Energy-efficient system and method for carbon dioxide conversion

Patent metadata

Field	Value
Publication number	US-12116284-B2
Application number	US-201917053577-A
Country	US
Kind code	B2
Filing date	May 29, 2019
Priority date	May 30, 2018
Publication date	Oct 15, 2024
Grant date	Oct 15, 2024

Abstract

A system and method for converting carbon dioxide are proposed. The system for converting carbon dioxide includes a carbon monoxide generator for generating carbon monoxide through a reverse water gas shift reaction and a hydrocarbon generator for producing a hydrocarbon through a Fischer-Tropsch synthesis reaction, whereby the carbon monoxide generator is packed both with a catalyst for the reverse water gas shift reaction and with a catalyst for the Fischer-Tropsch synthesis reaction, thus increasing the CO yield in the carbon monoxide generator even at a low temperature compared to when the catalyst for the reverse water gas shift reaction is used alone, ultimately increasing the hydrocarbon yield in the hydrocarbon generator. Moreover, the energy of the exothermic Fischer-Tropsch synthesis reaction can be used as the energy required for the endothermic reverse water gas shift reaction, thereby increasing energy efficiency and processing yield and thus reducing operation and maintenance costs.

First claim

What is claimed is:

1. A system for converting carbon dioxide, suitable for converting carbon dioxide using hydrogen, comprising:
a carbon monoxide generator comprising:
a case having an inlet, into which carbon dioxide and hydrogen are introduced, formed in one side and an outlet, from which a reaction product is discharged, formed in an opposite side,
a catalytic reactor disposed in an internal space of the case and packed with both a catalyst for a reverse water gas shift reaction and a catalyst for a Fischer-Tropsch synthesis reaction so that the reverse water gas shift reaction and the Fischer-Tropsch synthesis reaction are carried out together, thereby increasing a carbon monoxide yield and allowing reaction heat generated in the Fischer-Tropsch synthesis reaction to be used for the reverse water gas shift reaction,

a remover disposed downstream of the carbon monoxide generator and receiving the reaction product from the carbon monoxide generator to separate and remove at least one of H 2 O and a hydrocarbon from the reaction product; and
a hydrocarbon generator disposed downstream of the remover, packed with a catalyst for a further Fischer-Tropsch synthesis reaction, and receiving a gaseous material from the remover to carry out the further Fischer-Tropsch synthesis reaction to produce a high grade hydrocarbon.

2. The system of claim 1 , wherein the catalyst for the Fischer-Tropsch synthesis reaction that is charged in the carbon monoxide generator is a catalyst comprising Fe and further comprising at least one selected from among Cu, K, Co, Zn and Al.

3. The system of claim 1 , wherein the catalytic reactor of the carbon monoxide generator is configured such that a catalyst layer packed with the catalyst for the reverse water gas shift reaction and a catalyst layer packed with the catalyst for the Fischer-Tropsch synthesis reaction are repeatedly and alternately stacked one or more times, or such that the catalyst for the reverse water gas shift reaction and the catalyst for the Fischer-Tropsch synthesis reaction are uniformly mixed.

4. The system of claim 1 , wherein the catalytic reactor of the carbon monoxide generator is configured such that an internal space thereof is divided into at least two reaction zones by a partition wall or a reaction tube, and each of the reaction zones is packed with the catalyst for the reverse water gas shift reaction or the catalyst for the Fischer-Tropsch synthesis reaction, reaction zones adjacent to each other being packed with different catalysts.

5. The system of claim 1 , wherein the catalytic reactor of the carbon monoxide generator is configured such that an internal space thereof is divided into at least two reaction zones by a partition wall or a reaction tube, and a catalyst layer packed with the catalyst for the reverse water gas shift reaction and a catalyst layer packed with the catalyst for the Fischer-Tropsch synthesis reaction are repeatedly and alternately stacked one or more times in each of the reaction zones, catalyst layers located at a same height in reaction zones adjacent to each other being packed with different catalysts.

6. The system of claim 1 , wherein, in the catalytic reactor of the carbon monoxide generator, the catalyst for the Fischer-Tropsch synthesis reaction and the catalyst for the reverse water gas shift reaction are present at a mass ratio ranging from 1:99 to 99:1.

7. The system of claim 1 , wherein the catalyst for the reverse water gas shift reaction comprises at least one metal selected from the group consisting of Cu, Li, Rh, Mo, Pt, Ce and Pd.

8. A method of converting carbon dioxide, suitable for converting carbon dioxide using hydrogen, comprising:
generating carbon monoxide by introducing carbon dioxide and hydrogen into a reactor packed with both a catalyst for a reverse water gas shift reaction and a catalyst for a Fischer-Tropsch synthesis reaction,
separating and removing at least one of H 2 O and a hydrocarbon from a reaction product obtained in the generating the carbon monoxide; and
producing a hydrocarbon using a catalyst for a further Fischer-Tropsch synthesis reaction from a gaseous material obtained after the removing the at least one of H 2 O and the hydrocarbon.

9. The method of claim 8 , wherein the generating the carbon monoxide is performed at a reaction temperature of 300 to 475° C., and the producing the hydrocarbon is performed at a reaction temperature of 200 to 350° C.

10. The method of claim 8 , wherein the generating the carbon monoxide is performed using a reactor configured such that the catalyst for the reverse water gas shift reaction and the catalyst for the Fischer-Tropsch synthesis reaction are uniformly mixed, or using a reactor configured such that a catalyst layer for the reverse water gas shift reaction and a catalyst layer for the Fischer-Tropsch synthesis reaction are repeatedly and alternately stacked one or more times, the catalyst layers being arranged such that carbon dioxide and hydrogen introduced into the reactor first come into contact with the catalyst layer for the reverse water gas shift reaction,
wherein the catalyst for the reverse water gas shift reaction comprises at least one metal selected from the group consisting of Cu, Li, Rh, Mo, Pt, Ce and Pd, and
the catalyst for the Fischer-Tropsch synthesis reaction that is charged in the carbon monoxide generator is a catalyst comprising Fe and further comprising at least one selected from among Cu, K, Co, Zn and Al.

Assignees

• Korea Res Inst Chemical Tech

Inventors

• Kim Seok Ki
• Jun Ki Won
• Park Hae Gu
• Hwang Sun Mi

Classifications

• C07C9/04

  Methane (production by treatment of sewage C02F11/04; natural gas, synthetic natural gas C10L3/06) · CPC title

• C07C1/0485 Primary

  Set-up of reactors or accessories; Multi-step processes · CPC title

• B01J2231/641

  Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes · CPC title

• B01J23/78

  with alkali- or alkaline earth metals · CPC title

• B01J2208/00017

  Controlling the temperature · CPC title