Renewable hydrocarbon composition having good cetane number and good cold properties

Patent metadata

Field	Value
Publication number	US-12139678-B2
Application number	US-202318315029-A
Country	US
Kind code	B2
Filing date	May 10, 2023
Priority date	Dec 11, 2020
Publication date	Nov 12, 2024
Grant date	Nov 12, 2024

Abstract

A renewable hydrocarbon composition as disclosed includes monobranched isoparaffins, dibranched isoparaffins, tribranched isoparaffins multibranched isoparaffins, and n-paraffins, having carbon numbers from C8 to C30. Said renewable hydrocarbon composition has high cetane number and excellent cold properties. The renewable hydrocarbon composition can be used as diesel fuel or as a diesel fuel component.

First claim

The invention claimed is:

1. A renewable hydrocarbon composition comprising:
monobranched isoparaffins from 30 wt % to 50 wt % of a total hydrocarbon composition weight, each of the monobranched isoparaffins containing exactly one alkyl substituent;
a sum of dibranched isoparaffins and tribranched isoparaffins from 40 wt % to 60 wt % of the total hydrocarbon composition weight, each of the dibranched isoparaffins containing exactly two alkyl substituents and each of the tribranched isoparaffins containing exactly three alkyl substituents;
from 5 wt % to 15 wt % of a sum of multibranched isoparaffins including at least four branches, each of the multibranched isoparaffins containing more than three alkyl substituents; and
from 2 wt % to 20 wt % of n-paraffins,
wherein said isoparaffins and n-paraffins have carbon numbers from C8 to C30, and of said isoparaffins and n-paraffins from 85 to 98 wt % have carbon numbers from C15 to C30.

2. The composition according to claim 1 , wherein of said isoparaffins and n-paraffins, at least 90 wt-% by the total hydrocarbon composition weight, have carbon numbers from C10 to C30.

3. The composition according to claim 1 , wherein more than 70 wt % of the beta carbons of said isoparaffins are substituted with at least one alkyl substituent.

4. The composition according to claim 1 , wherein more than 90 wt-% of said alkyl substituents are selected from methyl and ethyl substituents.

5. The composition according to claim 1 , wherein more than 95 wt-% of the beta carbons of said isoparaffins are substituted with at least one alkyl substituent.

6. The composition according to claim 1 , wherein a ratio of wt-% amount of the monobranched isoparaffins to a total wt-% amount of the isoparaffins is from 0.3 to 0.9.

7. The composition according to claim 1 , wherein more than 84 wt-% of the dibranched, tribranched and multibranched isoparaffins are each substituted with at least two methyl substituents in positions selected from beta carbons, (ω-1) carbons or combinations thereof.

8. The composition according to claim 1 , wherein a cloud point of said composition is from −25 to −40° C. when measured according to ASTM D 5771-2017.

9. The composition according to claim 1 , wherein a cetane number of said composition is from 74 to 84 when measured according to EN 15195-2014.

10. The composition according to claim 1 , having a density at 15° C. of 770-790 kg/m3 measured according to EN ISO 12185.

11. The composition according to claim 1 , wherein the composition has a boiling point in a range of 170° C. to 360° C. measured according to EN ISO 3405.

12. The composition according to claim 1 , wherein a total aromatic hydrocarbon content of the composition is less than 1500 wt-ppm with regard to the total hydrocarbon composition weight.

13. A process for producing the renewable hydrocarbon composition according to claim 1 , the process comprising:
i) providing a renewable feedstock;
ii) subjecting the renewable feedstock to hydrotreatment and hydroisomerisation reactions, the hydroisomerisation reaction conditions comprise a catalyst system including a molecular sieve and a noble metal catalyst; and a temperature from 200-500° C.; and
iii) recovering a renewable hydrocarbon composition produced in ii), the renewable hydrocarbon composition including:
monobranched isoparaffins from 30 wt % to 50 wt % of a total hydrocarbon composition weight, each of the monobranched isoparaffins containing exactly one alkyl substituent;
a sum of dibranched isoparaffins and tribranched isoparaffins from 40 wt % to 60 wt % of the total hydrocarbon composition weight, each of the dibranched isoparaffins containing exactly two alkyl substituents and each of the tribranched isoparaffins containing exactly three alkyl substituents;
from 5 wt % to 15 wt % of a sum of multibranched isoparaffins including at least four branches, each of the multibranched isoparaffins containing more than three alkyl substituents; and
from 2 wt % to 20 wt % of n-paraffins,
wherein said isoparaffins and n-paraffins have carbon numbers from C8 to C30, and of said isoparaffins and n-paraffins from 85 to 98 wt % have carbon numbers from C15 to C30.

14. The process according to claim 13 , wherein the renewable feedstock comprises oils and fats of biological origin or waste materials.

Assignees

• Neste Oyj

Inventors

• Kuronen Markku
• Kiiski Ulla
• Nortio Jenni
• Ruonakangas Anne

Classifications

• C10L2270/026

  for diesel engines, e.g. automobiles, stationary, marine · CPC title

• C10L2200/0469

  Renewables or materials of biological origin · CPC title

• C10G2400/04

  Diesel oil · CPC title

• C10G2300/307

  Cetane number, cetane index · CPC title

• C10G2300/304

  Pour point, cloud point, cold flow properties · CPC title