Aqueous polymer dispersion and process of making the same

Patent metadata

Field	Value
Publication number	US-12110394-B2
Application number	US-201917611696-A
Country	US
Kind code	B2
Filing date	Jun 13, 2019
Priority date	Jun 13, 2019
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

An aqueous dispersion comprising a multistage polymer comprising a first polymer and a second polymer that comprises structural units of an ethylenically unsaturated siloxane monomer, the multistage polymer comprising, by weight based on the weight of the multistage polymer, 4.5% or more of structural units of the ethylenically unsaturated siloxane monomer, and the coagulum content of the aqueous dispersion is less than 2,000 ppm after filtration through a 44 micron sieve.

First claim

What is claimed is:

1. An aqueous dispersion comprising a multistage polymer, wherein the multistage polymer comprises at least a first polymer and a second polymer,
wherein the second polymer comprises structural units of an ethylenically unsaturated siloxane monomer of formula (I), (II), or (III),

wherein, in formula (I), R is an ethylenically unsaturated group, and j and k are each independently in the range of from 0 to 100, and j+k=5 to 100;

wherein, in formula (II), R is an ethylenically unsaturated group, R 1 is a hydroxyl, alkyl, aryl, alkoxyl, aryloxy, alkyl ether, or aryl ether group, and m is from 1 to 100;

wherein, in formula (III), R is an ethylenically unsaturated group, R 1 and R 2 are each independently a hydroxyl, alkyl, aryl, alkoxyl, aryloxy, alkyl ether, or aryl ether group, n is from 1 to 5, and p is from 1 to 100;
wherein the multistage polymer comprises, by weight based on the weight of the multistage polymer, 4.5% or more of structural units of the ethylenically unsaturated siloxane monomer; and
wherein the coagulum content of the aqueous dispersion is less than 2,000 ppm after filtration through a 44 micron sieve.

2. The aqueous dispersion of claim 1 , wherein the second polymer comprises, by weight based on the weight of the second polymer, 5% or more of structural units of the ethylenically unsaturated siloxane monomer.

3. The aqueous dispersion of claim 1 , wherein the ethylenically unsaturated siloxane monomer has the structure represented by formula (I), wherein R is —CH═CH 2 , —R p —OC(═O)CH═CH 2 , or —R p —OC(═O)C(CH 3 )═CH 2 , where R p is a C 1 -C 6 bivalent hydrocarbon group, and j+k is in the range of from 5 to 50.

4. The aqueous dispersion of claim 1 , wherein the multistage polymer has a weight average molecular weight of 50,000 g/mol or more.

5. The aqueous dispersion of claim 1 , wherein the weight ratio of the first polymer to the second polymer is from 95:5 to 10:90.

6. The aqueous dispersion of claim 1 , wherein the second polymer further comprises structural units of an additional ethylenically unsaturated nonionic monomer, and optionally structural units of an ethylenically unsaturated functional monomer carrying at least one functional group selected from an amide, ureido, carboxyl, carboxylic anhydride, hydroxyl, or sulfonic acid group, a salt thereof, or mixtures thereof.

7. The aqueous dispersion of claim 1 , wherein the multistage polymer comprises, by weight based on the weight of the multistage polymer, from 4.8% to 40% of structural units of the ethylenically unsaturated siloxane monomer.

8. The aqueous dispersion of claim 1 , wherein the first polymer comprises structural units of an ethylenically unsaturated functional monomer carrying at least one functional group selected from an amide, ureido, carboxyl, carboxylic anhydride, hydroxyl, or sulfonic acid group, a salt thereof, or mixtures thereof; and structural units of an additional ethylenically unsaturated nonionic monomer.

9. The aqueous dispersion of claim 1 , wherein the first polymer comprises, by weight based on the weight of the first polymer, less than 5% of structural units of the ethylenically unsaturated siloxane monomer.

10. A process for preparing the aqueous dispersion comprising a multistage polymer of claim 1 , comprising:
preparing a first polymer by emulsion polymerization;
dispersing in the first polymer, a second monomer composition comprising an ethylenically unsaturated siloxane monomer, whereby the second monomer composition swells the first polymer, and
polymerizing the second monomer composition within the monomer-swollen first polymer to form a second polymer, thus to obtain the aqueous dispersion with a coagulum content of less than 2,000 ppm after filtration through a 44 micron sieve;
wherein the multistage polymer comprising the first polymer and the second polymer comprises, by weight based on the weight of the multistage polymer, 4.5% or more of structural units of the ethylenically unsaturated siloxane monomer; and
wherein the ethylenically unsaturated siloxane monomer has formula (I), (II), or (III),

wherein, in formula (I), R is an ethylenically unsaturated group, and j and k are each independently in the range of from 0 to 100, and j+k=5 to 100;

wherein, in formula (II), R is an ethylenically unsaturated group, R 1 is a hydroxyl, alkyl, aryl, alkoxyl, aryloxy, alkyl ether, or aryl ether group, and m is from 1 to 100;

wherein, in formula (III), R is an ethylenically unsaturated group, R 1 and R 2 are each independently a hydroxyl, alkyl, aryl, alkoxyl, aryloxy, alkyl ether, or aryl ether group, n is from 1 to 5, and p is from 1 to 100.

11. The process of preparing the aqueous dispersion of claim 10 , wherein the second monomer composition is emulsified and homogenized prior to dispersing in the first polymer.

12. An aqueous coating composition comprising the aqueous dispersion of claim 1 .

Assignees

• Dow Global Technologies Llc
• Rohm & Haas
• Dow Silicones Corp

Inventors

• Dong Xiangting
• Li Ling
• Liu Zhihua
• Liu Hui
• Cui Wei
• Zheng Baoqing
• Gong Zhi Juan
• Wu Yan
• Piao Changkun
• Tang Jia
• Yun Dong

Classifications

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• C08L2201/50

  Aqueous dispersion, e.g. containing polymers with a glass transition temperature (Tg) above 20°C · CPC title

• C08G2150/00

  Compositions for coatings · CPC title

• C08G77/20

  containing silicon bound to unsaturated aliphatic groups · CPC title

• C08G77/16

  to hydroxy groups · CPC title