Composition and method for producing cellulose fiber

Patent metadata

Field	Value
Publication number	US-12129357-B2
Application number	US-202017605336-A
Country	US
Kind code	B2
Filing date	Apr 21, 2020
Priority date	Apr 23, 2019
Publication date	Oct 29, 2024
Grant date	Oct 29, 2024

Abstract

Provided is a cellulose solution (a composition) in which decomposition of cellulose does not easily proceed even if heated. Further, provided is a method for producing a cellulose fiber excellent in mechanical strength. The composition includes cellulose and a compound represented by the following formula (1), a concentration of 1-methylimidazolium chloride being 300 ppm or less on a mass basis with respect to the compound represented by the formula (1).
In the formula (1), R is an alkyl group having 2 to 6 carbon atoms, and Me is a methyl group.

First claim

The invention claimed is:

1. A composition comprising cellulose and a compound represented by the following formula (1),
a concentration of 1-methylimidazolium chloride being 300 ppm or less on a mass basis with respect to the compound represented by the formula (1):

 wherein R is an alkyl group having 2 to 6 carbon atoms, and Me is a methyl group, in the formula (1).

2. The composition according to claim 1 , wherein a content of the compound represented by the formula (1) in the composition accounts for 90% by mass or more of a solvent contained in the composition.

3. The composition according to claim 1 , wherein the content of 1-methylimidazolium chloride in the composition is 1 ppb or more with respect to the compound represented by the formula (1).

4. The composition according to claim 1 , wherein R is a butyl group in the formula (1).

5. A method for producing a cellulose fiber, comprising
spinning a composition,
the composition comprising cellulose and a compound represented by the following formula (1),
a concentration of 1-methylimidazolium chloride being 300 ppm or less on a mass basis with respect to the compound represented by the formula (1):

wherein R is an alkyl group having 2 to 6 carbon atoms, and Me is a methyl group.

6. The method for producing the cellulose fiber according to claim 5 , wherein a content of the compound represented by the formula (1) in the composition accounts for 90% by mass or more of a solvent contained in the composition.

7. The method for producing the cellulose fiber according to claim 5 , wherein a content of 1-methylimidazolium chloride in the composition is 1 ppb or more with respect to the compound represented by the formula (1).

8. The method for producing the cellulose fiber according to claim 5 , wherein R is a butyl group in the formula (1).

9. The method for producing the cellulose fiber according to claim 5 , wherein the compound represented by the formula (1) is obtained by treating a reaction product of 1-methyl imidazole and RCl with a treating agent having ion adsorption ability, and wherein R is an alkyl group having 2 to 6 carbon atoms.

10. The method for producing the cellulose fiber according to claim 9 , wherein the treating agent having ion adsorption ability is at least one selected from the group consisting of an ion exchange resin, activated carbon, zeolite, hydrotalcite, and a metal oxide.

11. The method for producing the cellulose fiber according to claim 5 , wherein the compound represented by the formula (1) is obtained by treating a reaction product of 1-methyl imidazole and RCl with an alkali, and wherein R is an alkyl group having 2 to 6 carbon atoms.

12. The method for producing the cellulose fiber according to claim 11 , wherein the alkali is at least one selected from the group consisting of sodium hydroxide, potassium hydroxide, lithium hydroxide, calcium hydroxide, magnesium hydroxide, strontium hydroxide, barium hydroxide, tetramethylammonium hydroxide, tetraethylammonium hydroxide, and tetrabutylammonium hydroxide.

13. The method for producing the cellulose fiber according to claim 5 , wherein the method comprises immersing the spun cellulose fiber in a coagulating liquid, to elute the compound represented by the formula (1) contained in the cellulose fiber into the coagulating liquid.

14. The method for producing the cellulose fiber according to claim 13 , wherein the method comprises recycling the compound represented by the formula (1) eluted into the coagulating liquid.

15. The method for producing the cellulose fiber according to claim 13 , wherein the coagulating liquid comprises water.

16. The method for producing the cellulose fiber according to claim 6 , wherein a content of 1 -methylimidazolium chloride in the composition is 1 ppb or more with respect to the compound represented by the formula (1).

17. The method for producing the cellulose fiber according to claim 6 , wherein R is a butyl group in the formula (1).

18. The method for producing the cellulose fiber according to claim 6 , wherein the compound represented by the formula (1) is obtained by treating a reaction product of 1-methyl imidazole and RCl with a treating agent having ion adsorption ability, and wherein R is an alkyl group having 2 to 6 carbon atoms.

19. The method for producing the cellulose fiber according to claim 6 , wherein the treating agent having ion adsorption ability is at least one selected from the group consisting of an ion exchange resin, activated carbon, zeolite, hydrotalcite, and a metal oxide.

20. The method for producing the cellulose fiber according to claim 6 , wherein the compound represented by the formula (1) is obtained by treating a reaction product of 1-methyl imidazole and RCl with an alkali, and wherein R is an alkyl group having 2 to 6 carbon atoms.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Aoyama Kimihiro
• MIZUSAKA Tetsuhiko
• NAKAYASU Yasuyoshi
• Gotoh Yasuo

Classifications

• D10B2201/20

  Cellulose-derived artificial fibres · CPC title

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• C08L1/02 Primary

  Cellulose; Modified cellulose · CPC title

• D01F2/00

  Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title