Molybdenum sulfide powder and method for producing same, heavy-metal adsorbent, photothermal conversion material, distillation method, oxygen reduction catalyst, and catalyst ink

Patent metadata

Field	Value
Publication number	US-12129184-B2
Application number	US-202017762736-A
Country	US
Kind code	B2
Filing date	Sep 24, 2020
Priority date	Sep 24, 2019
Publication date	Oct 29, 2024
Grant date	Oct 29, 2024

Abstract

A molybdenum sulfide powder according to the invention contains molybdenum disulfide having a 3R crystal structure. A heavy-metal adsorbent according to the invention contains molybdenum sulfide particles, and the molybdenum sulfide particles have a median diameter D 50 of 10 nm to 1,000 nm obtained by a dynamic light scattering type particle diameter distribution measuring device. A photothermal conversion material according to the invention contains a material containing molybdenum sulfide particles and generates heat by absorbing light energy.

First claim

The invention claimed is:

1. A molybdenum sulfide powder comprising:
molybdenum disulfide having a 3R crystal structure, and molybdenum disulfide having a 2H crystal structure and a 3R crystal structure, wherein primary particles of molybdenum sulfide particles constituting the molybdenum sulfide powder have a string shape, a ribbon shape, or a sheet shape, and have a thickness in a range of 1 nm to 40 nm, and wherein the molybdenum sulfide powder has a specific surface area of 10 m 2 /g or more measured by a BET method.

2. The molybdenum sulfide powder according to claim 1 , wherein in a spectrum obtained from powder X-ray diffraction (XRD) using Cu-Kα rays as an X-ray source, both a peak in the vicinity of 39.5° and a peak in the vicinity of 49.5° include a synthetic peak of the 2H crystal structure and the 3R crystal structure, and a half width is 1° or more.

3. The molybdenum sulfide powder according to claim 1 , which has a median diameter D 50 of 10 nm to 1000 nm obtained by a dynamic light scattering type particle diameter distribution measuring device.

4. The molybdenum sulfide powder according to claim 1 , wherein in a radial distribution function obtained from an extended X-ray absorption fine structure (EXAFS) spectrum of a K absorption edge of molybdenum, a ratio (I/II) of peak intensity I caused by Mo—S to peak intensity II caused by Mo—Mo is more than 1.0.

5. A method for producing the molybdenum sulfide powder according to claim 1 , comprising:
heating a molybdenum trioxide powder made of an aggregate of primary particles containing molybdenum trioxide having a ß crystal structure at a temperature of 200° ° C. to 1,000° C. in the presence of a sulfur source.

6. The method for producing the molybdenum sulfide powder according to claim 5 , wherein the molybdenum trioxide powder made of the aggregate of the primary particles containing molybdenum trioxide having a β crystal structure is heated at a temperature of 100° C. to 800° C. in the absence of the sulfur source, and then the molybdenum trioxide powder is heated at the temperature of 200° ° C. to 1,000° C. in the presence of the sulfur source.

7. The method for producing the molybdenum sulfide powder according to claim 5 , wherein the primary particles of the molybdenum trioxide powder have an average particle diameter of 5 nm to 1,000 nm.

8. The method for producing the molybdenum sulfide powder according to claim 5 , wherein S has an amount of 500 mol % or more in the sulfur source with respect to 100 mol % of the amount of MoO 3 in the molybdenum trioxide powder.

9. The method for producing the molybdenum sulfide powder according to claim 5 , wherein a heating temperature in the presence of the sulfur source is 320° C. or higher.

10. A heavy-metal adsorbent comprising:
the molybdenum sulfide powder according to claim 1 .

11. A photothermal conversion material, comprising:
a material containing the molybdenum sulfide powder according to claim 1 , wherein
the photothermal conversion material generates heat by absorbing light energy.

12. The photothermal conversion material according to claim 11 , which is a light-absorbing fluid containing a liquid and the molybdenum sulfide powder which is dispersed in the liquid.

13. The photothermal conversion material according to claim 12 , wherein a main component of the liquid is water.

14. A distillation method comprising:
evaporating the liquid by irradiating the photothermal conversion material according to claim 12 with sunlight followed by heating.

15. An oxygen reduction catalyst comprising:
the molybdenum sulfide powder according to claim 1 .

16. A catalyst ink comprising:
the oxygen reduction catalyst according to claim 15 ;
a polyelectrolyte; and
a solvent.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Oki Hironobu
• Kano Yusuke
• Dohi Tomoki
• MIZUTA Seiji
• Tabuchi Minoru
• Yuan Jianjun
• Otsu Masato

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/10

  Infrared [IR] · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J2235/15

  X-ray diffraction · CPC title