Method for the combined processing of at least two polymer melts

Patent metadata

Field	Value
Publication number	US-12110369-B2
Application number	US-202017434140-A
Country	US
Kind code	B2
Filing date	Mar 5, 2020
Priority date	Mar 19, 2019
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

The invention relates to a method for the combined processing of at least two polymer melts selected from the group consisting of (M1), (M2) and (M3), wherein (M1) is a polymer melt comprising a terephthalate polyester (A1), (M2) is a polymer melt comprising a copolyester (A2) on the basis of terephthalic acid, at least one aliphatic, ω-dicarboxylic acid and at least one aliphatic 1,ω-diol, and (M3) is a polymer melt 0 comprising a copolyester (A3) on the basis of terephthalic acid, at least one polytetramethylene glycol and at least one aliphatic 1,ω-diol. The method comprises the alternating processing of the at least two polymer melts into at least one product selected from the group consisting of pellets (P1), fibers (P2), expanded particles (P3), preforms (P4) and articles (P5).

First claim

The invention claimed is:

1. A method for a combined processing of at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ), and (M 3 ), wherein
(M 1 ) is a polymer melt comprising a terephthalate polyester (A 1 ),
(M 2 ) is a polymer melt comprising a copolyester (A 2 ) on the basis of terephthalic acid, at least one aliphatic 1,ω-dicarboxylic acid, and at least one aliphatic 1,ω-diol, and
(M 3 ) is a polymer melt comprising a copolyester (A 3 ) on the basis of terephthalic acid, at least one polytetramethylene glycol and at least one aliphatic 1,ω-diol,
the method comprising alternating processing of the at least two polymer melts into at least one product selected from the group consisting of pellets (P 1 ), fibres (P 2 ), expanded particles (P 3 ), preforms (P 4 ), and articles (P 5 ).

2. The method according to claim 1 , wherein at least one polymer melt of the at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ), and (M 3 ) is processed into pellets (P 1 ), wherein the processing into pellets (P 1 ) comprises:
a) supplying the at least one polymer melt to a device (D 1 ), wherein the device (D 1 ) comprises a perforated disk (PD),
b) pressing the at least one polymer melt through the perforated disk (PD) into a pelletizing chamber (PC), wherein the pelletizing chamber (PC) comprises a cutting device (CD),
c) using the cutting device (CD) to comminute the at least one polymer melt pressed through the perforated disk (PD) into individual pellets (P 1 ),
d) removing the pellets (P 1 ) from the pelletizing chamber (PC).

3. The method according to claim 1 , wherein at least one polymer melt of the at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ) and (M 3 ) is processed into fibres (P 2 ), wherein the processing into fibres (P 2 ) comprises:
a) supplying the at least one polymer melt to a device (D 2 ), wherein the device (D 2 ) comprises at least one spinning nozzle (SN),
b) extruding the at least one polymer melt through the at least one spinning nozzle (SN) in the device (D 2 ), wherein fibres (P 2 ) are obtained,
c) removing the fibres (P 2 ) from the device (D 2 ).

4. The method according to claim 1 , wherein the at least one aliphatic 1,ω-dicarboxylic acid is selected from the group consisting of succinic acid, adipic acid, and sebacic acid.

5. The method according to claim 1 , wherein the at least one aliphatic 1,ω-diol is selected from the group consisting of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and diethylene glycol.

6. The method according to claim 1 , wherein at least one polymer melt of the at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ) and (M 3 ) is processed into expanded particles (P 3 ), wherein the processing into expanded particles (P 3 ) comprises:
a) supplying the at least one polymer melt to a device (D 3 ), wherein the device (D 3 ) comprises a perforated disk (PD 2 ),
b) adding at least one blowing agent (BL) to the at least one polymer melt in the device (D 3 ),
c) mixing the at least one polymer melt and the at least one blowing agent (BL) in the device (D 3 ), wherein a mixture (M 1 ) is obtained,
d) pressing the mixture (M 1 ) through the perforated disk (PD 2 ) into a pelletizing chamber (PC 2 ), wherein the pelletizing chamber (PC 2 ) comprises a cutting device (CD 2 ),
e) using the cutting device (CD 2 ) to comminute the mixture (M 1 ) pressed through the perforated disk (PD 2 ) into individual expanded particles (P 3 ),
f) removing the expanded particles (P 3 ) from the pelletizing chamber (PC 2 ).

7. The method according to claim 1 , wherein at least one polymer melt of the at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ) and (M 3 ) is processed into preforms (P 4 ), wherein the processing into preforms (P 4 ) comprises:
a) supplying the at least one polymer melt in at least one mould cavity (D 4 ),
b) permitting the at least one polymer melt to cool in the at least one mould cavity (D 4 ), wherein at least one preform (P 4 ) is obtained,
c) removing the at least one preform (P 4 ) from the at least one mould cavity (D 4 ).

8. The method according to claim 1 , wherein the terephthalate polyester (A 1 ) is the polycondensation product of
i) 100 mol %, based on component i), of terephthalic acid, and
ii) 100 to 104 mol %, based on component i), of at least one aliphatic 1,ω-diol.

9. The method according to claim 1 , wherein the copolyester (A 2 ) is the polycondensation product of
i) 30 to 60 mol %, based on components i) to ii), of terephthalic acid,
ii) 40 to 70 mol %, based on components i) to ii), of at least one aliphatic 1,ω-dicarboxylic acid, and
iii) 100 to 106 mol %, based on components i) to ii), of at least one aliphatic 1,ω-diol.

10. The method according to claim 1 , wherein the copolyester (A 3 ) is the polycondensation product of
i) 100 mol %, based on component i), of terephthalic acid,
ii) 30 to 74 mol %, based on component i), of at least one polytetramethylene glycol, and
iii) 30 to 74 mol %, based on component i), of at least one aliphatic 1,ω-diol,
wherein the sum of components ii) and iii) is in the range from 100 to 104 mol %.

11. The method according to claim 1 , wherein at least one polymer melt of the at least two polymer melts selected from the group consisting of (M 1 ), (M 2 ) and (M 3 ) is processed into articles (P 5 ), wherein the processing into articles (P 5 ) is carried out by blow moulding, injection moulding, or extrusion.

12. The method according to claim 1 , wherein the pellets (P 1 ) have an average diameter of from 0.05 mm to 20 mm.

13. The method according to claim 1 , wherein the fibres (P 2 ) are spun into a yarn.

14. The method according to claim 1 , wherein the expanded particles (P 3 ) are further processed into foam mouldings.

Assignees

• Basf Se

Inventors

• Heitz Thomas
• Brand Johann Diedrich
• Erbes Joerg

Classifications

• D01F6/78

  from copolycondensation products · CPC title

• D01D5/08

  Melt spinning methods {(D01D5/0023 takes precedence)} · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2203/30

  used for thermoforming · CPC title