Composition of heat-expandable microspheres and use thereof
US-2024191049-A1 · Jun 13, 2024 · US
US12087470B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12087470-B2 |
| Application number | US-202017762744-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 23, 2020 |
| Priority date | Sep 26, 2019 |
| Publication date | Sep 10, 2024 |
| Grant date | Sep 10, 2024 |
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An electrical insulation device includes an insulator body having a chamber and an electrically insulating material within the chamber. The electrically insulating material includes a dry syntactic foam.
Opening claim text (preview).
The invention claimed is: 1. An electrical insulation device, the electrical insulation device comprising an insulator body comprising a chamber and an electrically insulating material within the chamber, wherein the electrically insulating material comprises a dry syntactic foam, wherein the dry syntactic foam is obtainable by foaming a mixture at least of polymer-based thermally expandable hollow microbeads in the expanded state and polymer-based thermally expandable hollow microbeads in the unexpanded state. 2. The electrical insulation device as claimed in claim 1 , wherein the insulator body consists of a material selected from composite materials, porcelain, and combinations thereof. 3. The electrical insulation device as claimed in claim 1 , wherein the insulator body is a tube made of a composite material or of porcelain. 4. The electrical insulation device as claimed in claim 1 , wherein the chamber of the insulator body is filled essentially completely with the dry syntactic foam. 5. The electrical insulation device as claimed in claim 1 wherein the dry syntactic foam is obtainable by foaming a mixture of at least two types of polymer-based thermally expandable hollow microbeads in the unexpanded state, wherein the at least two types of thermally expandable hollow microbeads have different temperature ranges for expansion. 6. The electrical insulation device as claimed in claim 1 in the form of a composite insulator or in the form of an arm of a high-voltage mast. 7. The electrical insulation device as claimed in claim 1 wherein the electrically insulating material has a density of 0.01 g/cm 3 to 0.6 g/cm 3 . 8. A composite insulator or an arm of a high-voltage mast comprising the electrical insulating device of claim 1 . 9. The electrical insulation device as claimed in claim 1 , wherein the dry syntactic foam does not contain any liquid polymer matrix. 10. A process for producing an electrical insulation device, the process comprising: (a) providing an insulator body having a chamber, either: (b1) providing a mixture at least comprised of polymer-based thermally expandable hollow microbeads in an expanded state and polymer-based thermally expandable hollow microbeads in the unexpanded state, or (b2) providing a mixture of at least two types of polymer-based thermally expandable hollow microbeads in an unexpanded state that have different temperature ranges for expansion, and (c) foaming of the mixture of thermally expandable hollow microbeads by heat treatment at a temperature in the range from 50° C. to 200° ° C. to form a dry syntactic foam as electrically insulating material, wherein the mixture of thermally expandable hollow microbeads is either introduced into the chamber of the insulator body and foamed therein or the mixture of thermally expandable hollow microbeads is first foamed and the resultant dry syntactic foam is introduced into the chamber of the insulator body. 11. The process as claimed in claim 10 , wherein the step (c) comprises the following component steps (c1) and (c2): (c1) foaming the mixture of thermally expandable hollow microbeads by heat treatment at a temperature in the range from 50° C. to 200° C. for a fixed duration to form a pre-expanded mixture of thermally expandable hollow microbeads, and (c2) foaming the pre-expanded mixture of thermally expandable hollow microbeads by another heat treatment for a fixed duration to form a dry syntactic foam as electrically insulating material, wherein the mixture of thermally expandable hollow microbeads in the component step (c1) is foamed in at least one suitable expansion mold having at least a smaller volume than the chamber of the insulator body to form individual structure components, and, in the component step (c2), the individual structure components are introduced into the chamber of the insulator body or into a suitable expansion mold for another heat treatment. 12. The process as claimed in claim 10 , wherein no adhesive is used for bonding of the electrically insulating material to the insulator body. 13. The process as claimed in claim 10 , wherein the foaming is conducted at a temperature in the range from 100° C. to 180° C.
Apparatus or processes specially adapted for manufacturing insulators or insulating bodies {(manufacture of porcelain for electric insulation C04B33/26)} · CPC title
Expandable microspheres, e.g. Expancel® · CPC title
from compositions containing microballoons, e.g. syntactic foams · CPC title
by sintering expandable particles · CPC title
plastics; resins; waxes · CPC title
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