Polymer-based build material for selective sintering

Patent metadata

Field	Value
Publication number	US-12098297-B2
Application number	US-201917291891-A
Country	US
Kind code	B2
Filing date	Nov 7, 2019
Priority date	Nov 12, 2018
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

Plastic powder for use as a building material for manufacturing a three-dimensional object by layer-by-layer melting and solidification by hardening of the building material at the positions corresponding to the cross-section of the three-dimensional object in the respective layer by exposure to radiation, preferably by exposure to NIR radiation, wherein the plastic powder comprises a dry blend of polymer-based particles and particles of a NIR absorber, wherein the NIR absorber comprises carbon black or is carbon black and wherein the weight percentage of carbon black in the total weight of polymer and carbon black particles is in the range of at least 0.02% and at most 0.45%, and/or wherein the carbon black has a mean primary particle diameter in the range of from 15 nm to 70 nm, preferably of at least 26 nm and/or at most 58 nm.

First claim

The invention claimed is:

1. A plastic powder for use as a building material for additively manufacturing a three-dimensional object by selectively solidifying the building material at positions corresponding to a cross-section of the three-dimensional object in the respective layer by exposure to near infrared radiation, wherein the plastic powder comprises:
a dry mixture of polymer-based particles and particles of a near infrared absorber,
wherein the near infrared absorber comprises carbon black;
wherein the weight percentage of the near infrared absorber in a total weight of the plastic powder is in the range of 0.02% and 0.45%; and
wherein the plastic powder comprises reflection particles having a surface which at least partially reflects the near infrared radiation, and wherein the reflection particles comprise TiO 2 .

2. The plastic powder according to claim 1 , wherein the weight percentage of the near infrared absorber in the total weight of the plastic powder is at least 0.07% and/or at most 0.15%.

3. The plastic powder according to claim 1 , wherein the plastic powder comprises a dry mixture of polymer-based particles and particles of a near infrared-absorber and the near infrared-absorber comprises carbon black, wherein the carbon black has an average primary particle diameter in the range of from 15 nm to 70 nm.

4. The plastic powder according to claim 1 , wherein in the CIE L*a*b* color model a lightness value (L* value) of the plastic powder, measured spectrophotometrically, is at most 75.00.

5. The plastic powder according to claim 1 , wherein:
the carbon black is amorphous industrial carbon black (definition according to EC number 215-609-9, CAS number 1333-86-4); and/or
a C content of the carbon black is more than 96% in quantitative elemental analysis.

6. The plastic powder according to claim 1 , wherein in the powder analysis of the plastic powder by means of a rheometer at aeration 1.0 mm/s, the power consumption is at most 200 mJ.

7. The plastic powder according to claim 1 , wherein the polymer-based particles comprise as polymer material at least one polymer selected from the group consisting of polyaryletherketone (PAEK), polyarylether sulfone (PAES), polyamide, polyester, polyether, polylactide, polyolefin, polystyrene, polyphenylene sulfide, polyvinylidene fluoride, polyphenylene oxide, polyimide, polyetherimide, polycarbonate and/or at least one copolymer which includes at least one of the preceding polymers or their monomer units, and/or at least one polymer blend comprising at least one of the polymers or copolymers.

8. A plastic powder for use as a building material for additively manufacturing a three-dimensional object by selectively solidifying the building material at positions corresponding to a cross-section of the three-dimensional object, wherein the plastic powder comprises:
polymer-based particles;
particles of a near infrared absorber dry-mixed with the polymer-based particles, wherein the near infrared absorber comprises at least carbon black, has a weight percentage in a range of 0.02% to 0.45% of a total weight of the plastic powder, and has a primary particle diameter in the range of at least 26 nm to at most 58 nm; and
reflection particles having a surface which at least partially reflects the near infrared radiation, and wherein the reflection particles comprise TiO 2 .

Assignees

• Eos Gmbh Electro Optical Systems

Inventors

• Hotter Andreas
• Paternoster Stefan
• Pfisterer Heiko
• Gerg Malin
• Mattes Thomas
• Christ Marius

Classifications

• C09D177/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C09D177/10 takes precedence) · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08K3/04

  Carbon · CPC title

• B29K2995/0077

  Yield strength; Tensile strength · CPC title