Multilayer structure, method for producing same, packaging material and product including same, and protective sheet for electronic device

Patent metadata

Field	Value
Publication number	US-12097688-B2
Application number	US-202017782061-A
Country	US
Kind code	B2
Filing date	Dec 4, 2020
Priority date	Dec 6, 2019
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

The present invention provides a multilayer structure that has excellent gas barrier properties and an excellent peel strength between a base and a gas barrier layer after retorting, and that can retain a good appearance with no delamination even after retorting under stress. The present invention also provides packaging materials and products including such a multilayer structure. The present invention relates to a multilayer structure comprising a base (X), a layer (Z) stacked on the base (X), and a layer (Y) stacked on the layer (Z), the layer (Y) containing a reaction product (D) of an aluminum-containing metal oxide (A) and an inorganic phosphorus compound (BI), the layer (Z) containing a polyvinyl alcohol resin (C) and a polyester resin (L).

First claim

The invention claimed is:

1. A multilayer structure comprising a base (X), a layer (Z) stacked on the base (X), and a layer (Y) stacked on the layer (Z),
the layer (Y) containing a reaction product (D) of an aluminum-containing metal oxide (A) and an inorganic phosphorus compound (BI),
the layer (Z) containing a water-soluble polyvinyl alcohol resin (C) and a polyester resin (L),
wherein a mass ratio (C)/(L) of the water-soluble polyvinyl alcohol resin (C) and the polyester resin (L) is 1/99 to 45/55.

2. The multilayer structure according to claim 1 , wherein the polyester resin (L) is a polyester resin having a carboxyl group.

3. The multilayer structure according to claim 2 , wherein the layer (Z) has a thickness ranging from 1 to 100 nm, a degree of saponification of the water-soluble polyvinyl alcohol resin is 70 mol % or more and 99.9 mol % or less, the base (X) includes polyethylene terephthalate, the aluminum-containing metal oxide (A) includes at least one hydrolytic condensate of a compound (E) that includes a metal atom (M) and an optionally substituted alkoxy group having 1 to 9 carbon atoms bonded to the metal atom (M), and the inorganic phosphorus compound (BI) includes a phosphorus oxoacid.

4. The multilayer structure according to claim 1 , wherein the water-soluble polyvinyl alcohol resin (C) has a viscosity in a 4 mass % aqueous solution of 1 mPa·s to 100 mPa·s as measured in accordance with JIS K 6726 (1994).

5. The multilayer structure according to claim 1 , wherein the layer (Z) has a thickness ranging from 1 to 100 nm.

6. The multilayer structure according to claim 1 , wherein the base (X) and the layer (Y) have an interlayer peel strength of 100 gf/15 mm or more as measured while dropping water on a delaminating interface after 125° C., 30-minute retorting.

7. A method for producing the multilayer structure of claim 1 , comprising:
a step (I) of applying a coating liquid (R) containing the water-soluble polyvinyl alcohol resin (C), the polyester resin (La), and a solvent to the base (X), and removing the solvent to form the layer (Z);
a step (II) of applying a coating liquid (S) containing the aluminum-containing metal oxide (A), the inorganic phosphorus compound (BI), and a solvent to the layer (Z), and removing the solvent to form a precursor of layer (Y); and
a step (III) of heat treating the precursor of layer (Y) to form a layer (Y).

8. The method of claim 7 , further comprising, before the step (I), dissolving the water-soluble polyvinyl alcohol resin (C) in water to form an aqueous solution.

9. The method of claim 8 , further comprising, mixing the aqueous solution with the polyester resin (La) to form the coating liquid (R).

10. A packaging material comprising the multilayer structure of claim 1 .

11. The packaging material according to claim 10 , which is a vertical form-fill-seal bag, a vacuum packaging bag, a pouch, a laminated tube container, an infusion bag, a paper container, a strip tape, a container lid, or an in-mold labeled container.

12. A product using the packaging material of claim 10 in at least a part of the product.

13. The product according to claim 12 , wherein
the product comprises contents in an interior thereof,
the contents are a core material,
the interior of the product has a reduced pressure, and
the product functions as a vacuum insulator.

14. A protective sheet for electronic devices, comprising the multilayer structure of claim 1 .

15. An electronic device comprising the protective sheet of claim 14 .

16. The multilayer structure according to claim 1 , wherein the aluminum-containing metal oxide (A) includes at least one hydrolytic condensate of a compound (E) that includes a metal atom (M) and a characteristic group bonded to the metal atom (M), the characteristic group is selected from the group consisting of a halogen atom, nitrate, an optionally substituted alkoxy group having 1 to 9 carbon atoms, an optionally substituted aryloxy group having 6 to 9 carbon atoms, an optionally substituted acyloxy group having 2 to 9 carbon atoms, an optionally substituted alkenyloxy group having 3 to 9 carbon atoms, an optionally substituted P-diketonato group having 5 to 15 carbon atoms, and a diacylmethyl group having an optionally substituted acyl group having 1 to 9 carbon atoms.

17. The multilayer structure according to claim 1 , wherein the inorganic phosphorus compound (BI) includes at least one selected from the group consisting of a phosphorus oxoacid, a salt of the phosphorus oxoacid, and a derivative of the phosphorus oxoacid.

18. The multilayer structure according to claim 1 , wherein the water-soluble polyvinyl alcohol resin (C) includes at least one selected from the group consisting of an unmodified or modified polyvinyl alcohol resin and an unmodified or modified ethylene-vinyl alcohol copolymer resin.

19. The multilayer structure according to claim 1 , wherein the polyester resin (L) includes at least one reaction product between a polyvalent carboxylic acid and a polyol, the polyvalent carboxylic acid includes at least one selected from the group consisting of terephthalic acid, isophthalic acid, o-phthalic acid, 2,6-naphthalene dicarboxylic acid, p-phenylene carboxylic acid, 1,4-cyclohexane dicarboxylic acid, succinic acid, glutaric acid, adipic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, trimellitic acid, pyromellitic acid, and sodium sulfoisophthalate, and the polyol includes at least one selected from the group consisting of ethylene glycol, 1,2-propylene glycol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, diethylene glycol, triethylene glycol, polyethylene glycol, polytetramethylene glycol, 1,4-cyclohexane dimethanol, trimethylolpropane, pentaerythritol, and ethylene oxide adducts of bisphenol A.

20. The multilayer structure according to claim 1 , wherein the layer (Z) further includes an acrylic resin.

Assignees

• Kuraray Co

Inventors

• Kuzume Shuhei
• Sasaki Ryoichi
• Morihara Yasushi

Classifications

• C09D167/03

  the dicarboxylic acids and dihydroxy compounds having the carboxyl - and the hydroxy groups directly linked to aromatic rings · CPC title

• C09D167/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C09D167/06 takes precedence) · CPC title

• B32B2439/80

  Medical packaging · CPC title

• B32B2367/00

  Polyesters, e.g. PET, i.e. polyethylene terephthalate · CPC title

• B05D1/36

  Successively applying liquids or other fluent materials, e.g. without intermediate treatment · CPC title