Method for producing carboxyl-group-containing nitrile rubber
US-2020031955-A1 · Jan 30, 2020 · US
US12110348B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12110348-B2 |
| Application number | US-201917419166-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 25, 2019 |
| Priority date | Dec 28, 2018 |
| Publication date | Oct 8, 2024 |
| Grant date | Oct 8, 2024 |
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A carboxyl group-containing nitrile rubber having an iodine value of 120 or less, wherein the content of sodium is 1500 ppm by weight or less, the total content of calcium, magnesium, and aluminum is 350 ppm by weight or less, and the storage elastic modulus at 140° C. is 350 kPa or more.
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The invention claimed is: 1. A carboxyl group-containing nitrile rubber having an iodine value of 120 or less, wherein the carboxyl group-containing nitrile rubber does not contain a polymer flocculant, a content of sodium is 1500 ppm by weight or less, a total content of calcium, magnesium, and aluminum is 350 ppm by weight or less, and a storage elastic modulus at 140° C. is 350 kPa or more. 2. The carboxyl group-containing nitrile rubber according to claim 1 , wherein a methyl ethyl ketone insoluble content is 40 w % or less. 3. The carboxyl group-containing nitrile rubber according to claim 1 , wherein the content of sodium is 10 ppm by weight or more. 4. The carboxyl group-containing nitrile rubber according to claim 1 , wherein the total content of calcium, magnesium, and aluminum is 1.5 ppm by weight or more. 5. The carboxyl group-containing nitrile rubber according to claim 1 comprising an α,ß-ethylenically unsaturated nitrile monomer unit and an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit. 6. The carboxyl group-containing nitrile rubber according to claim 5 comprising the α,β-ethylenically unsaturated nitrile monomer unit, the α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, a conjugated diene monomer unit which includes a saturated unit thereof, and an α,β-ethylenically unsaturated monocarboxylic acid ester monomer unit. 7. A rubber composition obtained by blending a cross-linking agent with the carboxyl group-containing nitrile rubber according to claim 1 . 8. A cross-linked rubber obtained by cross-linking the rubber composition according to claim 7 .
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