Methods of hydrogenating carbon dioxide using electrochemical cells comprising tunable catalysts

Patent metadata

Field	Value
Publication number	US-12146233-B2
Application number	US-202117445685-A
Country	US
Kind code	B2
Filing date	Aug 23, 2021
Priority date	Aug 21, 2020
Publication date	Nov 19, 2024
Grant date	Nov 19, 2024

Abstract

A method of hydrogenating carbon dioxide comprises forming a tunable catalyst comprising at least one metal comprising a size within a range of from a single atom to about 999 nanometers and formulated to produce one or more carbon-containing compounds. An electrochemical cell comprising a positive electrode, a negative electrode comprising the tunable catalyst, and an electrolyte between the positive electrode and the negative electrode is formed. Carbon dioxide is introduced to the negative electrode of the electrochemical cell and a potential difference is applied between the positive electrode and the negative electrode to selectively hydrogenate the carbon dioxide. The hydrogen ions are diffused through the electrochemical cell. The carbon dioxide at the negative electrode is hydrogenated to selectively form carbon monoxide, methane, or a desired ratio of carbon monoxide and methane. An electrochemical cell and a carbon dioxide hydrogenation system are also disclosed.

First claim

What is claimed is:

1. A method of hydrogenating carbon dioxide, comprising:
forming a tunable catalyst comprising at least one metal comprising a size within a range of from a single atom to about 999 nanometers and formulated to produce one or more carbon-containing compound, the tunable catalyst comprising a transition metal-metal oxide catalyst comprising a Sm 2 O 3 -doped CeO 2 supported Ir catalyst;
forming an electrochemical cell comprising a positive electrode, a negative electrode comprising the tunable catalyst, and an electrolyte between the positive electrode and the negative electrode;
introducing carbon dioxide to the negative electrode of the electrochemical cell;
applying a potential difference between the positive electrode and the negative electrode of the electrochemical cell to generate hydrogen ions;
diffusing the hydrogen ions through the electrochemical cell; and
hydrogenating the carbon dioxide at the negative electrode to selectively form carbon monoxide, methane, or a combination thereof.

2. The method of claim 1 , wherein when the at least one metal of the tunable catalyst comprises from a single metal atom to about 100 metal atoms, hydrogenating the carbon dioxide at the negative electrode comprises selectively forming carbon monoxide at greater than or equal to about 80% relative to the methane.

3. The method of claim 1 , wherein when the at least one metal of the tunable catalyst comprises from a single metal atom to about 100 metal atoms, hydrogenating the carbon dioxide at the negative electrode comprises selectively forming carbon monoxide at greater than or equal to about 90% relative to the methane.

4. The method of claim 1 , wherein forming a tunable catalyst comprises forming the Sm 2 O 3 -doped CeO 2 supported Ir catalyst, the Ir metal in the tunable catalyst comprising a size range of from about 1 Å to about 999 nm.

5. A method of hydrogenating carbon dioxide, comprising:
forming a tunable catalyst comprising Sm 2 O 3 -doped CeO 2 supported Ir catalyst and formulated to produce one or more carbon-containing compound;
forming an electrochemical cell comprising a positive electrode, a negative electrode comprising the tunable catalyst, and an electrolyte between the positive electrode and the negative electrode;
introducing carbon dioxide to the negative electrode of the electrochemical cell;
applying a potential difference between the positive electrode and the negative electrode of the electrochemical cell to generate hydrogen ions;
diffusing the hydrogen ions through the electrochemical cell; and
hydrogenating the carbon dioxide at the negative electrode at a temperature of from about 300° C. to about 500° C. to selectively form carbon monoxide, methane, or a combination thereof.

6. The method of claim 5 , further comprising introducing hydrogen to the positive electrode of the electrochemical cell.

7. The method of claim 6 , further comprising forming an alkane at the positive electrode of the electrochemical cell.

8. The method of claim 5 , wherein hydrogenating the carbon dioxide at the negative electrode comprises forming a product stream consisting essentially of carbon monoxide.

9. The method of claim 5 , wherein hydrogenating the carbon dioxide at the negative electrode comprises forming a product stream consisting essentially of methane.

10. The method of claim 5 , wherein diffusing the hydrogen ions through the electrochemical cell comprises diffusing the hydrogen ions across the electrolyte and to the negative electrode.

11. The method of claim 5 , wherein introducing carbon dioxide to the negative electrode of the electrochemical cell comprises introducing gaseous carbon dioxide, liquid carbon dioxide, or a combination thereof to the negative electrode of the electrochemical cell.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Li Meng
• Hua Bin
• Ding Dong

Classifications

• C25B3/03

  Acyclic or carbocyclic hydrocarbons · CPC title

• C25B11/069

  consisting of at least one single element and at least one compound; consisting of two or more compounds · CPC title

• C25B11/081

  the element being a noble metal · CPC title

• C25B11/052

  Electrodes comprising one or more electrocatalytic coatings on a substrate · CPC title

• C25B9/17

  Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof · CPC title