Polyoxymethylene composition in food handling applications

Patent metadata

Field	Value
Publication number	US-12091525-B2
Application number	US-201916426625-A
Country	US
Kind code	B2
Filing date	May 30, 2019
Priority date	Jun 4, 2018
Publication date	Sep 17, 2024
Grant date	Sep 17, 2024

Abstract

The present disclosure is directed to a polyacetal, or polyoxymethylene (POM), base composition which contains an additive package containing additives suitable for food processing applications. Polyacetal or polyoxymethylene polymers are of the class of polymers containing —CH 2 O-repeat units, useful for molding all different types of products and articles. Of particular advantage, POM produced according to the present disclosure may demonstrate low formaldehyde emissions, extractables, or both, when measured by standard methods without containing any formaldehyde scavenger packages.

First claim

What is claimed:

1. A polymer composition comprising:
a polyoxymethylene polymer present in the polymer composition in an amount greater than about 60% by weight, the polyoxymethylene polymer having a melt volume flow rate of from about 1 cm 3 per 10 min to about 80 cm 3 per 10 min when tested at a temperature of 190° C. and at a load of 2.16 kg, the polyoxymethylene polymer comprising a polyoxymethylene copolymer having terminal hydroxyl groups, the polyoxymethylene polymer having a content of terminal hydroxyl groups of at least 5 mmol/kg, and wherein, in addition to terminal hydroxyl groups, the terminal groups of the polyoxymethylene polymer only including alkoxy groups, formate groups, acetate groups, aldehyde groups, or a combination thereof;
a mineral nucleant;
an antioxidant;
an acid scavenger;
one or more coloring agents; the one or more coloring agents comprising lead in an amount less than 50 ppm and zinc in an amount less than 100 ppm, wherein the one or more coloring agents are present in the polymer composition in conjunction with a dispersing agent, the dispersing agent comprising a polyethylene polymer, the polyethylene polymer having a molecular weight of from about 500 g/mol to about 10,000 g/mol, the polyethylene polymer being non-polar; and
wherein the polymer composition is free of all formaldehyde scavengers and displays a formaldehyde emission of less than about 15 ppm when tested according to VDA Test 275 and displays a formaldehyde extractable content of less than 15 ppm when tested according to a formaldehyde extractable test in water at a temperature of 40° C. for 10 days, and wherein the polymer composition contains no polymeric nucleant.

2. A polymer composition as defined in claim 1 , wherein the mineral nucleant comprises talc, talc being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight.

3. A polymer composition as defined in claim 1 , wherein the acid scavenger comprises a carboxylic acid salt.

4. A polymer composition as defined in claim 3 , wherein the carboxylic acid salt comprises an alkaline earth metal salt of a carboxylic acid.

5. A polymer composition as defined in claim 4 , wherein the acid scavenger comprises a calcium hydroxy stearate, the acid scavenger being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight.

6. A polymer composition as defined in claim 1 , wherein the polymer composition has an extractable formaldehyde content of less than about 8 ppm, when tested in water at 40° C. for 10 days.

7. A polymer composition as defined in claim 1 , wherein the polymer composition further contains a lubricant.

8. A polymer composition as defined in claim 7 , wherein the lubricant comprises an ethylene bis(stearamide), the ethylene bis(stearamide) being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight.

9. A polymer composition as defined in claim 1 , wherein the dispersing agent comprises a polymer having a density of from about 0.92 g/cm 3 to about 0.94 g/cm 3 .

10. A polymer composition as defined in claim 7 , wherein the lubricant comprises polytetrafluoroethylene, ultrahigh molecular weight silicone, a silicone oil, or a wax.

11. A polymer composition as defined in claim 1 , wherein the polymer composition further contains glass fibers.

12. A polymer composition as defined in claim 1 , wherein the polymer composition further contains a thermoplastic elastomer.

13. A polymer composition as defined in claim 12 , wherein the thermoplastic elastomer comprises a thermoplastic polyurethane elastomer.

14. A polymer composition as defined in claim 1 , wherein the mineral nucleant comprises talc, talc being present in the polymer composition in an amount from about 0.1% by weight to about 1% by weight, the acid scavenger comprising a calcium hydroxy stearate, the calcium hydroxy stearate being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight, the polymer composition further containing ethylene bis(stearamide), and wherein the polymer composition is free of polymeric nucleants.

15. A polymer composition as defined in claim 14 , wherein the polyoxymethylene polymer is present in the polymer composition in an amount greater than about 90% by weight.

16. A molded article made from the polymer composition as defined in claim 1 .

17. A molded article as defined in claim 16 , wherein the molded article comprises a consumer appliance part.

18. A molded article as defined in claim 16 , wherein the molded article comprises a conveyor part.

19. A molded article as defined in claim 16 , wherein the molded article comprises a part for a medical product.

20. A molded article formed from a polymer composition, the polymer composition comprising a polyoxymethylene polymer present in the polymer composition in an amount greater than about 60% by weight, the polyoxymethylene polymer having a melt volume flow rate of from about 1 cm 3 per 10 min to about 80 cm 3 per 10 min when tested at a temperature of 190° C. and at a load of 2.16 kg, the polyoxymethylene polymer comprising a polyoxymethylene copolymer having terminal hydroxyl groups, the polyoxymethylene polymer having a content of terminal hydroxyl groups of at least 5 mmol/kg, and wherein, in addition to terminal hydroxyl groups, the terminal groups of the polyoxymethylene polymer only including alkoxy groups, formate groups, acetate groups, aldehyde groups, or a combination thereof, talc being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight, an acid scavenger comprising a carboxylic acid salt, the acid scavenger being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight, a lubricant being present in the polymer composition in an amount from about 0.01% by weight to about 1% by weight, an antioxidant comprising a sterically hindered phenol, the antioxidant being present in the polymer composition in an amount from about 0.01% by weight to about 0.75% by weight, wherein the polymer composition comprises one or more coloring agents, the one or more coloring agents comprising lead in an amount less than 50 ppm and zinc in an amount less than 100 ppm, and wherein the polymer composition is free of all formaldehyde scavengers and displays a formaldehyde emission of less than about 15 ppm when tested according to VDA Test 275 and displays a formaldehyde extractable content of less than 15 ppm when tested according to a formaldehyde extractable test in water at a temperature of 40° ° C. for 10 days, and wherein the polymer composition contains no polymeric nucleant, the polymer composition exhibiting a tensile modulus of greater than about 2,000 MPa, a notched Charpy impact strength at 23° C. of greater than about 5 KJ/m 2 , and exhibiting a notched Charpy impact strength at −30° C. of greater than about 5 KJ/m 2 .

21. A molded article as defined in claim 20 , wherein the molded article comprises part of a food processing or beverage processing device.

22. A polymer composition comprising:
a polyoxymethylene polymer present in the polymer composition in an amount greater than about 60% by weight, the polyoxymethylene polymer having a melt volume flow rate of from about 1 cm 3 per 10 min to about 80 cm 3 per 10 min when tested at a temperature of 190° C. and at a load of 2.16 kg, the polyoxymethylene polymer comprising a polyoxymethylene copol

Assignees

• Celanese Int Corp

Inventors

• Zia Qamer
• Toennes Kai-Uwe
• Markgraf Kirsten

Classifications

• C08L2205/24

  Crystallisation aids · CPC title

• C08K5/1345

  Carboxylic esters of phenolcarboxylic acids · CPC title

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title