Compression and separation device and compression process

Patent metadata

Field	Value
Publication number	US-12123418-B2
Application number	US-202017629434-A
Country	US
Kind code	B2
Filing date	Jul 20, 2020
Priority date	Jul 24, 2019
Publication date	Oct 22, 2024
Grant date	Oct 22, 2024

Abstract

In a compression process in a dynamic compressor having at least one first and one second compression stages, a first gas having a first molecular weight of less than 10 g/mol is compressed, at least one second fluid having a second molecular weight greater than 50 g/mol is mixed with the first gas to form a third gas to be compressed having a molecular weight greater than 10 g/mol, the third gas is sent to the first compression stage, the third gas is cooled in a first heat exchanger downstream of the first compression stage, where it is partially condensed, the partially condensed third gas is sent to a first phase separator to form a fourth gas having a lower molecular weight than the third gas and a first condensed liquid having a higher molecular weight than the third gas, the fourth gas is sent from the first phase separator to the second compression stage, the fourth gas compressed in the second compression stage is sent to cool in a second heat exchanger where it partially condenses, and the partially condensed fourth gas is sent to a second phase separator to produce a fifth gas having a lower molecular weight than the fourth gas.

First claim

The invention claimed is:

1. A compression and separation device, comprising a dynamic compressor having first and second compression stages for compressing a first gas having a first molecular weight less than 10 g/mol:
a. an inlet for the first gas;
b. means for mixing at least one second fluid having a second molecular weight greater than 50 g/mol with the first gas to form a third gas to be compressed having a molecular weight greater than 10 g/mol;
c. means for sending the third gas to the first compression stage, a first heat exchanger for cooling the third gas downstream of the first compression stage in order to partially condense it, a first phase separator, means for sending the partially condensed third gas to the first phase separator to form a fourth gas having a lower molecular weight than the third gas and a first condensed liquid having a higher molecular weight than the third gas;
d. means for sending the fourth gas from the first phase separator to the second compression stage, a second heat exchanger downstream of the second compression stage, means for sending the compressed fourth gas to the second compression stage and cooling it in the second heat exchanger in order to partially condense it, a second phase separator and means for sending the partially condensed fourth gas to the second phase separator to produce a fifth gas having a lower molecular weight than the fourth gas and a second condensed liquid having a higher molecular weight than the fourth gas; and
e. a separation device and means for sending the fifth gas or a gas derived from the fifth gas to the separation device to be separated therein to produce a gaseous product having a molecular weight of less than 10 g/mol, and a composition of less than 10 ppm of any component having a molecular weight greater than 50 g/mol.

2. The device as claimed in claim 1 , comprising means for recovering the first condensed liquid and/or the second condensed liquid, and further comprising means for mixing the first and/or second condensed liquid with the first gas.

3. The device as claimed in claim 2 , said means for recovering comprising a common reservoir.

4. The device as claimed in claim 2 , comprising means for at least partially vaporizing the first and/or second condensed liquid and means for at least partially recycling the vaporized portion as a second fluid.

5. The device as claimed in claim 1 , comprising means for using some of the heat generated by compression to vaporize the first and/or second condensed liquid.

6. The device as claimed in claim 1 , in which the first and/or second phase separator is not thermally insulated from the ambient air.

7. A compression process in a dynamic compressor having at least one first and one second compression stages, the process comprising the steps of:
compressing a first gas having a first molecular weight of less than 10 g/mol;
mixing at least one second fluid having a second molecular weight greater than 50 g/mol with the first gas to form a third gas to be compressed having a molecular weight greater than 10 g/mol;
sending the third gas to the first compression stage;
cooling the third gas in a first heat exchanger downstream of the first compression stage, where the third gas is partially condensed;
sending the partially condensed third gas to a first phase separator operating at a temperature greater than −50° C. to form a fourth gas having a lower molecular weight than the third gas and a first condensed liquid having a higher molecular weight than the third gas, the fourth gas is sent from the first phase separator to the second compression stage;
sending the fourth gas compressed in the second compression stage to cool in a second heat exchanger where it partially condenses; and
sending the partially condensed fourth gas to a second phase separator operating at a temperature greater than −50° C. to produce a fifth gas having a lower molecular weight than the fourth gas and a second condensed liquid having a higher molecular weight than the fourth gas.

8. The process as claimed in claim 7 , wherein the first condensed liquid and/or the second condensed liquid are recovered, optionally in a common reservoir, and the first and/or second condensed liquid is mixed with the first gas optionally after vaporization.

9. The process as claimed in claim 7 , wherein the first and/or second condensed liquid is at least partially vaporized and the vaporized portion is at least partially recycled as the second fluid.

10. The process as claimed in claim 7 , wherein the first gas is hydrogen.

11. A compression and separation process comprising a compression process as claimed in claim 7 , in which the fifth gas or a gas derived from the fifth gas is sent to a separation device to be separated therein to produce a gaseous product having a molecular weight of less than 10 g/mol, or even less than 7.5 g/mol, or even less than 5 g/mol, and a composition of less than 10 ppm, or even less than 5 ppm, or even less than 1 ppm of any component having a molecular weight greater than 50 g/mol.

12. The process as claimed in claim 11 , wherein the separation device also produces a gas having a molecular weight greater than 10 g/mol, or even greater than 7.5 g/mol, or even greater than 5 g/mol, and a composition of more than 10 ppm, or even more than 5 ppm, or even more than 1 ppm of any component having a molecular weight greater than 50 g/mol, and this gas is sent upstream of the compressor to be compressed therein with the first gas.

Assignees

• Air Liquide

Inventors

• Le Bot Patrick

Classifications

• B01D53/002

  by condensation · CPC title

• F04D29/705

  Adding liquids · CPC title

• F25J2230/30

  Compression of the feed stream · CPC title

• F25J2230/04

  Compressor cooling arrangement, e.g. inter- or after-stage cooling or condensate removal · CPC title

• F25J2210/04

  Mixing or blending of fluids with the feed stream · CPC title