Diesel fuel composition

Patent metadata

Field	Value
Publication number	US-12098339-B2
Application number	US-202017602186-A
Country	US
Kind code	B2
Filing date	Apr 7, 2020
Priority date	Apr 10, 2019
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A diesel fuel composition as disclosed includes a fossil diesel component, a fatty acid methyl esters component, and a hydrotreated renewable paraffinic diesel component. A method is disclosed for producing the diesel composition and use thereof. Use of the hydrotreated renewable paraffinic diesel component as an oxidation stability improver is further disclosed.

First claim

The invention claimed is:

1. A diesel fuel composition comprising:
a. a fossil diesel component at least 20 vol-% of a total diesel fuel composition volume, the fossil diesel component having a boiling point range within a temperature range 150-400° C. measured according to EN-ISO-3405:2011;
b. a fatty acid methyl esters (FAME) component 2-10 vol-% of the total diesel fuel composition volume;
c. a hydrotreated renewable paraffinic diesel component 30-70 vol-% of the total diesel fuel composition volume, the hydrotreated renewable paraffinic diesel component containing at least 70 wt-% paraffins in a range of carbon number C15-C18 of a total weight of paraffins in the hydrotreated renewable paraffinic diesel component; and
d. antioxidant 10-1000 ppm by weight of the diesel fuel composition weight;
wherein a total amount of the fossil diesel component, the FAME component, and the hydrotreated renewable paraffinic diesel component is at least 99 vol-% of the total diesel fuel composition volume, and
wherein the diesel fuel composition has an oxidation stability of 105 min or more as measured according to EN 16091:2011.

2. The diesel fuel composition according to claim 1 , comprising:
hydrotreated renewable paraffinic diesel component 30-60 vol-% of the total diesel fuel composition volume.

3. The diesel fuel composition according to claim 1 , comprising:
fossil diesel component at least 30 vol-% of the total diesel fuel composition volume.

4. The diesel fuel composition according to claim 1 , wherein the hydrotreated renewable paraffinic diesel component comprises:
paraffins at least 90 wt-% of the total weight of the hydrotreated renewable paraffinic diesel component.

5. The diesel fuel composition according to claim 1 , wherein the hydrotreated renewable paraffinic diesel component comprises:
naphthenes at most 5.0 wt-% of the total weight of the hydrotreated renewable paraffinic diesel component.

6. The diesel fuel composition according to claim 1 , wherein the hydrotreated renewable paraffinic diesel component comprises:
paraffins in a range of carbon number C15-C18 at least 80 wt-% of the total weight of paraffins in the hydrotreated renewable paraffinic diesel component.

7. The diesel fuel composition according to claim 1 , wherein the hydrotreated renewable paraffinic diesel component comprises:
i-paraffins and n-paraffins in a weight ratio of i-paraffins to n-paraffins of at least 2.2.

8. The diesel fuel composition according to claim 1 , wherein the fossil diesel component is fossil middle distillate originating from non-renewable sources and having a boiling point range within a temperature range from 180 to 360° C.

9. The diesel fuel composition according to claim 1 , wherein the fossil diesel component comprises:
10-50 wt-% naphthenics, less than 45 wt-% aromatics, and 10-70 wt-% paraffins of a total weight of the fossil diesel component.

10. The diesel fuel composition according to claim 1 , comprising:
antioxidant 70 ppm by weight.

11. A method for producing a diesel fuel composition the method comprising:
providing a fossil diesel component;
providing a hydrotreated renewable paraffinic diesel component;
providing a fatty acid methyl esters (FAME) component;
providing an antioxidant; and
mixing the fossil diesel component, the hydrotreated renewable paraffinic diesel component, the FAME component, and the antioxidant with each other to form a diesel fuel composition containing, based on a total diesel composition volume, at least 20 vol-% fossil diesel component, the fossil diesel component having a boiling point range within a temperature range 150-400° C. measured according to EN-ISO-3405:2011; 30-70 vol-% hydrotreated renewable paraffinic diesel component, wherein the hydrotreated renewable paraffinic diesel component contains at least 70 wt-% paraffins in a range of carbon number C15-C18 of the total weight of paraffins in the hydrotreated renewable paraffinic diesel component; 2 vol-%-10 vol-% FAME component; and antioxidant 10-1000 ppm by weight of a diesel fuel composition weight, wherein the diesel fuel composition has an oxidation stability of 105 min or more as measured according to EN 16091:2011.

12. The method according to claim 11 , wherein providing a hydrotreated renewable paraffinic diesel component comprises:
i. providing a feedstock originating from renewable sources, the feedstock containing fatty acids, or fatty acid derivatives, or triglycerides, or a combination thereof;
ii. subjecting the feedstock to hydrotreatment to produce n-paraffins; and
optionally;
iii. subjecting at least a portion of the n-paraffins from step ii) to an isomerisation treatment to produce i-paraffins.

13. The method according to claim 11 comprising:
mixing the antioxidant with the fossil diesel component, the renewable paraffinic diesel component, and the FAME component to form a diesel fuel composition containing 70 ppm by weight antioxidant.

14. The method according to claim 11 , wherein the provided FAME component comprises:
10-5000 ppm by weight antioxidant.

15. A method of producing a diesel fuel composition according to claim 1 , the method comprising:
producing the diesel fuel composition as a heating oil.

16. A method to improve oxidation stability of a fuel composition containing a fossil diesel component and a fatty acid methyl esters (FAME) component the method comprising:
adding an oxidation stability improver as a hydrotreated renewable paraffinic diesel component to the fuel composition to form a combined fuel composition containing 30-70 vol-% renewable paraffinic diesel component of a total combined fuel composition volume.

17. The method according to claim 16 , wherein the hydrotreated renewable paraffinic diesel component comprises:
at least 70 wt-% paraffins in a range of carbon number C15-C18 of a total weight of paraffins in the hydrotreated renewable paraffinic diesel component.

18. The method according to claim 16 , wherein the combined fuel composition has a higher oxidation stability measured according to EN 16091:2011 compared to the components of the combined diesel fuel composition.

19. The method according to claim 16 , wherein the combined fuel composition comprises:
at least 20 vol-% fossil diesel component; and
2-10 vol-% FAME component of the total combined fuel composition volume.

20. The method according to claim 16 , wherein the total amount of the fossil diesel component, the FAME component, and the hydrotreated renewable paraffinic diesel component is at least 99 vol-% of the total combined diesel fuel composition volume.

21. The method according to claim 16 , comprising:
adding an antioxidant 10-1000 ppm by weight.

22. The method according to claim 16 , comprising:
wherein the combined fuel composition comprises antioxidant 10-1000 ppm by weight.

23. A method of improving oxidation stability of a fuel
composition to form the diesel fuel composition according to claim 1 , comprising:
adding a hydrotreated renewable paraffinic diesel component containing at least 70 wt-% paraffins in a range of carbon number C15-C18 of the total weight of paraffins in the hydrotreated renewable paraffinic diesel component, to the fuel composition containing:
a. a fossil diesel component having a boiling point range within a temperature range 150-400° C. measured according to EN-ISO-3405:2011;
b. a fatty acid methyl esters (FAME) component; and
d. antioxidant;

Assignees

• Neste Oyj

Inventors

• Kiiski Ulla
• Nortio Jenni
• Kuronen Markku

Classifications

• C10L2270/026

  for diesel engines, e.g. automobiles, stationary, marine · CPC title

• C10L2230/081

  Anti-oxidants · CPC title

• C10L2200/0446

  Diesel · CPC title

• C10L1/19

  Esters {ester radical containing compounds; ester ethers; carbonic acid esters (C10L1/1802, C10L1/1805, C10L1/1808, C10L1/1811, C10L1/1814, C10L1/1817 take precedence)} · CPC title

• C10L1/026 Primary

  for compression ignition · CPC title