Viscosity index improver with improved shear-resistance and solubility after shear
US-10920164-B2 · Feb 16, 2021 · US
US12104137B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12104137-B2 |
| Application number | US-202118040165-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 1, 2021 |
| Priority date | Sep 1, 2020 |
| Publication date | Oct 1, 2024 |
| Grant date | Oct 1, 2024 |
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The present invention provides an engine oil composition including 70 to 95 percent by weight of a base oil and 0.01 to 15 percent by weight of a dispersant comb polymer, based on the overall weight of the engine oil composition. The dispersant comb polymer consists of 13.7% by weight of a macromonomer, which is an ester of methacrylic acid and a hydroxylated hydrogenated polybutadiene with Mn of 4750 g/mol; 51.5% by weight of n-butyl methacrylate; 17.3% by weight of LMA; 11.2% by weight of styrene; 0.2% by weight of methyl methacrylate; and 6.10% by weight of N,N-dimethylaminoethyl methacrylate. The modified dispersant inhibitor package contains 30 wt % or less of succinimide type dispersant based on the overall weight of the modified dispersant inhibitor additive package, and the engine oil composition has an SAE viscosity grade of 0W-X, wherein X is 30 or less.
Opening claim text (preview).
We claim: 1. An engine oil composition comprising: i) in the range of 70 to 95 percent by weight of a base oil, based on the overall weight of the engine oil composition; ii) in the range of 0.01 to 15 percent by weight of a dispersant comb polymer, based on the overall weight of the engine oil composition; iii) in the range of from 4.99 to 15 percent by weight of a modified dispersant inhibitor additive package based on the overall weight of the engine oil composition, wherein the dispersant comb polymer consists of a. 13.7% by weight of a macromonomer, which is an ester of methacrylic acid and a hydroxylated hydrogenated polybutadiene with Mn of 4750 g/mol; b. 51.5% by weight of n-butyl methacrylate; c. 17.3% by weight of LMA; d. 11.2% by weight of styrene; e. 0.2% by weight of methyl methacrylate; and f. 6.1% by weight of N,N-dimethylaminoethyl methacrylate; wherein the modified dispersant inhibitor package contains 30 wt % or less of succinimide dispersant based on the overall weight of the modified dispersant inhibitor additive package, and wherein the engine oil composition has an SAE viscosity grade of 0W-X, wherein X is 30 or less. 2. The engine oil composition according to claim 1 , wherein the base oil is a Fischer-Tropsch derived base oil. 3. The engine oil composition according to claim 1 , wherein the succinimide dispersant is present in the modified dispersant inhibitor package at an amount that is at least 50% less than that which would have been present if a viscosity modifier that was not a dispersant comb polymer consisting of 13.7% by weight of a macromonomer, which is an ester of methacrylic acid and a hydroxylated hydrogenated polybutadiene with Mn of 4750 g/mol); 51.5% by weight of n-butyl methacrylate; 17.3% by weight of LMA; 11.2% by weight of styrene; 0.2% by weight of methyl methacrylate; and 6.1% by weight of N,N-dimethylaminoethyl methacrylate, was used. 4. The engine oil composition according to claim 1 , wherein the succinimide dispersant is present in an amount in the range of from 0.01 to 3.5 wt % of the engine oil composition. 5. The engine oil composition according to claim 1 , wherein the succinimide dispersant is a polyolefin substituted succinimide dispersant.
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