Method for obtaining hexachlorodisilane by reacting at least one partially hydrogenated chlorodisilane on a solid unfunctionalized adsorber

Patent metadata

Field	Value
Publication number	US-12098075-B2
Application number	US-202017620046-A
Country	US
Kind code	B2
Filing date	Feb 20, 2020
Priority date	Feb 20, 2020
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A process for obtaining hexachlorodisilane and uses for the same. The process includes contacting at least one partially hydrogenated chlorodisilane of general formula H x Si 2 Cl (6-x) where x is from 1 to 5 in the liquid state with a solid non-functionalized adsorber material that is selected from the group comprising silicates, aluminosilicates, organic polymer and/or combinations thereof. The process also includes optionally separating the hexachlorodisilane and/or optionally separating the adsorber material.

First claim

The invention claimed is:

1. A process for obtaining hexachlorodisilane, comprising:
a) contacting at least one partially hydrogenated chlorodisilane of general formula H x Si 2 Cl (6-x) wherein x is selected from 1 to 5 and wherein the at least one partially hydrogenated chlorodisilane is in the liquid state, with a solid, non-functionalized adsorber material selected selected from the group consisting of silicates, aluminosilicates, organic polymer and combinations thereof; and
b) optionally separating the hexachlorodisilane and/or optionally separating the adsorber material.

2. The process of claim 1 , wherein the partially hydrogenated chlorodisilane is pentachlorodisilane.

3. The process of claim 1 , wherein the organic polymer is selected from the group consisting of polystyrene, polydivinylbenzene, styrene-divinylbenzene copolymer and combinations thereof.

4. The process of claim 1 , wherein the non-functionalized adsorber material is a styrene-divinylbenzene copolymer.

5. The process of claim 1 , wherein the non-functionalized adsorber material has an average particle size of 0.149 to 4.760 mm.

6. The process of claim 1 , wherein the non-functionalized adsorber material has a surface area of 200 to 2000 m2/g.

7. The process of claim 1 , wherein the non-functionalized adsorber material has an average pore diameter of 1 to 900*10{circumflex over ( )}-10 m.

8. The process of claim 1 , wherein prior to contacting the non-functionalized adsorber material with the at least one partially hydrogenated chlorodisilane, the non-functionalized adsorber material contains a proportion of water of less than 5% by weight.

9. The process of claim 1 , wherein the at least one partially hydrogenated chlorodisilane is a constituent of a mixture containing at least one chlorosilane of general formula H (4-x) SiCl x wherein x is from 1 to 4.

10. The process of claim 9 , wherein the mixture is an offgas stream from the production of polycrystalline silicon by hydrogen reduction of chlorosilane.

11. The process of claim 9 , wherein the mixture is an offgas stream from the production of tetrachlorosilane by hydrogenation.

12. The process of claim 9 , wherein low-boiling chlorosilanes present in the mixture are separated before the contacting with the non-functionalized adsorber material.

13. The process of claim 1 , wherein after step a) the proportion of unconverted partially hydrogenated chlorodisilane is less than 10% based on the respective starting content of the chlorodisilane.

14. The process of claim 2 , wherein the proportion of unconverted pentachlorodisilane is less than 5% by weight based on the starting content thereof.

15. A process of using a solid non-functionalized adsorber material selected from the group consisting of silicates, aluminosilicates, organic polymer and combinations thereof for obtaining hexachlorodisilane by contacting the adsorber material with at least one partially hydrogenated chlorodisilane of general formula H x Si 2 Cl (6-x) wherein x is from 1 to 5 in the liquid state.

Assignees

• Wacker Chemie Ag

Inventors

• Knoth Jens Felix
• Pätzold Uwe
• Strasser Monika

Classifications

• C01B33/107 Primary

  Halogenated silanes · CPC title

• C01B33/03

  by decomposition of silicon halides or halosilanes or reduction thereof with hydrogen as the only reducing agent · CPC title

• B01J20/261

  obtained by reactions only involving carbon to carbon unsaturated bonds (macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds per se C08F) · CPC title

• C01B33/1071 Primary

  Tetrachloride, trichlorosilane or silicochloroform, dichlorosilane, monochlorosilane or mixtures thereof · CPC title

• B01J20/10

  comprising silica or silicate · CPC title