Effect pigment, production method, value document and printing ink

Patent metadata

Field	Value
Publication number	US-12129382-B2
Application number	US-202017779270-A
Country	US
Kind code	B2
Filing date	Nov 20, 2020
Priority date	Nov 27, 2019
Publication date	Oct 29, 2024
Grant date	Oct 29, 2024

Abstract

A platelet-shaped magnetic effect pigment is provided for use in a printing ink, and includes a layer construction with a magnetic layer and at least one optical functional layer, such that the magnetic layer is based on a magnetic material having a column-shaped nanostructure and the magnetic columns respectively have a largely uniform preferential magnetic direction deviating from the platelet plane.

First claim

The invention claimed is:

1. A platelet-shaped magnetic effect pigment for use in a printing ink, comprising a layer construction with a magnetic layer and at least one optical functional layer,
wherein the magnetic layer is based on a magnetic material having a column-shaped nanostructure and magnetic columns respectively have a largely uniform preferential magnetic direction deviating from a platelet plane.

2. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the largely uniform preferential magnetic direction of the magnetic columns is aligned substantially perpendicular to the platelet plane of the effect pigment.

3. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the largely uniform preferential magnetic direction of the magnetic columns is inclined towards the platelet plane with an angle of inclination, measured starting from the perpendicular to the platelet plane, in a region of 1° to 20°.

4. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the magnetic columns respectively have a size of less than 1000 nm.

5. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the largely uniform preferential magnetic direction of the magnetic columns is a uniaxial magnetic anisotropy.

6. The platelet-shaped magnetic effect pigment according to claim 5 , wherein the material of the magnetic layer is selected from the group consisting of BaFe 12 O 19 , FePt, CoCrPt, CoPt, BiMn, α-Fe 2 O 3 and Nd 2 Fe 14 B, and the largely uniform preferential magnetic direction of the magnetic columns is a uniaxial magnetic crystal anisotropy, or
wherein the material of the magnetic layer is selected from the group consisting of iron, cobalt, nickel and an alloy of one or several of the aforementioned elements, and the largely uniform preferential magnetic direction of the magnetic columns is a uniaxial magnetic shape anisotropy.

7. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the column-shaped nanostructure of the magnetic material is obtainable by means of a glancing angle deposition (GLAD) technique or an oblique angle deposition (OAD) technique.

8. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the optical functional layer is a metallic layer, a color layer obtainable by printing technology, an interference layer construction based on a reflective layer, a dielectric layer and an absorbent layer, or a combination of two or several of the aforementioned elements.

9. The platelet-shaped magnetic effect pigment according to claim 8 , wherein the optical functional layer is an interference layer construction based on a reflective layer, a dielectric layer and an absorbent layer and the effect pigment has the following layer sequence: absorbent layer-dielectric layer-reflective layer-dielectric layer-absorbent layer-magnetic layer.

10. A method for manufacturing a platelet-shaped magnetic effect pigment according to claim 1 , comprising:
a) producing a magnetic layer on a basis of a magnetic material having a column-shaped nanostructure, the magnetic columns being formed with a largely uniform preferential magnetic direction deviating from a plane of the magnetic layer;
b) producing a layer construction having the magnetic layer and at least one optical functional layer according to claim 1 ; and
c) crushing the layer construction obtained in step b) into the individual platelet-shaped magnetic effect pigments.

11. A method for manufacturing a value document, comprising
printing a value document substrate with a first printing ink containing platelet-shaped magnetic effect pigments according to claim 1 in a first region;
aligning the platelet-shaped magnetic effect pigments in the first printing ink respectively printed in the first region by means of an external magnetic field;
curing the first printing ink printed in the first region.

12. The method according to claim 11 , wherein the method further comprises:
printing the value document substrate with a second printing ink containing second platelet-shaped magnetic effect pigments in a second region adjacent to the first region, the second effect pigments being visually different from the first effect pigments;
aligning the platelet-shaped magnetic effect pigments in the second printing ink printed in the second region by means of an external magnetic field; and
curing the second printing ink printed in the second region.

13. The method according to claim 11 , wherein the method further comprises:
printing the value document substrate with a second printing ink containing conventional platelet-shaped magnetic effect pigments in a second region adjacent to the first region, the conventional platelet-shaped magnetic effect pigments having a preferential magnetic direction extending along the platelet plane;
aligning the platelet-shaped magnetic effect pigments in the second printing ink printed in the second region by means of an external magnetic field; and
curing the second printing ink printed in the second region so that the first and second regions have a clearly distinguishable appearance due to a different alignment of the two types of effect pigments.

14. A value document obtainable by the method according to claim 11 .

15. The value document according to claim 14 , wherein the value document is a bank note or an identification document.

16. A printing ink comprising platelet-shaped magnetic effect pigments according to claim 1 .

17. The printing ink according to claim 16 , wherein the printing ink further comprises a binding agent including a UV-curing binding agent, a binding agent curing by means of electron beams or a heat-curing binding agent.

18. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the effect pigment has a sandwich-like layer construction and the magnetic layer as a central layer is provided both on the front side and on the back side with respectively one optical functional layer,
wherein the two optical functional layers independently from each other are selected from a reflective metallic layer, a color layer obtainable by printing technology, an interference layer construction based on a reflective layer, a dielectric layer and an absorbent layer, or a combination of two or more of the aforementioned elements.

19. The platelet-shaped magnetic effect pigment according to claim 1 , wherein the effect pigment has an asymmetric layer construction with two optical functional layers differing from each other, which respectively are an interference layer construction based on a reflective layer, a dielectric layer and an absorbent layer and differ from each other with regard to the material or a layer thickness of the dielectric layer, and the effect pigment has the following layer sequence: absorbent layer-dielectric layer-reflective layer-magnetic layer-reflective layer-dielectric layer-absorbent layer.

20. The platelet-shaped magnetic effect pigment according to claim 19 , wherein the effect pigment has an asymmetric layer construction,
wherein the magnetic layer, on the front side, is provided with an interference layer construction based on a reflective layer, a dielectric layer and an absorbent layer and the magnetic layer, on the back side, is provided with a reflective metallic layer, so that the effect pigment has the following layer sequence: absorbent layer-dielectric layer-reflective layer-magnetic layer-reflective metallic layer.

21. The

Assignees

• Giesecke & Devrient Currency Technology Gmbh

Inventors

• Rahm Michael
• Heim Manfred
• Dehmel Raphael
• Hoffmuller Winfried

Classifications

• H01F1/0551

  in the form of particles, e.g. rapid quenched powders or ribbon flakes · CPC title

• C09D11/50

  Sympathetic, colour changing or similar inks · CPC title

• C09D11/101

  Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing · CPC title

• C09D11/037

  characterised by the pigment · CPC title

• C09C1/0021

  comprising a core coated with only one layer having a high or low refractive index · CPC title