Retroreflective article comprising embedded reflective layers

Patent metadata

Field	Value
Publication number	US-12099220-B2
Application number	US-202217957098-A
Country	US
Kind code	B2
Filing date	Sep 30, 2022
Priority date	Oct 27, 2017
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A retroreflective article including a binder layer and a plurality of retroreflective elements. Each retroreflective element includes a transparent microsphere partially embedded in the binder layer. At least some of the retroreflective elements include a reflective layer that is embedded between the transparent microsphere and the binder layer. At least some of the embedded reflective layers are localized reflective layers.

First claim

What is claimed is:

1. An intermediate article comprising:
a disposable carrier layer with a major surface;
a plurality of transparent microspheres partially and releasably embedded in the disposable carrier layer so that the transparent microspheres exhibit protruding surface areas;
and wherein at least some of the transparent microspheres each comprise an isolated reflective layer that is present on a portion of the protruding surface area of the transparent microsphere;
wherein each isolated reflective layer covers a portion of the protruding surface area of the transparent microsphere that is less than the entirety of the protruding surface area of the transparent microsphere,
wherein the isolated reflective layers are irregular and non-circular in shape and are positioned on the transparent microspheres so that, on average, geometric centers of the isolated reflective layers at least generally coincide with forward-rearward centerlines of the transparent microspheres and so that the isolated reflective layers occupy angular arcs of, on average, from at least 15 degrees to less than 60 degrees;
wherein all of the reflective layers on the transparent microspheres are metal reflective layers, with the proviso that none of the reflective layers on the transparent microspheres are, or include, a dielectric reflecting layer;
and with the further proviso that for each transparent microspheres in which the isolated metal reflective layer covers the portion of the protruding surface area of the transparent microsphere that is less than the entirety of the protruding surface area of the transparent microsphere, a remaining portion of the protruding surface area of the transparent microsphere that is not covered by the isolated metal reflective layer, does not comprise any reflective material of any kind.

2. The intermediate article of claim 1 wherein the article is configured so that at least some of the isolated metal reflective layers each cover a portion of the protruding surface area of the transparent microsphere that is at most 60% of the protruding surface area of the transparent microsphere.

3. The intermediate article of claim 1 wherein the article is configured so that at least some of the isolated metal reflective layers each cover a portion of the protruding surface area of the transparent microsphere that is at most 25% of the protruding surface area of the transparent microsphere.

4. The intermediate article of claim 1 wherein the article is configured so that at least some of the isolated metal reflective layers each cover a portion of the protruding surface area of the transparent microsphere in such manner that the covered portion of the protruding surface area of the transparent microsphere is less than 50% of a total surface area of the transparent microsphere.

5. The intermediate article of claim 1 wherein the article is configured so that at least some of the isolated metal reflective layers each cover a portion of the protruding surface area of the transparent microsphere in such manner that the covered portion of the protruding surface area of the transparent microsphere is less than 15% of a total surface area of the transparent microsphere.

6. The intermediate article of claim 1 wherein at least some of the isolated metal reflective layers occupy an angular arc of, on average, from at least 15 degrees to less than 50 degrees.

7. The intermediate article of claim 1 wherein at least some of the isolated metal reflective layers occupy an angular arc of, on average, from at least 15 degrees to less than 35 degrees.

8. The intermediate article of claim 1 wherein the article is configured to comprise at least some transparent microspheres that do not comprise any reflective layers disposed thereon, and wherein the transparent microspheres that comprise isolated metal reflective layers make up from at least 5 percent to at most 95 percent of the total number of transparent microspheres of the intermediate article.

9. The intermediate article of claim 1 wherein the isolated metal reflective layers are vapor-coated metal layers comprised of aluminum or silver.

10. The intermediate article of claim 1 wherein the transparent microspheres are partially and releasably embedded in the disposable carrier to 20 to 50 percent of the transparent microspheres' diameter.

11. The intermediate article of claim 1 wherein the transparent microspheres are covered by a removable cover film provided on the transparent microsphere-bearing side of the disposable carrier layer.

12. A method of making the intermediate article of claim 1 , the method comprising:
disposing isolated metal reflective layers or isolated metal reflective layer precursors onto portions of protruding areas of at least some transparent microspheres that are borne by a disposable carrier layer and that are partially and releasably embedded therein;
and, if isolated metal reflective layer precursors are present, transforming the isolated metal reflective layer precursors into isolated metal reflective layers.

13. The method of claim 12 wherein the process of disposing the isolated metal reflective layers or isolated metal reflective layer precursors onto the portions of the protruding areas of at least some of the transparent microspheres, is arranged so that the isolated metal reflective layers or isolated metal reflective layer precursors are not disposed on a surface of the disposable carrier.

14. A method of making a retroreflective article from the intermediate article of claim 1 , the method comprising:
disposing a binder precursor on the disposable carrier layer and on the protruding areas of the transparent microspheres; then,
solidifying the binder precursor to form a retroreflective article comprising a binder layer so that the metal isolated reflective layers become embedded between the transparent microspheres and the binder layer.

15. The method of claim 14 further comprising a step of removing the disposable carrier layer from the binder layer and from the transparent microspheres.

Assignees

• 3M Innovative Properties Company

Inventors

• Chen-Ho Kui
• Gilman Ann M
• Gotrik Kevin W
• Jones Scott J
• Lentz Daniel M
• Mccoy Michael A
• Niwas Shri
• Stay Matthew S
• Kuduva Raman Thanumoorthy Ramasubramani
• Xia Ying

Classifications

• A41D31/325

  using layered materials · CPC title

• B32B5/24

  one layer being a fibrous or filamentary layer · CPC title

• G02B5/128 Primary

  transparent spheres being embedded in matrix · CPC title