Light reflecting material, reflecting layer and preparation method therefor

Patent metadata

Field	Value
Publication number	US-12105307-B2
Application number	US-201917279975-A
Country	US
Kind code	B2
Filing date	Aug 14, 2019
Priority date	Sep 25, 2018
Publication date	Oct 1, 2024
Grant date	Oct 1, 2024

Abstract

A light reflecting material, a reflecting layer and a preparation method therefor; the light reflecting material comprises glass powder particles (1), diffuse reflection particles, ultra-fine nano particles and an organic carrier; the particle size of the glass powder particles (1) is ≤5 μm, the particle size of the diffuse reflection particles is 0.1 μm to 0.2 μm, and the particle size of the ultra-fine nano particles is 0.01 μm to 0.05 μm. The glass powder particles (1), diffuse reflection particles and ultra-fine nano particles the particle sizes of which decrease progressively in sequence by one order of magnitude are used as the raw materials of the reflecting layer, without deceasing the adhesion between the reflecting layer and a substrate, the surface area within the reflecting layer that may cause reflection or refraction is increased to obtain better reflectivity.

First claim

What is claimed is:

1. A light reflecting material, comprising glass powder particles, diffuser particles, ultrafine nano particles, and an organic carrier, wherein a particle size of the glass powder particles is ≤5 μm, a particle size of the diffuser particles is 0.1 μm-0.2 μm, and a particle size of the ultrafine nano particles is 0.01 μm-0.05 μm.

2. The light reflecting material according to claim 1 , wherein the diffuser particles are TiO 2 , the ultrafine nano particles are second Al 2 O 3 , and the glass powder particles are selected from the group consisting of silicate glass, lead silicate glass, aluminoborosilicate glass, aluminate glass, soda-lime glass, quartz glass, and combinations thereof.

3. The light reflecting material according to claim 2 , wherein a mass ratio of the diffuser particles, the ultrafine nano particles and the glass powder particles is (1 to 6):(0.3 to 8):(1 to 5).

4. The light reflecting material according to claim 2 , wherein the diffuser particles further comprise first Al 2 O 3 , and a mass ratio of the TiO 2 to the first Al 2 O 3 is (1 to 6):(0 to 4).

5. The light reflecting material according to claim 4 , wherein a mass ratio of the first Al 2 O 3 to the second Al 2 O 3 is (0 to 4):1.

6. The light reflecting material according to claim 4 , wherein a mass ratio of the TiO 2 , the first Al 2 O 3 , the second Al 2 O 3 and the glass powder particles is 3:2:1:4.

7. A reflecting layer, comprising ultrafine nano particles, diffuser particles and a glass phase having a reticulated structure, wherein the diffuser particles are attached to a surface of the reticulated structure formed by the glass phase, and the ultrafine nano particles are at least partially distributed on the surface of the reticulated structure formed by the glass phase or on a surface of the diffuser particles or in clearances of the reticulated structure.

8. The reflecting layer according to claim 7 , wherein at least part of the ultrafine nano particles are distributed in the clearances of the reticulated structure formed by the glass phase in a form of agglomeration.

9. The reflecting layer according to claim 7 , wherein the diffuser particles are TiO 2 , the ultrafine nano particles are second Al 2 O 3 , the glass phase is formed by sintering glass powder particles, and the glass powder particles are selected from the group consisting of silicate glass, lead silicate glass, aluminoborosilicate glass, aluminate glass, soda-lime glass, quartz glass, and combinations thereof, wherein a particle size of the TiO 2 is 0.1 μm-0.2 μm, and a particle size of the second Al 2 O 3 is 0.01 μm-0.05 μm.

10. The reflecting layer according to claim 9 , wherein a mass ratio of the TiO 2 , the second Al 2 O 3 and the glass powder particles is (1 to 6):(0.3 to 8):(1 to 5).

11. The reflecting layer according to claim 9 , wherein the diffuse reflecting particles further comprise first Al 2 O 3 , and a mass ratio of the TiO 2 to the first Al 2 O 3 is (1 to 6):(0 to 4), and a particle size of the first Al 2 O 3 is 0.1 μm-0.2 μm.

12. A preparation method of a reflecting layer, the preparation method comprising:
S 11 , mixing ultrafine nano particles with an organic carrier, and then ball-milling to form a first slurry;
S 12 : adding glass powder particles into the first slurry, and then ball-milling to form a second slurry;
S 13 , adding diffuser particles into the second slurry, and then ball-milling to form a reflecting slurry;
S 14 : brushing the reflecting slurry on a thermally conductive ceramic substrate and drying; and
S 15 , brushing a light-emitting slurry on the dried reflecting slurry and sintering to form a wavelength conversion device consisting of a light-emitting layer, a reflecting layer and the thermally conductive ceramic substrate,
wherein the diffuser particles comprise first Al 2 O 3 and TiO 2 with particle sizes of 0.1 μm-0.2 μm, the ultrafine nano particles comprise second Al 2 O 3 with a particle size of 0.01 μm-0.05 μm, and a mass ratio of the TiO 2 , the first Al 2 O 3 , the second Al 2 O 3 and the glass powder particles is (1 to 6):(0 to 4):(0.3 to 8):(1 to 5).

13. A preparation method of a reflecting layer, the preparation method comprising:
S 21 : mixing ultrafine nano particles with an organic carrier, and then ball-milling to form a first slurry;
S 22 : adding glass powder particles into the first slurry, and then ball-milling to form a second slurry;
S 23 : adding diffuser particles in three batches into the second slurry, and ball-milling to form a reflecting slurry;
S 24 : brushing the reflecting slurry on a thermally conductive ceramic substrate and drying; and
S 25 : sintering the dried reflecting slurry to form a reflecting plate device consisting of a reflecting layer and the thermally conductive ceramic substrate,
wherein the diffuser particles comprise TiO 2 with a particle size of 0.1 μm-0.2 μm, and the ultrafine nano particles comprise second Al 2 O 3 with a particle size of 0.03 μm, and a mass ratio of the TiO 2 , the second Al 2 O 3 and the glass powder particles is 1:1:3.

Assignees

• Appotronics Corp Ltd

Inventors

• Li Qian
• Chen Yusan
• Wang Yangang
• Xu Yanzheng

Classifications

• G02B2207/107

  Porous materials, e.g. for reducing the refractive index · CPC title

• G02B5/0242

  by means of dispersed particles · CPC title

• G02B1/00

  Optical elements characterised by the material of which they are made; Optical coatings for optical elements · CPC title

• C03C11/00

  Multi-cellular glass {; Porous or hollow glass or glass particles} · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title