Production of paraffinic products

Patent metadata

Field	Value
Publication number	US-12098332-B2
Application number	US-202017776931-A
Country	US
Kind code	B2
Filing date	Nov 13, 2020
Priority date	Nov 15, 2019
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A method for combined production of renewable paraffinic products is disclosed, wherein the method includes providing a renewable paraffinic feed, and fractionating the renewable paraffinic feed into two fractions. Within the two fractions, a lighter fraction fulfils a specification for an aviation fuel component, and a heavier fraction fulfils a specification for an electrotechnical fluid component.

First claim

The invention claimed is:

1. A method for combined production of renewable paraffinic products, the method comprising:
subjecting a renewable raw material containing fatty acids and/or esters of fatty acids to a hydrodeoxygenation and an isomerization to provide a renewable paraffinic feed; and
fractionating the renewable paraffinic feed into two fractions, such that within the two fractions,
a lighter fraction fulfils a specification for an aviation fuel component of ASTM D7566-17b Annex A2 for HEFA (hydroprocessed esters and fatty acids), and
a heavier fraction fulfils a specification for an electrotechnical fluid component of standard IEC 60296- 2 018,

a combined yield of the two fractions is at least 98 wt-% of the renewable paraffinic feed subjected to the fractionation, and
a yield of the lighter fraction is 20-90 wt-% of a total weight of the two fractions, and a yield of the heavier fraction is 10-80 wt-% of the total weight of the two fractions.

2. The method according to claim 1 , wherein the heavier fraction fulfils a specification for an electrotechnical fluid component of standard IEC 60296-2018 comprising:
a viscosity at 40° C. as measured according to ENISO 3104-1996 of 12 mm 2 /s or below, typically 3.4mm 2 /s,
a viscosity at −30°° C. as measured according to ENISO 3104-1996 of 1800 mm 2 /s or below, typically 42.2 mm 2 /s,
a flash point (PM) as measured according to ENISO 2719-2016 of at least 135° C., typically 138.5° C., and
an acidity of 0.01 mg KOH/g or below, typically less than 0.001 mg KOH/.

3. The method according to claim 1 , wherein the heavier fraction is a transformer oil fulfilling all Table 2 General Specifications of standard IEC 60296-2018.

4. The method according to claim 1 , wherein the fractionating is provided by distillation.

5. The method according to claim 1 , wherein the combined yield of the two fractions is at least 99 wt-% or 100 wt-% of the renewable paraffinic feed subjected to the fractionation.

6. The method according to claim 1 , wherein the isomerization is catalytic isomerization, and/or catalytic hydroisomerization.

7. The method according to claim 1 , comprising:
adjusting a production capacity of the lighter fraction and the production capacity of the heavier fraction by selection of at least one or more of hydrodeoxygenation and isomerization conditions, temperature and/or residence time in the isomerization, and/or by selection of the renewable raw material.

8. The method according to claim 1 , comprising:
performing the hydrodeoxygenation under a hydrogen pressure from 10 to 200 barg (bar gauge), at temperature from 200 to 400° C., and using liquid hourly space velocity of 0.2 h-1 to 10 h-1.

9. The method according to claim 1 , comprising:
performing the isomerization at a temperature of 200-500° C., and/or at 280-400°° C., and at a pressure of 10-150 bar (absolute), and/or 30-100 bar.

10. The method according to claim 1 , comprising:
subjecting the renewable paraffinic feed, after the hydrodeoxygenation and the isomerization, to a stabilization treatment in a stabilization column, at a pressure lower than the isomerization pressure, to obtain a stabilized renewable paraffinic feed and an overhead fraction containing hydrocarbons in a naphtha range (C4-C8);
followed by subjecting the stabilized renewable paraffinic feed to the fractionation, and optionally recovering and recycling at least part of the overhead fraction back to the stabilization column for refluxing.

11. The method according to claim 1 , comprising:
adjusting a production capacity of the lighter fraction and the production capacity of the heavier fraction by selection of a cloud point and/or density of the renewable paraffinic feed.

12. The method according to claim 11 ,
wherein the cloud point of the renewable paraffinic feed is −30° C. or below, or −34° C. or below, or −40° C. or below, or −48° C. or below, as measured according to EN23015-1994.

13. The method according to claim 1 , wherein a yield of the lighter fraction is 70-90 wt-% of the total weight of the two fractions, and a yield of the heavier fraction is 10-30 wt-% of the total weight of the two fractions.

14. The method according to claim 1 , wherein the renewable paraffinic feed contains C8-C22 hydrocarbons, or C10-C20 hydrocarbons, or C15-C18 hydrocarbons.

15. The method according to claim 1 , wherein the renewable paraffinic feed has a distillation range of within a range of 140° C.-340° C., and/or within the range of 180° C.-320° C.

16. The method according to claim 1 , wherein the lighter fraction fulfils a specification for an aviation fuel component of ASTM D7566-17b Annex A2 for HEFA comprising:
a density of at most 772 kg/m 3 as measured at 15° C. according to ASTM D4052-2016; and
a freezing point of less than −40° C. as measured according to IP529-2016.

17. The method according to claim 1 , wherein the lighter fraction is an aviation fuel component fulfilling all specifications of ASTM D7566-17b Annex A2 for HEFA.

18. The method according to claim 1 , comprising:
stabilizing the lighter fraction by admixing one or more antioxidants.

19. The method according to claim 1 , comprising:
blending:
1-50 vol-%, and/or 3-50 vol-%, of the lighter fraction;
99-50 vol-%, and/or 97-50 vol-%, of a fossil aviation fuel component;
and optionally one or more aviation fuel performance enhancing additive selected from at least one or more of antioxidants, metal deactivators, and fuel system icing inhibitors, and/or one or more aviation fuel handling and maintenance additive selected from electrical conductivity improvers, leak detection additives, biocidal additives, corrosion inhibitors, and/or lubricity improvers;
to obtain a final aviation fuel composition.

Assignees

• Neste Oyj

Inventors

• Nortio Jenni
• Sandberg Kati
• Sippola Väinö
• Rämö Virpi
• Vilja Jesse

Classifications

• C10M2203/003

  used as base material · CPC title

• C10M109/02

  Reaction products · CPC title

• C10G2400/10

  Lubricating oil · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G2300/4006

  Temperature · CPC title