Recording medium, information recording method, information reading method, and composition for producing recording layer

Patent metadata

Field	Value
Publication number	US-12112780-B2
Application number	US-202318506171-A
Country	US
Kind code	B2
Filing date	Nov 10, 2023
Priority date	Jun 4, 2021
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

A recording medium includes a recording layer. The recording layer includes an aliphatic polymer, and a multiphoton absorption compound containing at least one bond selected from the group consisting of a carbon-carbon double bond, a carbon-nitrogen double bond, and a carbon-carbon triple bond, and having a multiphoton absorption characteristic. When the thickness of the recording layer is 100 μm, the transmittance of the recording layer in the thickness direction with respect to light having a wavelength of 405 nm is greater than or equal to 80%.

First claim

What is claimed is:

1. A recording medium comprising:
at least one recording layer, wherein
the at least one recording layer comprises:
an aliphatic polymer; and
a multiphoton absorption compound containing at least one bond selected from the group consisting of a carbon-carbon double bond, a carbon-nitrogen double bond, and a carbon-carbon triple bond, and having a multiphoton absorption characteristic; and

when a thickness of the at least one recording layer is 100 μm, a transmittance of the at least one recording layer in a thickness direction with respect to light having a wavelength of 405 nm is greater than or equal to 80%.

2. The recording medium according to claim 1 , wherein
a total of a content of the aliphatic polymer and a content of the multiphoton absorption compound in the at least one recording layer is greater than or equal to 95 wt %.

3. The recording medium according to claim 1 , wherein
the aliphatic polymer includes a structural unit derived from an aliphatic monomer, and
the aliphatic monomer contains at least one group selected from the group consisting of an acrylic group, a methacrylic group, an epoxy group, an oxetanyl group, and a vinyl group.

4. The recording medium according to claim 3 , wherein
the aliphatic monomer contains at least one group selected from the group consisting of an acrylic group, a methacrylic group, and an epoxy group.

5. The recording medium according to claim 3 , wherein
the aliphatic monomer comprises at least one compound selected from the group consisting of at least one compound A represented by formula (A) below, at least one compound B represented by formula (B) below, a compound C represented by formula (C) below, a compound D represented by formula (D) below, at least one compound E represented by formula (E) below, a compound F represented by formula (F) below, and a compound G represented by formula (G) below:

in the formula (A), R 1 is a hydrogen atom or a methyl group, and R 2 is an aliphatic group,
in the formula (B), R 3 and R 5 are each independently a hydrogen atom or a methyl group, and R 4 is an aliphatic group,
in the formula (C), R 6 is a hydrogen atom or a methyl group, R 7 is an aliphatic group, and R 8 is a hydrogen atom or an aliphatic group,
in the formula (D), R 9 is a hydrogen atom or a methyl group, R 10 is an aliphatic group, and R 11 is a hydrogen atom or an aliphatic group,
in the formula (E), R 12 and R 14 are each independently a hydrogen atom or an aliphatic group, and R 13 is an aliphatic group,
in the formula (F), R 15 and R 17 are each independently a hydrogen atom or an aliphatic group, and R 16 is an aliphatic group, and
in the formula (G), R 18 and R 20 are each independently a hydrogen atom or an aliphatic group, and R 19 is an aliphatic group.

6. The recording medium according to claim 5 , wherein
the at least one compound A includes at least one compound selected from the group consisting of a compound A1 represented by formula (A1) below and a compound A2 represented by formula (A2) below:

in the formula (A1), n is an integer greater than or equal to 0 and less than or equal to 11.

7. The recording medium according to claim 5 , wherein
the at least one compound B includes a compound B1 represented by formula (B1) below:

in the formula (B1), m is an integer greater than or equal to 1 and less than or equal to 4.

8. The recording medium according to claim 5 , wherein
the at least one compound E includes at least one compound selected from the group consisting of a compound E1 represented by formula (E1) below, a compound E2 represented by formula (E2) below, and a compound E3 represented by formula (E3) below:

in the formula (E1), x is an integer greater than or equal to 1 and less than or equal to 12, and
in the formula (E3), y is an integer greater than or equal to 1 and less than or equal to 11.

9. The recording medium according to claim 1 , wherein
the multiphoton absorption compound contains an aromatic ring.

10. The recording medium according to claim 1 , wherein
the recording medium further comprises dielectric layers,
the at least one recording layer comprises recording layers, and
the recording layers and the dielectric layers are arranged alternately.

11. The recording medium according to claim 1 , wherein
information is recorded using light having a wavelength greater than or equal to 390 nm and less than or equal to 420 nm.

12. An information recording method comprising:
providing a light source that emits light having a wavelength greater than or equal to 390 nm and less than or equal to 420 nm; and
focusing the light from the light source and applying the light to the at least one recording layer in the recording medium according to claim 1 .

13. An information reading method for reading information recorded by the information recording method according to claim 12 , the information reading method comprising:
measuring an optical characteristic of the at least one recording layer by applying light to the at least one recording layer; and
reading the information from the at least one recording layer.

14. A composition for producing a recording layer having a transmittance greater than or equal to 80% in a thickness direction with respect to light having a wavelength of 405 nm when a thickness of the recording layer is 100 μm, the composition comprising:
an aliphatic monomer; and
a multiphoton absorption compound containing at least one bond selected from the group consisting of a carbon-carbon double bond, a carbon-nitrogen double bond, and a carbon-carbon triple bond, and having a multiphoton absorption characteristic.

Assignees

• Panasonic Ip Man Co Ltd

Inventors

• Ando Kota
• Yokoyama Masako
• Sakata Naoya
• Tagashira Kenji
• Arase Hidekazu

Classifications

• G11B7/2533

  comprising resins · CPC title

• C09B69/109

  containing other specific dyes · CPC title

• G11B7/246

  containing dyes · CPC title

• G11B2007/24606

  Azo- dyes · CPC title

• G11B7/24035

  Recording layers (substrates also used as recording layers G11B7/24047) · CPC title