Articles including glass and/or glass-ceramic and methods of making the same

Patent metadata

Field	Value
Publication number	US-12091353-B2
Application number	US-202218288890-A
Country	US
Kind code	B2
Filing date	Apr 26, 2022
Priority date	May 3, 2021
Publication date	Sep 17, 2024
Grant date	Sep 17, 2024

Abstract

Glazing, such as for vehicles, includes a sheet of glass-ceramic that has different regions with different transmission properties, including a first visually clear region that blocks infrared, a second visually clear region that allows transmission of infrared, and a third colored region.

First claim

What is claimed is:

1. A glazing, comprising:
a sheet of glass-ceramic, the glass-ceramic having a silicate amorphous phase and a crystalline phase comprising precipitates of formula M x WO 3 and/or M x MoO 3 , where 0<x<1 and M is a dopant cation selected from the group consisting of H, Li, Na, K, Rb, Cs, Ca, Sr, Ba, Zn, Ag, Au, Cu, Sn, Cd, In, Tl, Pb, Bi, Th, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, U, Ti, V, Cr, Mn, Fe, Ni, Cu, Pd, Se, Ta, Bi, and Ce;
wherein the sheet is at least 0.5 millimeters thick;
wherein the glass-ceramic consists of less than 200 parts per million of iron;
wherein the sheet comprises first, second, and third regions discrete from one another with respect to location on the sheet,
wherein the first region has the M x WO 3 and/or M x MoO 3 precipitates at a volume fraction of the glass-ceramic greater than 1% and less than 20% and homogenously distributed within the silicate amorphous phase, wherein the first region has transmittance of at least 70% over a 100 nanometer-wide band at wavelengths in a range between 380 to 750 nanometers and less than 50% at wavelengths between 900 nanometers to 1800 nanometers,
wherein the second region has less than half the volume fraction of M x WO 3 and/or M x MoO 3 precipitates of the first region, wherein the second region has transmittance of at least 80% over a 100 nanometer-wide band at wavelengths in a range between 900 nanometers to 1800 nanometers, and
wherein the third region has essentially the same volume fraction and distribution of the M x WO 3 and/or M x MoO 3 precipitates as the first region but with different stoichiometry with respect to the dopant cation M and concentration x, wherein the third region has transmittance of less than 40% at wavelengths between 380 to 750 nanometers.

2. The glazing of claim 1 , wherein the first region has greater surface area of the sheet than the second region.

3. The glazing of claim 2 , wherein the first region has at least ten times greater surface area of the sheet than the second region.

4. The glazing of claim 3 , wherein the third region frames the first region.

5. The glazing of claim 4 , wherein the third region adjoins edges of the sheet.

6. The glazing of claim 1 , wherein the second region transmits a greater average percentage than the first region at wavelengths in a range between 380 to 750 nanometers.

7. The glazing of claim 6 , wherein the average percentage is at least 5% greater.

8. The glazing of claim 1 , wherein the sheet of glass-ceramic is a first sheet, the glazing further comprising a second sheet and an interlayer between the first sheet and the second sheet, wherein the second sheet is thicker than the first sheet.

9. The glazing of claim 8 , wherein the second sheet is amorphous glass.

10. The glazing of claim 9 , wherein the amorphous glass is strengthened such that an interior of the second sheet is in tension while exterior surfaces of the second sheet are in compression.

11. The glazing of claim 9 , wherein the interlayer comprises a polymeric material.

12. The glazing of claim 11 , wherein both the second sheet and the interlayer have transmittance of at least 80% at most wavelengths between 380 to 750 nanometers and at least 80% over a 100 nanometer-wide band in a range between 900 nanometers to 1800 nanometers.

13. The glazing of claim 1 , wherein the third region appears colored.

14. The glazing of claim 13 , wherein the first and second regions appear clear.

15. The glazing of claim 14 , wherein the second region appears clearer than the first region.

16. A method of making glazing, comprising:
heating first and third regions of a sheet of glass-ceramic to different temperatures, such that the difference is at least 50° C.;
focusing energy on a second region of a sheet of glass-ceramic;
wherein the glass-ceramic has a silicate amorphous phase and a crystalline phase comprising precipitates of formula M x WO 3 and/or M x MoO 3 , where 0<x<1 and M is a dopant cation selected from the group consisting of H, Li, Na, K, Rb, Cs, Ca, Sr, Ba, Zn, Ag, Au, Cu, Sn, Cd, In, Tl, Pb, Bi, Th, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, U, Ti, V, Cr, Mn, Fe, Ni, Cu, Pd, Se, Ta, Bi, and Ce;
wherein, at least in part due to the heating and focusing steps:
the second region has less than half the volume fraction of the M x WO 3 and/or M x MoO 3 precipitates of the first region, and
wherein the third region has essentially the same volume fraction and distribution of the M x WO 3 and/or M x MoO 3 precipitates as the first region but with different stoichiometry with respect to the dopant cation M and concentration x such that, for at least one dopant cation of the group, concentration x of that at least one dopant cation differs in the first and third regions at least by a factor of 2.

17. The method of claim 16 , wherein a laser focuses the energy on the second region.

18. The method of claim 16 , wherein localized heat sources are used to heat the first and third regions to different temperatures.

19. The method of claim 16 , further comprising sagging the sheet during the heating.

20. The method of claim 19 , wherein during the sagging, a second sheet is co-sagged and the sheet of glass-ceramic and the second sheet are coupled to one another by an interlayer, wherein the second sheet and the interlayer both have a transmittance of at least 80% over a 100 nanometer-wide band at wavelengths in a range between 380 nanometers to 1800 nanometers.

Assignees

• Corning Inc

Inventors

• Dejneka Matthew John
• Kohl Jesse

Classifications

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title

• C03C23/007

  by thermal treatment · CPC title

• C03C23/0025

  by a laser beam · CPC title

• C03C3/093

  containing zinc or zirconium · CPC title

• C03C3/091

  containing aluminium · CPC title