Expanded graphite and preparation method therefor

Patent metadata

Field	Value
Publication number	US-12110231-B2
Application number	US-202218289488-A
Country	US
Kind code	B2
Filing date	Aug 31, 2022
Priority date	Dec 16, 2021
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

A preparation method comprises the following steps: (1) in a protective atmosphere, mixing a graphite powder with a metal peroxide and/or alkali metal superoxide, and leaving same to stand to obtain a mixed graphite-metal peroxide and/or graphite-alkali metal superoxide composite material; (2) putting the composite material prepared in step (1) into a liquid medium, which can react with the metal peroxide and/or the alkali metal superoxide, for a reaction to obtain intercalated graphite; and (3) heating the intercalated graphite prepared in step (2) to prepare the expanded graphite. The preparation method can effectively avoid the generation of harmful impurities such as sulfur and sulfides during the preparation process of the expanded graphite, thereby reducing environmental pollution.

First claim

The invention claimed is:

1. A preparation method for an expanded graphite, comprising the following steps:
(1) mixing a graphite powder with a metal peroxide and/or an alkali metal superoxide under a protective atmosphere, and leaving the mixture to stand still, to obtain a mixed graphite-metal peroxide and/or graphite-alkali metal superoxide composite material;
(2) putting the composite material prepared in step (1) into a liquid medium capable of reacting with the metal peroxide and/or the alkali metal superoxide for reacting, to obtain an intercalated graphite; and
(3) heating the intercalated graphite prepared in step (2) to prepare the expanded graphite,
wherein the metal peroxide is at least one of CaO 2 , K 2 O 2 , Na 2 O 2 and Li 2 O 2 ;
the alkali metal superoxide is at least one of KO 2 and NaO 2 ; and
a mass ratio of the graphite powder to the metal peroxide and/or the alkali metal superoxide in step (1) is (1 to 20):1.

2. The preparation method for the expanded graphite according to claim 1 , characterized in that, a time for leaving the mixture to stand still in step (1) is 12 hours to 24 hours.

3. The preparation method for the expanded graphite according to claim 1 , characterized in that, a temperature for the heating in step (3) is 1,000° C. to 1,500° C., and a time for the heating is 15 seconds to 30 seconds.

4. The preparation method for the expanded graphite according to claim 1 , characterized in that, the liquid medium is at least one of water, formic acid, acetic acid, propionic acid, hydrochloric acid, carbonic acid, citric acid, hydrofluoric acid, malic acid, gluconic acid, lactic acid, benzoic acid, acrylic acid, stearic acid, hydrosulphuric acid, hypochlorous acid and boric acid.

5. The preparation method for the expanded graphite according to claim 1 , characterized in that, a particle size of the graphite powder ranges from 80 meshes to 100 meshes.

6. The preparation method for the expanded graphite according to claim 1 , characterized in that, the graphite powder is obtained by washing, drying and sieving the leached residue of a waste lithium ion battery.

7. The preparation method for the expanded graphite according to claim 2 , characterized in that, the graphite powder is obtained by washing, drying and sieving the leached residue of a waste lithium ion battery.

8. The preparation method for the expanded graphite according to claim 3 , characterized in that, the graphite powder is obtained by washing, drying and sieving the leached residue of a waste lithium ion battery.

9. The preparation method for the expanded graphite according to claim 4 , characterized in that, the graphite powder is obtained by washing, drying and sieving the leached residue of a waste lithium ion battery.

10. The preparation method for the expanded graphite according to claim 5 , characterized in that, the graphite powder is obtained by washing, drying and sieving the leached residue of a waste lithium ion battery.

Assignees

• Guangdong Brunp Recycling Technology Co Ltd
• Hunan Brunp Recycling Tech Co Ltd
• Yichang Brunp Recycling Tech Co Ltd

Inventors

• Zhang Linshao
• Li Changdong
• Ruan Dingshan
• Zhou You
• Li Qiang
• Cai Yong

Classifications

• H01M10/54

  Reclaiming serviceable parts of waste accumulators · CPC title

• C01B32/225 Primary

  Expansion; Exfoliation · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• Y02W30/84

  Recycling of batteries or fuel cells · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title