Method for removing inert gas from liquid ammonia

Patent metadata

Field	Value
Publication number	US-12138564-B2
Application number	US-201917277499-A
Country	US
Kind code	B2
Filing date	Sep 13, 2019
Priority date	Sep 19, 2018
Publication date	Nov 12, 2024
Grant date	Nov 12, 2024

Abstract

A method of removing inert gas dissolved in liquid ammonia involves evaporating, compressing, and then condensing the liquid ammonia together with the inert gas dissolved therein. Thereby, a product stream of warm liquid ammonia that has been freed of the inert gas is obtained, which is under elevated pressure relative to standard pressure and hence suitable for immediate use in methods in which pure liquid pressurized ammonia is required. If, by contrast, the ammonia is cooled first, for example, below the boiling temperature for ammonia and expanded to standard pressure to store it in tanks as liquid ammonia at low temperatures, it is necessary first to reheat and compress it for further processing operations. Thus the disclosed methods lead to significant energy savings.

First claim

What is claimed is:

1. A method of removing inert gas dissolved in liquid ammonia, the method comprising delivering the liquid ammonia through a first conduit that branches into a first substream and a second substream, wherein the first substream sequentially undergoes evaporating at an evaporator, compressing at a compressor, and then condensing at a condenser causing the inert gas dissolved therein to escape from the liquid ammonia in the first substream at the condenser, wherein the second substream is expanded to a pressure in which gasses dissolved in the second substream are outgassed.

2. The method of claim 1 wherein the inert gas consists of a noble gas.

3. The method of claim 1 wherein the inert gas consists of at least one of helium, argon, or methane.

4. The method of claim 1 wherein the liquid ammonia enters the compressor at a first pressure and is compressed by the compressor to a second pressure, the second pressure being higher than the first pressure, the second pressure and at a temperature above +10° C.

5. The method of claim 1 wherein the liquid ammonia enters the compressor at a first pressure and is compressed by the compressor to a second pressure, the second pressure being higher than the first pressure, the second pressure in a range from 10 bar to 30 bar.

6. The method of claim 1 comprising cooling a process stream with heat that is absorbed by the ammonia during the evaporation.

7. The method of claim 6 comprising using the heat that is absorbed by the ammonia during the evaporation for condensation of ammonia in an ammonia synthesis plant.

8. The method of claim 1 wherein evaporated ammonia is compressed together with the inert gas dissolved in the ammonia.

9. The method of claim 1 wherein compressed ammonia is condensed with the aid of cooling water.

10. The method of claim 1 comprising drawing off gases that are insoluble in ammonia during the condensation from an apparatus used for the condensation.

11. The method of claim 10 comprising recycling the drawn off gases into a plant for preparing ammonia.

12. The method of claim 1 wherein the first substream of the liquid ammonia that has been evaporated, compressed, condensed, and then removed from a system as ammonia that has been freed of the inert gas is in a liquid pressurized warm stream, the second substream from the reactant stream branching off as a cold liquid stream.

13. The method of claim 12 wherein the first substream is a main stream of the ammonia removed from the system.

14. The method of claim 12 comprising:
feeding the second substream to a tank and expanding the second substream to a pressure in which gases dissolved in ammonia outgas in the tank; and
drawing off the inert gas from the tank while expanding the second substream.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag
• Thyssenkrupp Uhde Gmbh

Inventors

• Nölker Klaus

Classifications

• C01C1/024 Primary

  Purification · CPC title

• B01D19/0036

  Flash degasification (the other groups take precedence) · CPC title

• B01D5/0093

  Removing and treatment of non condensable gases · CPC title

• B01D5/0069

  with degasification or deaeration · CPC title

• B01D5/006

  with evaporation or distillation · CPC title