Lubricating composition and method of lubricating an internal combustion engine

Patent metadata

Field	Value
Publication number	US-12139686-B2
Application number	US-202318205732-A
Country	US
Kind code	B2
Filing date	Jun 5, 2023
Priority date	Sep 14, 2016
Publication date	Nov 12, 2024
Grant date	Nov 12, 2024

Abstract

The disclosed technology provides a lubricating composition and a method of lubricating an internal combustion engine where the lubricating composition contains an oil of lubricating viscosity, one or more metal-containing, sulfur-free, alkyl-phenol based detergents, an alkaline earth metal sulfonate detergent, a polyisobutenyl succinimide dispersant, and a dispersant viscosity modifier having a number average molecular weight of at least 20,000.
The lubricating composition of the present invention can be formulated to have lower HTHS viscosity, and reduced phosphorous content, while providing protection against adhesive wear.

First claim

What is claimed is:

1. A low viscosity lubricating composition, comprising:
a) an oil having a viscosity of 4.5 to 6.5 cSt;
b) up to 0.45 weight percent of one or more metal-containing sulfur-free alkyl-phenol based detergents derived from an alkylphenol in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % by weight sulfonate soap to the composition; and
d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants; and
e) 0.2 wt % to 1 wt % of a mixture of dispersant viscosity modifiers-, wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60,000 to 100,000;

wherein the lubricating composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricating composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.

2. The composition of claim 1 , wherein the lubricating composition contains less than 0.15 wt % of a sulfur-coupled phenate detergent.

3. The composition of claim 1 , wherein the composition contains 0.2 wt % to 0.8 wt % of the mixture of dispersant viscosity modifiers.

4. The composition of claim 1 , wherein the sulfur-free alkylphenol-based detergent is selected from alkylene coupled alkylphenol detergents, alkylsalicylate detergents, and combinations thereof.

5. The composition of claim 1 , further comprising:
a metal dialkyl dithiophosphate, wherein about 65 mol % of the alkyl groups have 5 or more carbon atoms, present in an amount to deliver 0.01 to 0.08 weight percent phosphorus to the composition.

6. The composition of claim 1 , further comprising:
a metal dialkyl dithiophosphate, wherein about 75 mol % of the alkyl groups have 5 or more carbon atoms, present in an amount to deliver 0.01 to 0.08 weight percent phosphorus to the composition and wherein the composition comprises 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants.

7. A method of lubricating a compression ignition internal combustion engine comprising supplying to the engine a low phosphorus lubricant composition comprising:
a) an oil having a viscosity of 4.5 to 6.5 cSt;
b) up to 0.45 weight percent of one or more metal-containing sulfur-free alkyl-phenol based detergents in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % sulfonate soap to the composition;
d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants;
e) 0.2 wt % to 1 wt % of a mixture of dispersant viscosity modifiers wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60,000 to 100,000;

wherein the composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricant composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.

8. The method of claim 7 , wherein the lubricant composition contains 0.2 wt % to 0.8 wt % of the mixture of dispersant viscosity modifiers.

9. The method of claim 7 , wherein the sulfur-free alkylphenol-based detergent is selected from alkylene coupled alkylphenol detergents, alkylsalicylate detergents, and combinations thereof.

10. The method of claim 7 , further comprising:
a metal dialkyl dithiophosphate, wherein at least about 65 mol % of the alkyl groups have 5 or more carbon atoms, present in an amount to deliver 0.01 to 0.08 weight percent phosphorus to the composition.

11. The method of claim 7 , further comprising:
a metal dialkyl dithiophosphate, wherein at least about 75 mol % of the alkyl groups have 5 or more carbon atoms, present in an amount to deliver 0.01 to 0.08 weight percent phosphorus to the composition and wherein the composition comprises 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants.

12. A method of reducing adhesive wear in a compression engine lubricated with a low phosphorus lubricant composition, comprising supplying to the engine a lubricant composition comprising:
a) an oil having a viscosity of 4.5 to 6.5 cSt;
b) up to 0.45 weight percent of one or more metal-containing sulfur-free detergents derived from an alkylphenol in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % by weight sulfonate soap to the composition;
d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants; and
e) 0.1 wt % to 1 wt % of a mixture of dispersant viscosity modifiers wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60.000 to 100,000;
wherein the lubricant composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricant composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.

13. The method of claim 12 , wherein the lubricating composition comprises less than 0.15 wt % of a sulfur-coupled phenate detergent.

14. The method of claim 12 , wherein the sulfur-free alkylphenol-based detergent is selected from alkylene coupled alkylphenol detergents, alkylsalicylate detergents, and combinations thereof.

15. The method of claim 12 , further comprising:
a metal dialkyl dithiophosphate, wherein at least about 75 mol % of the alkyl groups have 5 or more carbon atoms, present in an amount to deliver 0.01 to 0.08 weight percent phosphorus to the composition and wherein the composition comprises 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants.

Assignees

• Lubrizol Corp

Inventors

• Loop John G
• Raguz Mary Galic

Classifications

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title