Three-dimensional porous catalyst, catalyst carrier or absorbent structure of stacked strands

Patent metadata

Field	Value
Publication number	US-12146434-B2
Application number	US-202017626838-A
Country	US
Kind code	B2
Filing date	Jul 16, 2020
Priority date	Jul 19, 2019
Publication date	Nov 19, 2024
Grant date	Nov 19, 2024

Abstract

A three-dimensional porous catalyst, catalyst carrier or absorbent structure of stacked strands of catalyst, catalyst carrier or absorbent material, composed of layers of spaced-apart parallel strands, wherein parallel strands within a layer are arranged in groups of two or more closely spaced-apart, equidistant strands separated by a small distance, wherein the groups of equidistant strands are separated from adjacent strands or adjacent groups of strands by a larger distance.

First claim

The invention claimed is:

1. A three-dimensional porous catalyst, catalyst carrier or absorbent structure comprising stacked strands of catalyst, catalyst carrier or absorbent material, composed of adjacent layers of spaced-apart parallel strands, wherein parallel strands within a layer are arranged in groups of two or more closely spaced-apart, equidistant strands separated by a first distance, wherein the groups of equidistant strands are separated from adjacent strands or adjacent groups of strands by a second distance larger than the first distance.

2. The three-dimensional structure of claim 1 , wherein adjacent layers have the same pattern of parallel strands and are oriented at an angle to one another.

3. The three-dimensional structure of claim 1 having a hexagonal cross-section composed of at least three layers of parallel strands that are oriented at 0°, 60° and 120°, respectively, to one another.

4. The three-dimensional structure of claim 3 , wherein every third layer has a same orientation.

5. The three-dimensional structure of claim 1 having an octagonal cross-section composed of at least four layers of parallel strands that are oriented at 0°, 45° and 90 and 135°, respectively, to one another.

6. The three-dimensional structure of claim 5 , wherein every fourth layer has a same orientation.

7. The three-dimensional structure of claim 1 , comprising sections each composed of layers of spaced-apart parallel strands, wherein the pattern of the spaced-apart parallel strands within layers of one section are different from the pattern of spaced-apart parallel strands within layers of another section.

8. The three-dimensional structure of claim 7 , wherein each section comprises 3 or 4 layers of the same pattern oriented at an angle to one another.

9. The three-dimensional structure of claim 1 , comprising adjacent layers having different patterns of parallel strands.

10. The three-dimensional structure of claim 1 , wherein the thickness of the parallel strands varies in adjacent layers.

11. The three-dimensional structure of claim 1 , wherein the larger distance is 2 to 10 times the small distance.

12. The three-dimensional structure of claim 1 , wherein the groups of equidistant parallel strands are composed of 2, 3 or 4 to 6 parallel strands.

13. The three-dimensional structure of claim 1 , wherein in a layer single strands are arranged between two groups of equidistant parallel strands.

14. The three-dimensional structure of claim 1 , wherein the small distance is from 0.5 to 2 mm and the larger distance is 2 to 10 mm.

15. A method for producing a three-dimensional porous catalyst, catalyst carrier or absorbent structure as claimed in claim 1 , comprising the following steps:
a) Preparing a paste of metal, metal alloy, metal compound particles of catalytically active metal or inorganic oxide catalyst support particles in a liquid diluent, in which the metal, metal alloy or metal compound particles can be supported on or mixed with inorganic oxide catalyst support particles, and which paste comprises a binder material,
b) extruding the paste of step a) through one or more nozzles having a diameter larger than 100 μm to form strands, and depositing the extruded strands in consecutive layers of linear, spaced-apart parallel strands having the same or a different orientation and being congruent or not congruent with one another, to form a three-dimensional porous precursor,
c) drying the porous three dimensional precursor to remove the liquid diluent,
d) if necessary, reducing metal oxide(s) in the porous precursor to form the catalytically active metal or metal alloy, or conducting an additional heat treatment to produce a catalytically active material.

16. The method according to claim 15 , wherein parallel strands are deposited continuously as partial strands of one single individual strand in each layer.

17. The method according to claim 15 , wherein the inorganic oxide catalyst support is selected from the group consisting of silicon dioxide, aluminium oxide, titanium dioxide, zirconium dioxide, magnesium oxide, calcium oxide, mixed metal oxides, hydrotalcites, spinels, perovskites, metal phosphates, silicates, zeolites, steatite, cordierite, carbides, nitrides and mixtures or blends thereof.

18. The method according to claim 15 , wherein the catalytically active metal is selected from the group consisting of Na, K, Mg, Ca, Ba, Al, Si, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Sn, Sb, La, Hf, W, Re, Ir, Pt, Au, Pb, and Ce and mixtures or alloys thereof.

19. The method according to claim 15 , wherein a binder material is employed, selected from the group consisting of clays, alumina, silica and mixtures thereof.

20. A method of carrying out an oxidation, hydrogenation and dehydration reaction, comprising the step of bringing the reactants in contact with the three-dimensional porous catalyst structure of stacked catalyst strands according to claim 1 .

Assignees

• Basf Se

Inventors

• Kennema Marco Oskar
• Michielsen Bart
• Lefevere Jasper
• Walsdorff Christian
• Borninkhof Fred
• Scharf Florian

Classifications

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B22F1/105

  containing inorganic lubricating or binding agents, e.g. metal salts · CPC title

• B22F12/53

  Nozzles · CPC title

• B22F5/10

  of articles with cavities or holes, not otherwise provided for in the preceding subgroups · CPC title

• B01J37/16

  Reducing · CPC title