisting of calcium, strontium, and barium; and a metal compound containing at least one selected from the group consisting of manganese, iron, cobalt, and nickel.

9. The method for producing a metal composite oxide according to claim 1 , wherein a total amount of the different kinds of metal compounds is 100 parts by mass or more and 170 parts by mass or less per 100 parts by mass of the dispersion medium.

10. The method for producing a metal composite oxide according to claim 1 , wherein the metal composite oxide is represented by a following general formula:
A1 1-x A2 x BO 3-δ ,
where the element A1 is at least one selected from the group consisting of La and Sm, the element A2 is at least one selected from the group consisting of Ca, Sr, and Ba, the element B is at least one selected from the group consisting of Mn, Fe, Co, and Ni, 0<x<1, and the δ is an oxygen deficiency amount,
the metal composite oxide having a perovskite-type crystal structure.

11. A metal composite oxide, represented by a following general formula:
A1 1-x A2 x BO 3-δ ,
where the element A1 is at least one selected from the group consisting of La and Sm, the element A2 is at least one selected from the group consisting of Ca, Sr, and Ba, the element B is at least one selected from the group consisting of Mn, Fe, Co, and Ni, 0<x<1, and the δ is an oxygen deficiency amount,
the metal composite oxide having a perovskite-type crystal structure, wherein
a standard deviation of values determined at 10 random spots by dividing a molar concentration M A of a total of the element A1 and the element A2 by a molar concentration M B of the element B is 0.1 or less.

12. The metal composite oxide according to claim 11 , wherein a difference between maximum and minimum values obtained by dividing the molar concentration M A by the molar concentration M B is 0.3 or less.

13. An electrode for a solid oxide fuel cell, the electrode comprising the metal composite oxide of claim 11 .

Assignees

• Sakai Chemical Industry Co

Inventors

• MATSUDA Hironao
• Yoneda Minoru
• Hirata Norimune
• Miyasaka Kazuya

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/1213

  characterised by the electrode/electrolyte combination or the supporting material · CPC title

• H01M4/8882

  Heat treatment, e.g. drying, baking · CPC title

• H01M4/8825

  Methods for deposition of the catalytic active composition · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title