Graphene based structures and methods for shielding electromagnetic radiation
US-9215835-B2 · Dec 15, 2015 · US
US12089387B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12089387-B2 |
| Application number | US-202117392898-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 3, 2021 |
| Priority date | Aug 3, 2021 |
| Publication date | Sep 10, 2024 |
| Grant date | Sep 10, 2024 |
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A device and method for absorbing electromagnetic waves can include a honeycomb sheet formed by a plurality of interconnected hexagon cells arranged in rows. The hexagon cells are made up of sidewalls, each sidewall formed by two surfaces that converge at a top of the sidewall and diverge from the top to a bottom of the sidewall such that a thickness of the sidewalls increases from top to bottom and an angle forms between the two surfaces at the top of the sidewall. In an example, the angle is about 8 degrees. The honeycomb sheet can be coated with a magnetic, composite coating to increase electromagnetic shielding. An example coating includes magnetic multi-granular nanoclusters (MGNC) and multi-walled carbon nanotubes (MWCNT). A base layer can be attached to the honeycomb sheet for mechanical stability and additional absorption. The device is suitable for radar absorbing materials (RAM) for aerospace and military applications.
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What is claimed is: 1. A gradient honeycomb structure for absorbing electromagnetic waves, the honeycomb structure comprising: a honeycomb sheet formed by a plurality of interconnected hexagon cells arranged in rows, the hexagon cells made up of gradient sidewalls, each gradient sidewall having a thickness and a height, the height defined between a top and a bottom of the sidewall, the thickness of the sidewall defined between two surfaces of the sidewall and increasing along the height of the sidewall from the top to the bottom, the two surfaces that form the sidewall converging at the top of the sidewall to form an angle; and a magnetic coating applied to an exterior of the honeycomb sheet, the magnetic coating configured to increase electromagnetic shielding of the gradient honeycomb structure, wherein the gradient honeycomb structure exhibits decreased reflection and increased wave absorption, as compared to a non-gradient honeycomb structure. 2. The honeycomb structure of claim 1 further comprising a base layer connected to the honeycomb sheet. 3. The honeycomb structure of claim 1 wherein the magnetic coating is a composite of carbon nanotubes and nanoclusters. 4. The honeycomb structure of claim 3 wherein the composite comprises iron oxide (Fe 3 O 4 ) multi-granular nanoclusters (MGNC). 5. The honeycomb structure of claim 3 wherein the composite comprises flakes of multi-walled carbon nanotubes (MWCNT). 6. The honeycomb structure of claim 1 wherein the angle is between about 2 degrees and about 10 degrees. 7. The honeycomb structure of claim 6 wherein the angle is about 8 degrees. 8. The honeycomb structure of claim 1 wherein a thickness of the magnetic coating is between about 150 and about 200 mm. 9. A device for electromagnetic wave absorption, the device comprising: a honeycomb structure formed of multiple rows of interconnected, hollow hexagon cells, the hexagon cells formed of a plurality of gradient sidewalls, each gradient sidewall having a top, a bottom, an exterior surface and an interior surface, a height of the sidewall defined between the top and bottom, a thickness of the sidewall defined between the exterior and interior surfaces, the exterior and interior surfaces converge at the top of the sidewall and diverge from the top to the bottom such that the thickness is variable and increases from the top to the bottom of the sidewall, an angle forms between the exterior and interior surfaces at the top of the sidewall, and the angle is about 8 degrees; a base layer attached to a bottom of the honeycomb structure; and a composite coating applied to the honeycomb structure and the base layer, the composite coating comprising magnetic multi-granular nanoclusters (MGNC) and multi-walled carbon nanotubes (MWCNT). 10. The device of claim 9 wherein the thickness of the sidewall at or near the bottom of the sidewall is about 1 mm. 11. The device of claim 9 wherein a size of each hexagon cell is defined by a space between opposite sidewalls, and the size is about 5 mm. 12. The device of claim 9 wherein the height of each gradient sidewall is about 10 mm and a thickness of the base layer is about 7 mm. 13. The device of claim 9 wherein a thickness of the magnetic coating is between about 150 and about 200 mm. 14. The device of claim 9 wherein the exterior and interior surfaces intersect at the top of the sidewall. 15. A method of forming a gradient, coated honeycomb structure for use in absorbing electromagnetic waves, the method comprising: forming a honeycomb sheet having multiple rows of cells, each row of cells having a plurality of interconnected, hexagon cells formed by multiple gradient sidewalls, each gradient sidewall having a thickness and a height, the height defined between a top and a bottom of the sidewall, the thickness of the sidewall defined between two surfaces of the sidewall and increasing along the height of the sidewall from the top to the bottom, and the two surfaces that form the sidewall converge at the top of the sidewall to form an angle between about 2 degrees and about 10 degrees; and coating the honeycomb sheet with a magnetic, composite coating configured to increase electromagnetic shielding of the honeycomb structure. 16. The method of claim 15 further comprising: forming a base layer for attachment to the honeycomb sheet; and coating the base layer with the magnetic, composite coating. 17. The method of claim 16 wherein the base layer is integrally formed with the honeycomb sheet. 18. The method of claim 15 wherein the honeycomb sheet is formed via 3D printing. 19. The method of claim 15 wherein the magnetic, composite coating comprises magnetic multi-granular nanoclusters (MGNC) and multi-walled carbon nanotubes (MWCNT). 20. The method of claim 15 wherein the angle is 8 degrees.
Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite · CPC title
with carbon or carbonisable materials · CPC title
based on ferrites · CPC title
with a particular shape (H01Q17/007 takes precedence) · CPC title
Fibres, filaments, whiskers, platelets, or the like · CPC title
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