Binder solution having lithium ion conductivity for all-solid-state battery and electrode slurry comprising same

Patent metadata

Field	Value
Publication number	US-12148929-B2
Application number	US-202017092927-A
Country	US
Kind code	B2
Filing date	Nov 9, 2020
Priority date	Dec 26, 2019
Publication date	Nov 19, 2024
Grant date	Nov 19, 2024

Abstract

The present disclosure relates to a binder solution having lithium ion conductivity for an all-solid-state battery and an electrode slurry including the same. Specifically, the binder solution includes a first binder having high binding force, a second binder having higher lithium ion conductivity than that of the first binder, a lithium salt, and an organic solvent that dissolves the lithium salt.

First claim

The invention claimed is:

1. A binder solution for an all-solid-state battery, comprising:
a first binder having a lithium ion conductivity;
a second binder having a lithium ion conductivity higher than the lithium ion conductivity of the first binder;
a lithium salt; and
an organic solvent that dissolves the lithium salt,
wherein the first binder comprises nitrile-butadiene rubber (NBR),
wherein the second binder is selected from the group consisting of poly(propylene carbonate) (PPC), poly(vinyl acetate) (PVA), poly(1,4-butylene adipate) (PBA) and combinations thereof,
wherein the lithium ion conductivity (σ 1 ) of the first binder is 10 −6 S/cm to 10 −7 S/cm,
wherein the lithium ion conductivity (σ 2 ) of the second binder is 4×10 −4 S/cm to 10 −5 S/cm,
wherein a weight ratio (m 2 /m 1 ) of the second binder and the first binder is 3 or less but greater than 0,
wherein the lithium salt is selected from the group consisting of lithium hexafluorophosphate (LiPF 6 ), lithium bis(fluorosulfonyl)imide (LiFSI), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium bis(pentafluoroethanesulfonyl)imide (LiBETI), and combinations thereof,
wherein the second binder is miscible with the first binder, the lithium salt, and the organic solvent,
wherein the binder solution comprises:
10 wt % or less but exceeding 0 wt % of the first binder and the second binder;
0.5 wt % to 3 wt % of the lithium salt; and
a remainder of the organic solvent,
wherein the organic solvent is the remainder of the binder solution, whereby the wt % of the first binder and second binder, wt % of the lithium salt, and wt % of the organic solvent sum to 100 wt %.

2. The binder solution of claim 1 , wherein the second binder is at least partially miscible with the first binder.

3. The binder solution of claim 1 , wherein a lithium ion conductivity ratio (σ 2 /σ 1 ) of the second binder and the first binder is 100 to 4,000.

4. The binder solution of claim 1 , wherein the organic solvent is selected from the group consisting of benzyl acetate, ethyl 4-methylbenzoate, anisole, ethyl p-anisate, benzyl isobutyrate and combinations thereof.

5. The binder solution of claim 1 , wherein the organic solvent has a boiling point of 150° C. to 300° C.

6. The binder solution of claim 1 , wherein the organic solvent has a vapor pressure of 0.001 mmHg to 10 mmHg at room temperature.

7. An electrode slurry for an all-solid-state battery, comprising:
the binder solution of claim 1 ;
an electrode active material;
a conductive material; and
a solid electrolyte.

8. The electrode slurry of claim 7 , comprising:
30 wt % or less but exceeding 0 wt % of the binder solution;
10 wt % or less but exceeding 0 wt % of the conductive material;
20 wt % or less but exceeding 0 wt % of the solid electrolyte; and
a remainder of the electrode active material,
wherein the electrode active material is the remainder of the electrode slurry, whereby the wt % of the binder solution, wt % of the conductive material, wt % of the solid electrolyte, and wt % of the electrode active material sum to 100 wt %.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Univ Hanyang Ind Univ Coop Found

Inventors

• Kim Sang Mo
• Lim Jae Min
• Lee Sang Heon
• Kwon Tae Young
• Seok Hoon
• Jung Yoon Seok
• Kim Kyu Tae
• Oh Dae Yang

Classifications

• H01M10/0562

  Solid materials · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title