Process for Purifying Polycarbonate Polyols and Purifying Apparatus Therefor
US-2017152345-A1 · Jun 1, 2017 · US
US12146027B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12146027-B2 |
| Application number | US-202017424259-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 6, 2020 |
| Priority date | Jan 31, 2019 |
| Publication date | Nov 19, 2024 |
| Grant date | Nov 19, 2024 |
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Alkylene carbonates are removed from polyether-carbonate polymers by contacting the polyether-carbonate with an absorbent at a temperature of 30 to 150° C. The process is effective and inexpensive. The purified polyether-carbonate is useful for making polyurethanes as well as in many other applications.
Opening claim text (preview).
What is claimed is: 1. A process for removing an alkylene carbonate from a polyether-carbonate, comprising contacting a starting polyether-carbonate that contains at least 0.25 weight-%, based on the weight of the starting polyether carbonate, of one or more alkylene carbonates, with a solid absorbent that contains pores having an average pore size of at least 1 nm up to 100 nm at a temperature of 30 to 150° C. and at which temperature the starting polyether-carbonate is a liquid, wherein the solid absorbent has a pore volume of 0.25 to 2 mL/g and is selected from the group consisting of an unfunctionalized, crosslinked porous polymer that lacks ion exchange capacity in the form of a particulate solid and a crosslinked porous polymer which which crosslinking porous polymer is is a crosslinked porous anion exchange resin in the form of a particulate solid. 2. The process of claim 1 wherein the starting polyether-carbonate contains 0.5 to 15% by weight of the alkylene carbonate, based on the combined weight of polyether carbonate and alkylene carbonate. 3. The process of claim 1 wherein the alkylene carbonate includes propylene carbonate, ethylene carbonate or both propylene carbonate and ethylene carbonate. 4. The process of claim 1 wherein 40 to 100 weight % of the alkylene carbonate is removed. 5. The process of claim 1 wherein the temperature is 60 to 85° C.
and cyclic ethers · CPC title
Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title
and cyclic ethers · CPC title
saturated · CPC title
Cross-linked polymers · CPC title
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