Composite materials

Patent metadata

Field	Value
Publication number	US-12104101-B2
Application number	US-202016872088-A
Country	US
Kind code	B2
Filing date	May 11, 2020
Priority date	May 10, 2019
Publication date	Oct 1, 2024
Grant date	Oct 1, 2024

Abstract

A composite material is disclosed including: a first material including a plurality of crosslinked first polymer chains including a plurality of first polymer monomeric units; a coating layer on the surface of the first material, wherein the coating layer includes a plurality of adhesion polymer chains, wherein the plurality of adhesion polymer chains includes a plurality of the first polymer monomeric units and a plurality of first bond-forming units, wherein the adhesion polymer chains are interwoven with the first polymer chains; and a second material including a plurality of second polymer chains, wherein the coating layer is disposed in-between the first and the second material and contacting the surface of the first and the second material, and a portion of the second polymer chains includes a plurality of second polymer monomeric units and second bond-forming units; wherein the first and the second bond-forming units form one or more bonds.

First claim

The invention claimed is:

1. A composite material comprising:
a first material comprising a plurality of crosslinked first polymer chains comprising a plurality of first polymer monomeric units;
a coating layer on at least a portion of the surface of the first material, wherein the coating layer comprises a plurality of adhesion polymer chains, wherein said plurality of adhesion polymer chains comprises a plurality of the first polymer monomeric units and a plurality of first bond-forming units, wherein the adhesion polymer chains are interwoven with the crosslinked first polymer chains; and
a second material comprising a plurality of second polymer chains on at least a surface of the second material, wherein the coating layer is disposed in-between the first material and the second material and contacting the surface of the first material and the second material, and at least a portion of each of the second polymer chains comprises a plurality of second polymer monomeric units and second bond-forming units;
wherein the first bond-forming units and the second bond-forming units form one or more bonds;
wherein the first material comprises an elastomer and a soft robot or a portion thereof;
wherein the second material comprises a hydrogel; and
wherein the one or more bonds formed between the first bond-forming units and the second bond-forming units comprise siloxane bonds.

2. The composite material of claim 1 , wherein the first polymer monomeric units and the second polymer monomeric units are each independently selected from the group consisting of the monomeric units of poly(hydroxyethylmethacrylate) (PHEMA), poly(acrylamide) (PAAM), poly(dimethylacrylamide) (PDMA), poly(N-isopropylacrylamide) (PNIPAM), sodium polyacrylate (NaPAA), poly(acrylic acid) (PAAc), poly(lactic-co-glycolic acid) (PLGA), poly(ethylene glycol) (PEG), poly(ethylene glycol) diacrylate (PEGDA), poly(ethylene glycol) methacrylate (PEGMA), poly(ethylene glycol) dimethacrylate (PEGDMA), poly(vinylidene fluoride) (PVDF), poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-co-HFP), poly(methyl methacrylate) (PMMA), cellulose, alginate, chitosan, and a combination thereof.

3. The composite material of claim 1 , wherein the first polymer monomeric units and the second polymer monomeric units are each independently selected from the group consisting of the monomeric units of styrene butadiene rubber, polybutadiene rubber, silicone rubber, polyurethane, and a combination thereof.

4. The composite material of claim 1 , wherein the second material comprises:
a sensor attached on the soft robot or a portion thereof,
a portion of a sensor attached on the soft robot or a portion thereof,
a conductive cable attached on the soft robot or a portion thereof, or
a wire attached on the soft robot or a portion thereof.

5. The composite material of claim 4 , wherein the sensor is selected from the group consisting of strain sensor, force sensor, light sensor, temperature sensor, humidity sensor, and a combination thereof.

6. The composite material of claim 4 , wherein the sensor is resistive or capacitive.

7. The composite material of claim 1 , wherein the first bond-forming units and the second bond-forming units each comprises a molecular moiety comprising a silicon atom linked to a functional group selected from a group consisting of OH, Cl, Br, I, OPh, ester, and sulfonate ester.

8. The composite material of claim 7 , wherein the first bond-forming units and the second bond-forming units are 3-(trimethoxysilyl) propyl methacrylate.

Assignees

• Harvard College

Inventors

• Cheng Sibo
• Narang Yashraj S
• Yang Canhui
• Suo Zhigang
• Howe Robert D

Classifications

• B32B2255/26

  Polymeric coating · CPC title

• B32B2457/00

  Electrical equipment · CPC title

• B32B2250/24

  All layers being polymeric · CPC title

• B32B25/20

  comprising silicone rubber · CPC title

• B32B25/16

  comprising polydienes {homopolymers} or poly-halodienes {homopolymers (B32B25/12 takes precedence)} · CPC title