Dual curable organopolysiloxane composition

Patent metadata

Field	Value
Publication number	US-12098281-B2
Application number	US-201917282944-A
Country	US
Kind code	B2
Filing date	Oct 4, 2019
Priority date	Oct 8, 2018
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A dual curable organopolysiloxane composition is disclosed. The composition comprises: (A) a first organopolysiloxane having at least two mercapto (—SH) functional groups per molecule and free of an alkenyl group; (B) a second organopolysiloxane having at least one alkenyl group and at least one silicon atom-bonded alkoxy group per molecule; (C) optionally an organopolysiloxane having at least two alkenyl groups per molecule and free of silicon atom-bonded alkoxy group; (D) a photo-initiator; (E) a condensation catalyst; and (F) an epoxy functional compound. The composition has the ability to both photo-cure and cure through exposure to moisture, and exhibits good to excellent curability and long-term storage stability.

First claim

What is claimed is:

1. A dual curable organopolysiloxane composition, the composition comprising:
(A) a first organopolysiloxane having at least two mercapto functional groups per molecule and free of an alkenyl group;
(B) a second organopolysiloxane having at least one alkenyl group and at least one silicon atom-bonded alkoxy group per molecule, in an amount such that the amount of the mercapto groups in component (A) is in the range of from about 0.1 to about 10 moles per 1 mole of the total alkenyl groups in components (B) and (C);
(C) an organopolysiloxane having two alkenyl groups per molecule and free of a silicon atom-bonded alkoxy group, in an amount of from about 10 to about 80 mass % of the total mass of components (B) and (C);
(D) a photo-initiator in an amount of from about 0.01 to about 5 parts per 100 parts by mass of the total mass of components (A) to (F);
(E) a condensation catalyst in an amount of from about 0.01 to about 10 parts per 100 parts by mass of the total mass of components (A) to (F); and
(F) an epoxy functional compound in an amount of from about 0.01 to about 10 parts per 100 parts by mass of the total mass of components (A) to (F).

2. The composition according to claim 1 , wherein component (A) is an organopolysiloxane comprising at least two siloxane units represented by the following general formula:
(HSR 1 )R 2 x SiO (3-x)/2

wherein R 1 represents a divalent hydrocarbon group with 1 to 8 carbons, R 2 represents an alkyl group, an aryl group, a hydrogen atom, a hydroxyl group or an alkoxy group; and x is 0, 1 or 2.

3. The composition according to claim 1 , wherein component (A) has the mercapto groups in the range of from about 0.5 to about 15.0 mass %.

4. The composition according to claim 1 , wherein component (B) is an organopolysiloxane produced by a hydrosilation reaction of (B-1) an organopolysiloxane having at least two alkenyl groups per molecule and (B-2) an organosilicon compound having one silicon atom-bonded hydrogen atom and at least one silicon atom-bonded alkoxy group per molecule.

5. The composition according to claim 1 , wherein component (D) is selected from the group consisting of 4,4′-bis(dimethylamino)benzophenone, diethoxyacetophenone, 2,2-dimethoxy-1,2-diphenylethan-1-one, 1-hydroxycyclohexyl-phenyl-ketone, 2-hydroxy-2-methyl-1-phenyl-propan-1-one, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one, 1-[4-(2-hydroxyethoxy)phenyl]-2-hydroxy-2-methyl-propan-1-one, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)butan-1-one, bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide, and combinations thereof.

6. The composition according to claim 1 , wherein component (E) is an organo-metal catalyst selected from the group consisting of titanium compounds, zirconium compounds, and tin compounds.

7. The composition according to claim 1 , wherein component (F) is an epoxy functional organosilicon compound.

8. The composition according to claim 7 , wherein the epoxy functional silicon compound is selected from the group consisting of 3-glycidoxypropyl trimethoxysilane, 3-glycidoxypropyl methyldimethoxysilane, 3-glycidoxypropyl triethoxysilane, 2-(3,4-epoxycyclohexyl)ethyl trimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyl methyldimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyl triethoxysilane, 5,6-epoxyhexyl trimethoxysilane, 5,6-epoxyhexyl triethoxysilane, 8-glycidoxyoctyl trimethoxysilane, and combinations thereof.

9. The composition according to claim 1 , wherein the composition can cure from both a UV-radiation cure mechanism and a moisture cure mechanism.

10. A reaction product of a reaction of the composition according to claim 9 .

11. A potting, a coating, an adhesive or an encapsulation formed from the composition according to claim 1 .

Assignees

• Dow Silicones Corp

Inventors

• Liu Junying
• Wang Xianghuai

Classifications

• C09J183/06

  containing silicon bound to oxygen-containing groups (C09J183/12 takes precedence) · CPC title

• C09D183/08

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L83/08 Primary

  containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen · CPC title

• C08L83/06

  containing silicon bound to oxygen-containing groups (C08L83/12 takes precedence) · CPC title