Catalyst slurry mixing process and system

Patent metadata

Field	Value
Publication number	US-12115506-B2
Application number	US-202318236234-A
Country	US
Kind code	B2
Filing date	Aug 21, 2023
Priority date	Mar 26, 2020
Publication date	Oct 15, 2024
Grant date	Oct 15, 2024

Abstract

Disclosed are a process and system for preparing a catalyst slurry. The process can include preparing a catalyst slurry comprising a solid particulate catalyst and a carrier liquid in a catalyst slurry preparation system. The catalyst slurry preparation system can include a mixing vessel, a rotatable impeller system connected to the mixing vessel, and a motor connected to the rotatable impeller system. The rotatable impeller system can include an agitator shaft and a hub connected to the agitator shaft. The hub and at least a portion of the agitator shaft are positioned within the mixing vessel along a longitudinal axis of the mixing vessel, and the hub has at least three blades.

First claim

What is claimed is:

1. A process comprising:
preparing a first catalyst slurry comprising a solid particulate catalyst and a carrier liquid in a catalyst slurry preparation system,
wherein the catalyst slurry preparation system comprises:
a first mixing vessel,
a first rotatable impeller system connected to the first mixing vessel, and
a first motor connected to the first rotatable impeller system,

wherein the first rotatable impeller system comprises an agitator shaft and at least two hubs connected to the agitator shaft, wherein the at least two hubs and at least a portion of the agitator shaft are positioned within the first mixing vessel along a longitudinal axis of the first mixing vessel, and wherein each of the at least two hubs comprise at least two blades;
preparing a second catalyst slurry comprising the solid particulate catalyst and the carrier liquid in the catalyst slurry preparation system,
wherein the catalyst slurry preparation system further comprises:
a second mixing vessel,
a second rotatable impeller system connected to the second mixing vessel, and
a second motor connected to the second rotatable impeller system,

wherein the second rotatable impeller system comprises an agitator shaft and at least two hubs connected to the agitator shaft, wherein the at least two hubs and at least a portion of the agitator shaft are positioned within the second mixing vessel along a longitudinal axis of the second mixing vessel, wherein each of the at least two hubs comprise at least two blades,
wherein an outlet of the second mixing vessel is connected to an inlet of the first mixing vessel, and
wherein a first concentration of the solid particulate catalyst in the first catalyst slurry is about equal to or greater than a second concentration of the solid particulate catalyst in the second catalyst slurry.

2. The process of claim 1 , wherein the at least two hubs of the first rotatable impeller system, the at least two hubs of the second rotatable impeller system, or both each comprise 3 or 4 blades.

3. The process of claim 2 , wherein the blades of the at least two hubs of the first rotatable impeller system, the blades of the at least two hubs of the second rotatable impeller system, or both are configured such that a top side or a bottom side of one or more of the at least two hubs is concave.

4. The process of claim 2 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a third hub connected to the agitator shaft, wherein the third hub comprises two, three, or four blades.

5. The process of claim 3 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a third hub connected to the agitator shaft, wherein the third hub comprises two, three, or four blades, and wherein the blades of the third hub of the first rotatable impeller system, the blades of the third hub of the second rotatable impeller system, or both are configured such that a top side or a bottom side of the third hub is concave.

6. The process of claim 1 , further comprising:
feeding the first catalyst slurry from the mixing vessel of the catalyst slurry preparation system to a polymerization reactor; and
contacting one or more olefins with the first catalyst slurry under polymerization conditions in the polymerization reactor,
wherein the solid particulate catalyst comprises a chromium-containing catalyst, a Ziegler-Natta catalyst, or a metallocene catalyst.

7. The process of claim 1 , wherein the second mixing vessel holds a volume of catalyst slurry four to eight times the volume of catalyst slurry held by the first mixing vessel.

8. A process comprising:
preparing a first catalyst slurry comprising a solid particulate catalyst and a carrier liquid in a catalyst slurry preparation system,
wherein the catalyst slurry preparation system comprises:
a first mixing vessel,
a first rotatable impeller system connected to the first mixing vessel, and
a first motor connected to the first rotatable impeller system,

wherein the first rotatable impeller system comprises an agitator shaft and at least one hub connected to the agitator shaft, wherein the at least one hub and at least a portion of the agitator shaft are positioned within the first mixing vessel along a longitudinal axis of the first mixing vessel, and wherein the at least one hub comprises at least two blades;
preparing a second catalyst slurry comprising the solid particulate catalyst and the carrier liquid in the catalyst slurry preparation system,
wherein the catalyst slurry preparation system further comprises:
a second mixing vessel,
a second rotatable impeller system connected to the second mixing vessel, and
a second motor connected to the second rotatable impeller system,

wherein the second rotatable impeller system comprises an agitator shaft and at least one hub connected to the agitator shaft, wherein the at least one hub and at least a portion of the agitator shaft are positioned within the second mixing vessel along a longitudinal axis of the second mixing vessel, wherein the at least one hub comprises at least two blades,
wherein an outlet of the second mixing vessel is connected to an inlet of the first mixing vessel,
wherein a first concentration of the solid particulate catalyst in the first catalyst slurry is about equal to a second concentration of the solid particulate catalyst in the second catalyst slurry, and
wherein the second concentration of the solid particulate catalyst in the second catalyst slurry is equal to or less than about 20 wt % based on a total weight of the second catalyst slurry.

9. The process of claim 8 , wherein the at least one hub of the first rotatable impeller system, the at least one hub of the second rotatable impeller system, or both have 3 or 4 blades.

10. The process of claim 8 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a second hub connected to the agitator shaft, wherein the second hub comprises at least two blades.

11. The process of claim 9 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a second hub connected to the agitator shaft, wherein the second hub comprises three or four blades.

12. The process of claim 9 , wherein the blades of the at least one hub of the first rotatable impeller system, the blades of the at least one hub of the second rotatable impeller system, or both are configured such that a top side or a bottom side of the at least one hub is concave.

13. The process of claim 11 , wherein the blades of the second hub of the first rotatable impeller system, the blades of the second hub of the second rotatable impeller system, or both are configured such that a top side or a bottom side of the second hub is concave.

14. The process of claim 11 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a third hub connected to the agitator shaft, wherein the second hub comprises two, three, or four blades.

15. The process of claim 13 , wherein the first rotatable impeller system, the second rotatable impeller system, or both further comprises a third hub connected to the agitator shaft, wherein the second hub comprises two, three, or four blades, and wherein the blades of the third hub of the first rotatable impeller system, the blades of the third hub of the second rotatable impeller system, or both are configured such that a top side or a bottom side of the third hub is concave.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• Hein James E
• Kufeld Scott E

Classifications

• C08F2/00

  Processes of polymerisation · CPC title

• C08F4/78

  selected from chromium, molybdenum or tungsten · CPC title

• B01J8/0015

  Feeding of the particles in the reactor; Evacuation of the particles out of the reactor · CPC title

• B01F23/565

  by introducing liquids in solid material, e.g. to obtain slurries · CPC title

• B01F23/024

  Maintaining mixed ingredients in movement to prevent separation of the ingredients after mixing · CPC title