Pyrolysis vapor outlet anti-coking device and method of adsorbing medium self-recycling regeneration

Patent metadata

Field	Value
Publication number	US-12138580-B2
Application number	US-202218703716-A
Country	US
Kind code	B2
Filing date	Nov 22, 2022
Priority date	May 23, 2022
Publication date	Nov 12, 2024
Grant date	Nov 12, 2024

Abstract

A pyrolysis vapor outlet anti-coking device of adsorbing medium self-recycling regeneration includes a particle flow adsorbing system and a medium burning regeneration recycling system in mutual communication. The particle flow adsorbing system is configured to enable an easy-to-coke component to be adsorbed on an outer surface of an adsorbing medium to form a coking layer, and convey the a coking adsorbing medium into the medium burning regeneration recycling system. The medium burning regeneration recycling system is configured to quickly burn the coking layer on the outer surface of the adsorbing medium to realize regeneration of the adsorbing medium and convey the regenerated adsorbing medium into the particle flow adsorbing system for recycling use.

First claim

What is claimed is:

1. A pyrolysis vapor outlet anti-coking device of adsorbing medium self-recycling regeneration, comprising a particle flow adsorbing system and a medium burning regeneration recycling system in mutual communication; wherein
the particle flow adsorbing system is configured to enable tar to be adsorbed on an outer surface of an adsorbing medium to form a coking layer, and convey a coking adsorbing medium into the medium burning regeneration recycling system;
the medium burning regeneration recycling system is configured to burn the coking layer on the outer surface of the adsorbing medium to realize regeneration of the adsorbing medium and convey the regenerated adsorbing medium into the particle flow adsorbing system for recycling use;
the particle flow adsorbing system comprises a pyrolysis vapor pipe, one end of the pyrolysis vapor pipe is provided with a pyrolysis vapor inlet and a medium recycling inlet, the other end of the pyrolysis vapor pipe is provided with a pyrolysis vapor outlet and a medium recycling outlet, and a blocking net is disposed between the pyrolysis vapor outlet and the medium recycling outlet in the pyrolysis vapor pipe; and
the medium burning regeneration recycling system comprises a fluidized burning furnace, a gas-solid separator and a first blower, the medium recycling outlet of the pyrolysis vapor pipe is connected with a medium inlet of the fluidized burning furnace, an outlet of the fluidized burning furnace is connected with an inlet of the gas-solid separator, a medium outlet of the gas-solid separator is connected with the medium recycling inlet of the pyrolysis vapor pipe, and an air outlet of the first blower is connected with the fluidized burning furnace.

2. The pyrolysis vapor outlet anti-coking device of claim 1 , wherein a first air lock is disposed on a pipe connecting the medium recycling outlet of the pyrolysis vapor pipe with the medium inlet of the fluidized burning furnace, and a second air lock is disposed on a pipe connecting the medium outlet of the gas-solid separator with the medium recycling inlet of the pyrolysis vapor pipe.

3. The pyrolysis vapor outlet anti-coking device of claim 1 , further comprising an intelligent control system, wherein the intelligent control system comprises an automatic controller, a pyrolysis vapor flow rate sensor and an air volume regulator, the pyrolysis vapor flow rate sensor is disposed on the pyrolysis vapor outlet of the pyrolysis vapor pipe, the pyrolysis vapor flow rate sensor is connected with an input end of the automatic controller, and an output end of the automatic controller is connected with the first blower by the air volume regulator.

4. The pyrolysis vapor outlet anti-coking device of claim 1 , further comprising a tail gas heat supply treatment system, wherein the tail gas heat supply treatment system comprises a heat exchange unit and a tail gas treatment device, a tail gas outlet is disposed on a top of the gas-solid separator, and the tail gas outlet is connected with the tail gas treatment device by the heat exchange unit.

5. The pyrolysis vapor outlet anti-coking device of claim 4 , further comprising a second blower, wherein an air outlet of the second blower passes through the heat exchange unit and then connects with a sidewall of the fluidized burning furnace, and an output end of an automatic controller is connected with the second blower by an air volume regulator.

6. The pyrolysis vapor outlet anti-coking device of claim 2 , further comprising a tail gas heat supply treatment system, wherein the tail gas heat supply treatment system comprises a heat exchange unit and a tail gas treatment device, a tail gas outlet is disposed on a top of the gas-solid separator, and the tail gas outlet is connected with the tail gas treatment device by the heat exchange unit.

7. The pyrolysis vapor outlet anti-coking device of claim 3 , further comprising a tail gas heat supply treatment system, wherein the tail gas heat supply treatment system comprises a heat exchange unit and a tail gas treatment device, a tail gas outlet is disposed on a top of the gas-solid separator, and the tail gas outlet is connected with the tail gas treatment device by the heat exchange unit.

8. A pyrolysis vapor outlet anti-coking method of adsorbing medium self-recycling regeneration, comprising the following steps:
at step S1, an adsorbing medium and a pyrolysis vapor generated by a pre-reactor enter a front end of a pyrolysis vapor pipe and are fully mixed and fluidized to form a particle fluid and convey the particle fluid forward, macromolecular components of the tar in the pyrolysis vapor are formed into a coking layer around an adsorbing medium, and a coking adsorbing medium is separated from a gas phase at a blocking net at a tail of the pyrolysis vapor pipe, and enters a fluidized burning furnace; and
at step S2, the coking layer around the coking adsorbing medium is burned and consumed inside the fluidized burning furnace to regenerate the adsorbing medium, and the regenerated adsorbing medium is separated by a gas-solid separator and then enters the pyrolysis vapor pipe for recycling use.

9. The pyrolysis vapor outlet anti-coking method of claim 8 , wherein an automatic controller monitors a pyrolysis vapor flow rate by a pyrolysis vapor flow rate sensor, and regulates an adsorption and regeneration recycling rate of the adsorbing medium by a first blower and a second blower.

10. The pyrolysis vapor outlet anti-coking method of claim 9 , wherein an air volume of the second blower takes 30% to 50% of a total air volume, an excess air coefficient is 1.2 to 1.5, and a burning temperature inside the fluidized burning furnace is 900° C. to 1300° C. and a burning pressure is atmospheric pressure.

11. The pyrolysis vapor outlet anti-coking method of claim 9 , wherein a tail gas generated by the burning of the fluidized burning furnace enters a heat exchange unit for heat exchange and then undergoes tail gas treatment while the exchanged heat is conveyed into the fluidized burning furnace by the second blower.

Assignees

• Univ Southeast

Inventors

• Zhang Huiyan
• Peng Bo
• Wang Siyu
• Xiao Rui

Classifications

• C10G9/16 Primary

  Preventing or removing incrustation · CPC title

• B01D2259/4009

  using hot gas · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01D2253/106

  Silica or silicates · CPC title

• B01D2253/104

  Alumina · CPC title