Laminate containing a metal and a polymer layer of a polyamide and an acrylate

Patent metadata

Field	Value
Publication number	US-12090737-B2
Application number	US-201917274632-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	Sep 14, 2018
Publication date	Sep 17, 2024
Grant date	Sep 17, 2024

Abstract

Described herein is a laminate including at least one first layer of at least one first metal and at least one further layer of a polymer composition (PC). Also described herein is a process for producing the laminate.

First claim

The invention claimed is:

1. A laminate comprising at least one first layer of at least one first metal and at least one further layer of a polymer composition (PC), wherein the polymer composition (PC) comprises the following components:
(A) 55% to 85% by weight of at least one polyamide selected from the group consisting of PA 6, PA 6.6, PA 6.10, PA 6.12, PA 12, PA 6.36, PA 6/6.6, PA 6/6I6T, PA 6/6I, PA 6/6.36 and PA 6/6T,
(B) 5% to 20% by weight of at least one first copolymer obtainable by polymerizing at least the following components:
(B1) at least one first C 2 -C 20 -alkene selected from the group consisting of ethene, propene, 1-butene, 2-butene, octene and butadiene,
(B2) at least one second C 2 -C 20 -alkene selected from the group consisting of ethene, propene, 1-butene, 2-butene, octene and butadiene, and
(B4) maleic anhydride,
wherein components (B1) and (B2) are different than one another, and

(C) 10% to 30% by weight of at least one second copolymer obtainable by polymerizing at least the following components:
(C1) at least one third C 2 -C 20 -alkene selected from the group consisting of ethene, propene, 1-butene, 2-butene, octene and butadiene, and
(C2) at least one acrylic acid derivative selected from the group consisting of methyl acrylate, butyl acrylate and acrylic acid;
wherein the laminate has a peel strength of at least 460 N/40 m for a peel test according to ASTM D1876.

2. The laminate according to claim 1 , wherein the laminate additionally comprises at least one second layer of at least one second metal and wherein the at least one first layer is joined to the at least one second layer via the at least one further layer.

3. The laminate according to claim 1 , wherein the at least one first metal is selected from the group consisting of iron, aluminum, copper, nickel and magnesium and also alloys thereof.

4. The laminate according to claim 1 , wherein the at least one first layer has a thickness in the range from 0.1 mm to 0.6 mm and/or wherein the at least one further layer has a thickness in the range from 0.02 to 2 mm.

5. A process for producing a laminate according to claim 1 , comprising the steps of
a) providing a film of a polymer composition (PC) comprising the following components:
(A) at least one polyamide,
(B) at least one first copolymer obtainable by polymerizing at least the following components:
(B1) at least one first C 2 -C 20 -alkene and
(B2) at least one second C 2 -C 20 -alkene,
where components (B1) and (B2) are different than one another, and

(C) at least one second copolymer obtainable by polymerizing at least the following components:
(C1) at least one third C 2 -C 20 -alkene and
(C2) at least one acrylic acid derivative,

b) heating a first sheet of at least one first metal, and
c) pressing the heated first sheet from step b) with the film provided in step a) to obtain the laminate.

6. The process according to claim 5 , wherein step b) comprises heating the first sheet to a temperature in the range from 150° C. to 350° C.

7. The process according to claim 5 , wherein the heating of the first sheet in step b) is effected by inductive means.

8. The process according to claim 5 , wherein step a) comprises providing the film by an extrusion process.

Assignees

• Basf Se

Inventors

• Spies Patrick
• Desbois Philippe
• Simon Jasmina

Classifications

• B32B2307/732

  Dimensional properties · CPC title

• B32B37/06

  characterised by the heating method · CPC title

• B32B27/308

  comprising acrylic (co)polymers · CPC title

• B32B15/18

  comprising iron or steel {(B32B15/011, B32B15/012 and B32B15/013 take precedence)} · CPC title

• B32B15/088 Primary

  comprising polyamides · CPC title