Flow reactor synthesis of polymers

Patent metadata

Field	Value
Publication number	US-12104016-B2
Application number	US-202117391806-A
Country	US
Kind code	B2
Filing date	Aug 2, 2021
Priority date	Oct 13, 2015
Publication date	Oct 1, 2024
Grant date	Oct 1, 2024

Abstract

A flow reactor system and methods having tubing useful as polymerization chamber. The flow reactor has at least one inlet and at least one mixing chamber, and an outlet. The method includes providing two phases, an aqueous phase and a non-aqueous phase and forming an emulsion for introduction into the flow reactor.

First claim

What is claimed is:

1. A system for continuous flow, diffusion-limited synthesis of a conductive polymer salt comprising:
a mixing chamber configured to form an emulsified reactant composition;
one or more amounts of tubing disposed to receive the emulsified reactant composition from the mixing chamber, wherein the one or more amounts of tubing are configured to provide diffusion-limiting conditions within the one or more amounts of tubing to polymerize a monomer of the emulsified reactant composition to form the conductive polymer salt in the one or more amounts of tubing; and
a fluid line coupled to each of the one or more amounts of tubing configured to introduce a collection medium into the one or more amounts of tubing.

2. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the one or more amounts of tubing are arranged in a coiled configuration.

3. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the one or more amounts of tubing are arranged in a planar configuration comprising a plurality of curved portions.

4. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the one or more amounts of tubing are coupled in a parallel configuration.

5. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the one or more amounts of tubing are coupled in a series configuration.

6. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 further comprising another mixing chamber configured to form the emulsified reactant composition and fluidically coupled to the one or more amounts of tubing.

7. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 further comprising a temperature controller configured to control a temperature within the one or more amounts of tubing.

8. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 further comprising at least one pressure unit coupled to the one or more amounts of tubing, the at least one pressure unit configured to monitor, during polymerization of the monomer, a pressure within the one or more amounts of tubing or a difference in pressure between an inlet and an outlet of the one or more amounts of tubing.

9. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein each of the one or more amounts of tubing further comprise an outlet for discharging the conductive polymer salt and the collection medium.

10. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the emulsified reactant composition comprises an aqueous aniline solution and a non-aqueous acid solution.

11. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the conductive polymer salt is polyaniline (PANI).

12. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 10 further comprising an aqueous aniline solution fluid control device coupled to an inlet of the mixing chamber and a non-aqueous acid solution fluid control device coupled to an inlet of the mixing chamber.

13. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 further comprising a flow control valve disposed to control flow of the emulsified reactant composition into each of the one or more amounts of tubing.

14. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 1 wherein the one or more amounts of tubing comprise a fluoropolymer.

15. A system for continuous flow, diffusion-limited synthesis of a conductive polymer salt comprising:
a mixing chamber configured to form an emulsified reactant composition;
one or more amounts of tubing fluidically coupled to the mixing chamber,
wherein each of the one or more amounts of tubing comprise a plurality of inlet ports disposed along a length of the one or more amounts of tubing, the plurality of inlet ports configured to introduce the emulsified reactant composition from the mixing chamber into the one or more amounts of tubing, and
wherein the one or more amounts of tubing are configured to provide diffusion-limiting conditions within the one or more amounts of tubing to polymerize a monomer of the emulsified reactant composition and to form the conductive polymer salt in the one or more amounts of tubing; and

a fluid line coupled to each of the one or more amounts of tubing configured to introduce a collection medium into the one or more amounts of tubing.

16. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 15 further comprising a temperature controller configured to control a temperature within the one or more amounts of tubing.

17. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 15 further comprising at least one pressure unit coupled to the one or more amounts of tubing, the at least one pressure unit configured to monitor, during polymerization of the monomer, a pressure within the one or more amounts of tubing or a difference in pressure between an inlet and an outlet of the one or more amounts of tubing.

18. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 15 wherein each of the one or more amounts of tubing further comprise an outlet for discharging the conductive polymer salt and the collection medium.

19. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 15 wherein the one or more amounts of tubing are arranged in a coiled configuration to form an extended tubular flow reactor.

20. The system for continuous flow, diffusion-limited synthesis of a conductive polymer salt of claim 15 further comprising a flow control value disposed to control flow of the emulsified reactant composition into each of the plurality of inlet ports.

Assignees

• Boeing Co

Inventors

• Kinlen Patrick John
• Zweig Andrew M

Classifications

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• B01J2219/00164

  controlling the flow · CPC title

• B01J2219/00087

  with heat exchange elements outside the reactor · CPC title

• B01J19/2415

  Tubular reactors · CPC title

• B01J19/243

  spirally, concentrically or zigzag wound · CPC title