Precoated aluminum material and aluminum composite material

Patent metadata

Field	Value
Publication number	US-12104074-B2
Application number	US-201917274360-A
Country	US
Kind code	B2
Filing date	Sep 10, 2019
Priority date	Sep 10, 2018
Publication date	Oct 1, 2024
Grant date	Oct 1, 2024

Abstract

A precoated aluminum material to which various resin members can be bonded and an aluminum composite material that is prepared using this precoated aluminum material are provided. A precoated aluminum material ( 1 ) comprises: a substrate ( 2 ) composed of an aluminum material; and a primer coating ( 3 ) formed on the substrate ( 2 ). The primer coating ( 3 ) contains urethane resin. In the infrared-absorption spectrum of the primer coating ( 3 ), the value of the optical absorption A C═O at the peak top of the maximum peak among peaks present in the wavenumber range of 1,180-1,330 cm −1 is 0.8-1.5 times that of the optical absorption A urethane at the peak top of the maximum peak among peaks present in the wavenumber range of 1,670-1,770 cm −1 .

First claim

The invention claimed is:

1. A precoated aluminum material, to which a resin member is bondable, comprising:
a substrate composed of an aluminum material; and
a primer coating formed on the substrate;
wherein:
the primer coating:
contains 3-50 parts by mass of an acrylic resin to 100 parts by mass of a urethane resin and 0.3-13 parts by mass of a melamine resin to 100 parts by mass of the urethane resin; and
has an infrared-absorption spectrum in which the value of the optical absorption A C═O at the peak top of the maximum peak among peaks present in the wavenumber range of 1,180-1,330 cm −1 is 0.8-1.5 times that of the optical absorption A urethane at the peak top of the maximum peak among peaks present in the wavenumber range of 1,670-1,770 cm −1 .

2. The precoated aluminum material according to claim 1 , wherein, in the infrared-absorption spectrum of the primer coating, the value of the optical absorption A COC at the peak top of the maximum peak among peaks present in the wavenumber range of 990-1,150 cm −1 is 0.7-1.3 times that of the optical absorption A urethane .

3. The precoated aluminum material according to claim 2 , wherein, in the infrared-absorption spectrum of the primer coating, the value of the optical absorption A aromatic at the peak top of the maximum peak among peaks present in the wavenumber range of 660-760 cm −1 is 1.0-1.7 times that of the optical absorption A urethane .

4. The precoated aluminum material according to claim 3 , wherein the urethane resin contains a structural unit derived from a polyester polyol.

5. The precoated aluminum material according to claim 4 , wherein the urethane resin contains a structural unit derived from an aromatic polyisocyanate.

6. An aluminum composite material comprising:
the precoated aluminum material according to claim 5 ; and
a resin member bonded to the primer coating of the precoated aluminum material, the resin member comprising at least one polymer selected from the group consisting of polybutylene terephthalate, polyamide, polyphenylene sulfide, and acrylonitrile-butadiene-styrene copolymer.

7. The precoated aluminum material according to claim 1 , wherein, in the infrared-absorption spectrum of the primer coating, the value of the optical absorption A aromatic at the peak top of the maximum peak among peaks present in the wavenumber range of 660-760 cm −1 is 1.0-1.7 times that of the optical absorption A urethane .

8. The precoated aluminum material according to claim 1 , wherein the urethane resin contains a structural unit derived from a polyester polyol.

9. The precoated aluminum material according to claim 8 , wherein the urethane resin contains a structural unit derived from an aromatic polyisocyanate.

10. The precoated aluminum material according to claim 1 , wherein the urethane resin contains a structural unit derived from an aromatic polyisocyanate.

11. An aluminum composite material comprising:
the precoated aluminum material according to claim 1 ; and
a resin member, which contains one or two or more from among polybutylene terephthalate, polyamide, polyphenylene sulfide, and acrylonitrile-butadiene-styrene copolymer and is bonded to the primer coating of the precoated aluminum material.

12. A composition of matter, comprising:
a substrate composed of aluminum or an aluminum alloy; and
an adhesive primer coating bonded to the substrate and comprising 3-50 parts by mass of an acrylic resin per 100 parts by mass of a polyurethane and 0.3-13 parts by mass of a melamine resin per 100 parts by mass of the polyurethane;
wherein an infrared-absorption spectrum of the adhesive primer coating exhibits:
a maximal value of optical absorption A C═O in the wavenumber range of 1,180-1,330 cm −1 ,
a maximal value of optical absorption A urethane in the wavenumber range of 1,670-1,770 cm −1 , and
the maximal value of optical absorption A C═O is 0.8-1.5 times the maximal value of optical absorption A urethane .

13. The composition of matter according to claim 12 , wherein the infrared-absorption spectrum of the adhesive primer coating further exhibits:
a maximal value of optical absorption A COC in the wavenumber range of 990-1,150 cm −1 ,
a maximal value of optical absorption A aromatic in the wavenumber range of 660-760 cm −1 ,
the maximal value of optical absorption A COC is 0.7-1.3 times the optical absorption A urethane , and
the maximal value of optical absorption A aromatic is 1.0-1.7 times the optical absorption A urethane .

14. The composition of matter according to claim 13 , wherein the polyurethane is composed of alternating structural units derived from a polyester polyol and from an aromatic di-isocyanate.

15. An aluminum composite material comprising:
the composition of matter according to claim 12 ; and
a resin member bonded to the adhesive primer coating, the resin member comprising at least one polymer selected from the group consisting of polybutylene terephthalate, polyamide, polyphenylene sulfide, and acrylonitrile-butadiene-styrene copolymer.

Assignees

• Uacj Corp

Inventors

• Kato Osamu

Classifications

• C09J175/06

  from polyesters · CPC title

• C09D181/04

  Polysulfides · CPC title

• C09D177/00 Primary

  Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain (based on polyhydrazides C09D179/06; based on polyamide-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title

• C09D167/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl - and the hydroxy groups directly linked to aromatic rings · CPC title

• C09D175/06

  from polyesters · CPC title