Method of making a fuel cell stack with stress reducing seals

Patent metadata

Field	Value
Publication number	US-12136756-B1
Application number	US-202117206790-A
Country	US
Kind code	B1
Filing date	Mar 19, 2021
Priority date	Apr 2, 2020
Publication date	Nov 5, 2024
Grant date	Nov 5, 2024

Abstract

A method of assembling a fuel cell stack includes depositing a liquid seal material on an interconnect, pressing a fuel cell into the liquid seal material, and solidifying the liquid seal material after pressing the fuel cell into the liquid seal material. The seal material may also include a support portion or extensions which are configured to reduce an amount of compressive stress on corners of the fuel cell in the fuel cell stack.

First claim

What is claimed is:

1. A method of assembling a fuel cell stack, comprising:
providing a cross-flow first interconnect comprising fuel holes that extend through the interconnect, fuel channels that extend in a first direction between fuel ribs on a fuel side of the interconnect, and air channels that extend on an air side of the interconnect between air ribs in a second direction substantially perpendicular to the first direction;
depositing a glass or glass ceramic seal material on the air side of the first interconnect to form riser seals that surround the fuel holes;
depositing the glass or glass ceramic seal material on the fuel side of the first interconnect to form a perimeter seal that surrounds the fuel channels and the fuel holes;
positioning a first side of a first fuel cell on the air side of the first interconnect in contact with at least a portion of the riser seals;
placing a cross-flow second interconnect into the fuel cell stack facing a second side of the first fuel cell;
positioning a second side of a second fuel cell on the fuel side of the first interconnect in contact with at least a portion of the perimeter seal;
placing a cross-flow third interconnect into the fuel cell stack facing a first side of the second fuel cell; and
sintering the fuel cell stack to reflow the riser seals and the perimeter seal,
wherein the riser seals, the perimeter seal, or both the riser seals and the perimeter seal comprise at least one of at least one support portion or extensions that are formed of the glass or glass ceramic seal material and which are configured to reduce an amount of compressive stress on corners of at least one of the first or second fuel cells in the fuel cell stack, and
wherein:
the riser seals comprise the support portions having a first thickness and base portions having a second thickness that is less than the first thickness;
the support portions at least partially define a pocket region; and
positioning the first side of the first fuel cell comprises disposing the first side of the first fuel cell on the base portions in the pocket region, such that the first fuel cell is partially surrounded by the support portions and opposing edges of the first fuel cell contact the base portions.

2. The method of claim 1 , wherein:
the second thickness ranges from about 25 microns to about 400 microns; and
the first thickness ranges from about 150 microns to about 850 microns.

3. The method of claim 1 , wherein:
depositing the glass or glass ceramic seal material on the air side of the interconnect comprises using a dual emulsion screen printing process to form the riser seals; and
both the base portions and the support portions comprise the glass or glass ceramic seal material.

4. The method of claim 1 , wherein:
the base portions comprise the glass or glass ceramic seal material;
the support portions each comprise a lower layer of the glass or glass ceramic seal material and an upper layer of a sacrificial material that lacks the glass or glass ceramic seal material; and
the sintering comprises burning off the sacrificial material of the upper layer.

5. A method of assembling a fuel cell stack, comprising:
providing a cross-flow first interconnect comprising fuel holes that extend through the interconnect, fuel channels that extend in a first direction between fuel ribs on a fuel side of the interconnect, and air channels that extend on an air side of the interconnect between air ribs in a second direction substantially perpendicular to the first direction;
depositing a glass or glass ceramic seal material on the air side of the first interconnect to form riser seals that surround the fuel holes;
depositing the glass or glass ceramic seal material on the fuel side of the first interconnect to form a perimeter seal that surrounds the fuel channels and the fuel holes;
positioning a first side of a first fuel cell on the air side of the first interconnect in contact with at least a portion of the riser seals;
placing a cross-flow second interconnect into the fuel cell stack facing a second side of the first fuel cell;
positioning a second side of a second fuel cell on the fuel side of the first interconnect in contact with at least a portion of the perimeter seal;
placing a cross-flow third interconnect into the fuel cell stack facing a first side of the second fuel cell; and
sintering the fuel cell stack to reflow the riser seals and the perimeter seal,
wherein the riser seals, the perimeter seal, or both the riser seals and the perimeter seal comprise at least one of at least one support portion or extensions that are formed of the glass or glass ceramic seal material and which are configured to reduce an amount of compressive stress on corners of at least one of the first or second fuel cells in the fuel cell stack, and
wherein:
the perimeter seal comprises the support portion having a first thickness and base portion having a second thickness that is less than the first thickness;
the support portion at least partially defines a pocket region; and
positioning the second side of the second fuel cell comprises disposing the second side of the second fuel cell on the base portion in the pocket region, such that the second fuel cell is partially surrounded by the support portion and opposing edges of the second fuel cell contact the base portion.

6. The method of claim 5 , wherein:
the second thickness ranges from about 25 microns to about 400 microns; and
the first thickness ranges from about 150 microns to about 850 microns.

7. The method of claim 5 , wherein:
depositing the glass or glass ceramic seal material on the fuel side of the interconnect comprises using a dual emulsion screen printing process to form the perimeter seal; and
both the base portion and the support portion comprise the glass or glass ceramic seal material.

8. The method of claim 5 , wherein:
the base portion comprises the glass or glass ceramic seal material;
the support portion comprises a lower layer of the glass or glass ceramic seal material and an upper layer of a sacrificial material that lacks the glass or glass ceramic seal material; and
the sintering comprises burning off the sacrificial material of the upper layer.

9. The method of claim 5 , wherein the riser seals each comprise extensions that extend across and partially cover portions of some of the air channels.

10. The method of claim 5 , wherein the perimeter seal comprises the extensions that extend across and partially cover portions of some of the fuel channels.

11. The method of claim 5 , further comprising:
solidifying the riser seals prior to positioning the first side of the first fuel cell on the air side of the first interconnect in contact with the riser seals; and
solidifying the peripheral seal prior to positioning the second side of the second fuel cell on the fuel side of the first interconnect in contact with the perimeter seal.

12. The method of claim 5 , wherein the fuel holes comprise fuel inlet holes and fuel outlet holes.

Assignees

• Bloom Energy Corp

Inventors

• Gasda Michael D
• Nallabolu Madhuri
• Therault Brian
• Hintz Robert
• Vo Hoa
• Phan Phuc
• Nikong Patrick
• Young Greg

Classifications

• H01M8/2404

  Processes or apparatus for grouping fuel cells · CPC title

• H01M8/2432

  Grouping of unit cells of planar configuration · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0282

  Inorganic material · CPC title

• H01M8/248 Primary

  Means for compression of the fuel cell stacks · CPC title