Adhesive composition and preparation method therefor

Patent metadata

Field	Value
Publication number	US-12110431-B2
Application number	US-201917254018-A
Country	US
Kind code	B2
Filing date	Aug 30, 2019
Priority date	Aug 31, 2018
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

Provided is an adhesive composition including lysine, malic acid, and water, wherein the lysine and the malic acid are present in the form of an aqueous salt solution and do not form precipitates in the aqueous solution.

First claim

What is claimed is:

1. An adhesive composition comprising:
lysine, malic acid, and water,
wherein the lysine and the malic acid are present in the form of an aqueous salt solution and do not form precipitates in the adhesive composition,
wherein the mixing molar ratio of the lysine to the malic acid is in the range of 1:1.3 to 1:3.

2. The adhesive composition of claim 1 , wherein the precipitates are precipitates of lysine and malic acid.

3. The adhesive composition of claim 1 , wherein a mixing molar ratio of the lysine to the malic acid is adjusted such that precipitates of lysine and malic acid do not form in the adhesive composition.

4. The adhesive composition of claim 3 , wherein the mixing molar ratio of the lysine to the malic acid is in the range of 1:1.5 to 1:3.

5. The adhesive composition of claim 1 , wherein a solid content in the adhesive composition is 70 parts by weight or less based on a total weight of the adhesive composition.

6. The adhesive composition of claim 1 , wherein the sum of the respective contents of the lysine and the malic acid is in the range of 60 parts by weight to 100 parts by weight based on 100 parts by weight of the solid content in the adhesive composition.

7. The adhesive composition of claim 1 , further comprising at least one solvent selected from a primary alcohol, a polyhydric alcohol, a diol, and a triol.

8. The adhesive composition of claim 7 , wherein the solvent comprises: at least one monohydric alcohol selected from methanol, ethanol, butane-1-ol, pentane-1-ol, and hexadecane-1-ol; at least one polyhydric alcohol selected from ethane-1,2-diol, propane-1,2-diol, propane-1,2,3-triol, butane-1,3-diol, butane-1,2,3,4-tetraol, pentane-1,2,3,4,5-pentol, hexane-1,2,3,4,5,6-hexol, and heptane-1,2,3,4,5,6,7-heptol; at least one unsaturated aliphatic alcohol selected from prop-2-en-1-ol, 3,7-dimethylocta-2,6-dien-1-ol, and prop-2-yn-1-ol; at least one alicyclic alcohol selected from cyclohexane-1,2,3,4,5,6-hexol and 2-(2-propyl)-5-methylcyclohexane-1-ol; or a mixture thereof.

9. The adhesive composition of claim 1 , wherein precipitates do not form in the adhesive composition when the adhesive composition is stored at a temperature of −18° C. or higher than and less than 80° C. for 14 days or longer.

10. The adhesive composition of claim 1 , wherein a solid content in the adhesive composition is 0.1 part by weight to 63 parts by weight based on a total weight of the adhesive composition.

11. A method of preparing an adhesive composition, the method comprising:
mixing lysine, malic acid, and water to prepare a mixture; and
stirring the mixture at a temperature of less than 80° C.,
wherein the respective contents of the lysine, the malic acid, and the water are adjusted such that precipitates of lysine and malic acid do not form in the adhesive composition, and a mixing molar ratio of the lysine to the malic acid in the range of 1:1.3 to 1:3.

12. The method of claim 11 , wherein the mixture further comprises at least one solvent selected from a primary alcohol, a polyhydric alcohol, a diol, and a triol.

13. An adhesive product comprising the adhesive composition of claim 1 .

Assignees

• Cj Cheiljedang Corp

Inventors

• Hwang Ji Ho
• Yang Young Lyeol
• Oh Chang Yub
• Lee Chang Suk
• Na Kyung Su
• Moon Jun Ok

Classifications

• C09J7/255

  Polyesters · CPC title

• C09J11/06

  organic · CPC title

• C09J7/20

  characterised by their carriers · CPC title

• C09J4/00 Primary

  Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16} · CPC title

• C09J9/00 Primary

  Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks (C09J7/00 takes precedence) · CPC title