Fabric sheet with hig thermal stability
US-2016222557-A1 · Aug 4, 2016 · US
US12098482B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12098482-B2 |
| Application number | US-201816611865-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 6, 2018 |
| Priority date | May 11, 2017 |
| Publication date | Sep 24, 2024 |
| Grant date | Sep 24, 2024 |
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A textile fabric includes: a base body having at least one layer, the at least one layer comprising PEN, copolymers, and/or blends thereof as a binding component. The binding component is obtainable by applying temperatures above a glass transition temperature of a binding fiber sheath polymer to core/sheath binding fibers, in which the binding fiber sheath polymer contains PEN, copolymers, and/or blends thereof.
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The invention claimed is: 1. A textile fabric, comprising: a base body having at least one layer, the at least one layer comprising polyethylene naphthalate (PEN), copolymers of PEN, and/or blends thereof as a binding component, wherein the binding component is obtainable by applying temperatures above a glass transition temperature of a binding fiber sheath polymer to core/sheath binding fibers, in which the binding fiber sheath polymer contains PEN, copolymers of PEN, and/or blends thereof, and wherein the binding component is producible starting from core/sheath binding fibers in which the binding fiber sheath polymer comprises PEN, copolymers of PEN, and/or blends thereof having a non-zero degree of crystallinity of less than 80%, wherein the binding fiber sheath polymer has a higher melting point than the binding fiber core polymer, wherein a difference in the melting temperatures of the binding fiber sheath polymer and of the binding fiber core polymer is at least 2.5° C., wherein the fabric comprises matrix fibers, wherein a difference in a degree of crystallinity between the sheath of the core/sheath binding fibers and a degree of crystallinity of the matrix fibers prior to applying temperatures above a glass transition temperature of the binding fiber sheath polymer to core/sheath binding fibers is at least 5%, and wherein the degree of crystallinity of the matrix fibers is higher than the degree of crystallinity of the sheath of the core/sheath binding fibers. 2. The textile fabric according to claim 1 , wherein the binding component comprises a deformed fiber structure up to a completely fused continuous phase. 3. The textile fabric according to claim 1 , wherein after thermal storage at 160° ° C. for 1 week, the fabric exhibits a percentage reduction in a maximum tensile force in at least one direction of less than 5%, and/or an increase in the maximum tensile force in at least one direction of at least 1%. 4. The textile fabric according to claim 1 , wherein the PEN, copolymers of PEN, and/or blends thereof in the binding fiber sheath polymer have a cold crystallization temperature in a range of 70 to 200° C. 5. The textile fabric according to claim 1 , wherein the PEN, copolymers of PEN, and/or blends thereof in the binding fiber sheath polymer and/or in the binding component have a melting temperature in a range of 180 to 320° C. 6. The textile fabric according to claim 1 , wherein a ratio between the binding fiber core polymer and the binding fiber sheath polymer is from 90:10 to 10:90 (core:sheath weight ratio in wt. %). 7. The textile fabric according to claim 1 , wherein the matrix fibers comprise core/sheath matrix fibers comprising a matrix fiber sheath polymer and a matrix fiber core polymer. 8. The textile fabric according to claim 7 , wherein the matrix fiber sheath polymer is selected from same type of polymers, copolymers, and/or blends as the binding fiber sheath polymer, and/or wherein the matrix fiber core polymer is selected from same type of polymers, copolymers, and/or blends as the binding fiber core polymer. 9. The textile fabric according to claim 1 , wherein a total of a proportion of PEN, copolymers of PEN, and/or blends thereof and a proportion of polyethylene terephthalate and/or co-polyethylene terephthalate is more than 80 wt. % based on a total weight of the base body. 10. The textile fabric according to claim 1 , wherein a proportion of the PEN, copolymers of PEN, and/or blends thereof is 5 to 95 wt. % based on a total weight of the fabric. 11. A method of using the textile fabric according to claim 1 for production of electrical insulating materials, comprising: providing the textile fabric as carrier material for conductive strips and/or as layer separator for phase separation. 12. A method for producing the textile fabric according to claim 1 , comprising the following method steps: providing core/sheath binding fibers in which the sheath comprises PEN, copolymers of PEN, and/or blends thereof; forming a layer containing the core/sheath binding fibers; applying temperature to the layer, the temperature being above a cold crystallization temperature of the binding fiber sheath polymer so as to obtain the textile fabric. 13. The textile fabric according to claim 1 , wherein the non-zero degree of crystallinity is up to 70%. 14. The textile fabric according to claim 13 , wherein the non-zero degree of crystallinity is up to 60%. 15. The textile fabric according to claim 3 , wherein the percentage reduction in the maximum tensile force in at least one direction is from of 0 to 4%, and/or the increase in the maximum tensile force in at least one direction is from 5 to 100%. 16. The textile fabric according to claim 4 , wherein the cold crystallization temperature is in a range of 80 to 190° C. 17. The textile fabric according to claim 1 , wherein the binding fiber sheath polymer contains at least one homopolymer of PEN. 18. The textile fabric according to claim 1 , wherein the glass transition temperature of the binding fiber sheath polymer is higher by at least 5° C. than a glass transition temperature of a binding fiber core polymer.
Mixed fibres, e.g. at least two chemically different fibres or fibre blends · CPC title
sheath-core · CPC title
Composite yarns or filaments · CPC title
Polyesters · CPC title
the bonding agent being applied in dry state, e.g. thermo-activatable agents in solid or molten state, and heat being applied subsequently · CPC title
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